Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex

Abstract An original way of elaborating vertical metal/molecules/metal memristive junctions through diazonium electrografting of the organic layer and inkjet‐printed top electrodes is reported here. The molecule of interest is a FeII coordination complex with ter‐pyridine ligands, having a diazonium...

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Main Authors: Camille Jubert Tomasso, Thomas Petenzi, Anna Tidu, Rassen Boukraa, Sofia Russi, Giorgio Mattana, Christelle Gautier, Tony Breton, Ivan T. Lucas, Hubert Perrot, Laure Fillaud
Format: Article
Language:English
Published: Wiley-VCH 2025-02-01
Series:Advanced Electronic Materials
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Online Access:https://doi.org/10.1002/aelm.202400350
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author Camille Jubert Tomasso
Thomas Petenzi
Anna Tidu
Rassen Boukraa
Sofia Russi
Giorgio Mattana
Christelle Gautier
Tony Breton
Ivan T. Lucas
Hubert Perrot
Laure Fillaud
author_facet Camille Jubert Tomasso
Thomas Petenzi
Anna Tidu
Rassen Boukraa
Sofia Russi
Giorgio Mattana
Christelle Gautier
Tony Breton
Ivan T. Lucas
Hubert Perrot
Laure Fillaud
author_sort Camille Jubert Tomasso
collection DOAJ
description Abstract An original way of elaborating vertical metal/molecules/metal memristive junctions through diazonium electrografting of the organic layer and inkjet‐printed top electrodes is reported here. The molecule of interest is a FeII coordination complex with ter‐pyridine ligands, having a diazonium anchoring group. The resulting junction exhibits a memristive behavior characterized by a high ON/OFF ratio and plasticity property. Through the application of advanced techniques such as UV–vis and Raman time‐resolved spectroelectrochemistry, the study demonstrates the significant role of switchable azo bonds derived from diazo electrografting in memristive behavior.
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spelling doaj-art-710c0306903e49da85c3e4f6c22c47962025-08-20T02:29:38ZengWiley-VCHAdvanced Electronic Materials2199-160X2025-02-01112n/an/a10.1002/aelm.202400350Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted ComplexCamille Jubert Tomasso0Thomas Petenzi1Anna Tidu2Rassen Boukraa3Sofia Russi4Giorgio Mattana5Christelle Gautier6Tony Breton7Ivan T. Lucas8Hubert Perrot9Laure Fillaud10LISE Sorbonne Université Paris 75005 FranceLISE Sorbonne Université Paris 75005 FranceLISE Sorbonne Université Paris 75005 FranceUniversité Paris Cité, ITODYS, CNRS UMR 7086 15 rue J.‐A. de Baïf Paris F‐75013 FranceLISE Sorbonne Université Paris 75005 FranceUniversité Paris Cité, ITODYS, CNRS UMR 7086 15 rue J.‐A. de Baïf Paris F‐75013 FranceMoltech Anjou Université d'Angers Angers 49100 FranceMoltech Anjou Université d'Angers Angers 49100 FranceIMN Nantes Université Nantes 44300 FranceLISE Sorbonne Université Paris 75005 FranceLISE Sorbonne Université Paris 75005 FranceAbstract An original way of elaborating vertical metal/molecules/metal memristive junctions through diazonium electrografting of the organic layer and inkjet‐printed top electrodes is reported here. The molecule of interest is a FeII coordination complex with ter‐pyridine ligands, having a diazonium anchoring group. The resulting junction exhibits a memristive behavior characterized by a high ON/OFF ratio and plasticity property. Through the application of advanced techniques such as UV–vis and Raman time‐resolved spectroelectrochemistry, the study demonstrates the significant role of switchable azo bonds derived from diazo electrografting in memristive behavior.https://doi.org/10.1002/aelm.202400350electrograftingorganic memristorspectroelectrochemistry
spellingShingle Camille Jubert Tomasso
Thomas Petenzi
Anna Tidu
Rassen Boukraa
Sofia Russi
Giorgio Mattana
Christelle Gautier
Tony Breton
Ivan T. Lucas
Hubert Perrot
Laure Fillaud
Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex
Advanced Electronic Materials
electrografting
organic memristor
spectroelectrochemistry
title Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex
title_full Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex
title_fullStr Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex
title_full_unstemmed Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex
title_short Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex
title_sort elucidation of switching mechanisms in memristive junctions integrating a iron ii ter pyridine diazoted complex
topic electrografting
organic memristor
spectroelectrochemistry
url https://doi.org/10.1002/aelm.202400350
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