Hydroxypropyl Cellulose‐Based Meter‐Long Structurally Colored Fibers for Advanced Fabrics

Abstract Structurally colored fibers are attractive alternatives to chemically colored fibers due to their rich optical properties, color stability, and environmental friendliness. However, the fabrication of structurally colored fibers using cost‐effective raw materials with the possibility to scal...

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Main Authors: Qinan Qin, Yan Xu
Format: Article
Language:English
Published: Wiley 2024-12-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.202404761
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author Qinan Qin
Yan Xu
author_facet Qinan Qin
Yan Xu
author_sort Qinan Qin
collection DOAJ
description Abstract Structurally colored fibers are attractive alternatives to chemically colored fibers due to their rich optical properties, color stability, and environmental friendliness. However, the fabrication of structurally colored fibers using cost‐effective raw materials with the possibility to scale up remains challenging. Here, a simple and scalable approach is developed to fabricate continuous meter‐long structurally colored fibers exhibiting brilliant structural colors across the visible spectrum and helix orientation‐dependent polarization states. The fibers are fabricated by extrusion of concentrated aqueous solutions of chemically crosslinked hydroxypropyl cellulose (HPC). The wavelengths and polarization states can be tuned by solution concentration, relaxation time, and collector's surface energy. The HPC‐based structurally colored fibers display excellent optical stability to mechanical straining, repeated drying/water impregnation, and prolonged heating at 150 °C. It is demonstrated that the HPC‐based structurally colored fibers can be woven into structurally colored fabrics with wavelength‐ and polarization‐coded optical patterns. The current work presents a strategy to tune the chiral nematic order, which constitutes an important step toward mass production of structurally colored fibers with stable and rich optical properties using easily available raw materials.
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spelling doaj-art-71d001c6d29a424bacd6d49669d9d2122025-08-20T02:50:00ZengWileyAdvanced Science2198-38442024-12-011146n/an/a10.1002/advs.202404761Hydroxypropyl Cellulose‐Based Meter‐Long Structurally Colored Fibers for Advanced FabricsQinan Qin0Yan Xu1State Key Laboratory of Inorganic Synthesis and Preparative ChemistryJilin UniversityChangchun130012P. R. ChinaState Key Laboratory of Inorganic Synthesis and Preparative ChemistryJilin UniversityChangchun130012P. R. ChinaAbstract Structurally colored fibers are attractive alternatives to chemically colored fibers due to their rich optical properties, color stability, and environmental friendliness. However, the fabrication of structurally colored fibers using cost‐effective raw materials with the possibility to scale up remains challenging. Here, a simple and scalable approach is developed to fabricate continuous meter‐long structurally colored fibers exhibiting brilliant structural colors across the visible spectrum and helix orientation‐dependent polarization states. The fibers are fabricated by extrusion of concentrated aqueous solutions of chemically crosslinked hydroxypropyl cellulose (HPC). The wavelengths and polarization states can be tuned by solution concentration, relaxation time, and collector's surface energy. The HPC‐based structurally colored fibers display excellent optical stability to mechanical straining, repeated drying/water impregnation, and prolonged heating at 150 °C. It is demonstrated that the HPC‐based structurally colored fibers can be woven into structurally colored fabrics with wavelength‐ and polarization‐coded optical patterns. The current work presents a strategy to tune the chiral nematic order, which constitutes an important step toward mass production of structurally colored fibers with stable and rich optical properties using easily available raw materials.https://doi.org/10.1002/advs.202404761hydroxypropyl celluloseoptical patterningstructurally colored fabricsstructurally colored fiberstunable optical properties
spellingShingle Qinan Qin
Yan Xu
Hydroxypropyl Cellulose‐Based Meter‐Long Structurally Colored Fibers for Advanced Fabrics
Advanced Science
hydroxypropyl cellulose
optical patterning
structurally colored fabrics
structurally colored fibers
tunable optical properties
title Hydroxypropyl Cellulose‐Based Meter‐Long Structurally Colored Fibers for Advanced Fabrics
title_full Hydroxypropyl Cellulose‐Based Meter‐Long Structurally Colored Fibers for Advanced Fabrics
title_fullStr Hydroxypropyl Cellulose‐Based Meter‐Long Structurally Colored Fibers for Advanced Fabrics
title_full_unstemmed Hydroxypropyl Cellulose‐Based Meter‐Long Structurally Colored Fibers for Advanced Fabrics
title_short Hydroxypropyl Cellulose‐Based Meter‐Long Structurally Colored Fibers for Advanced Fabrics
title_sort hydroxypropyl cellulose based meter long structurally colored fibers for advanced fabrics
topic hydroxypropyl cellulose
optical patterning
structurally colored fabrics
structurally colored fibers
tunable optical properties
url https://doi.org/10.1002/advs.202404761
work_keys_str_mv AT qinanqin hydroxypropylcellulosebasedmeterlongstructurallycoloredfibersforadvancedfabrics
AT yanxu hydroxypropylcellulosebasedmeterlongstructurallycoloredfibersforadvancedfabrics