Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination Compounds
Bismuth(III) phenoxides have been synthesized by electrochemical reactions of 1-naphthol, 2-naphthol, 4-aminophenol, 2-nitrophenol, 4-nitrophenol, 2-hydroxybenzoic acid, p-cresol, phenol, resorcinol, 2-tert-butylphenol and 2-tert-butyl-4-methoxyphenol at sacrificial bismuth anode and inert platinum...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/403782 |
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| _version_ | 1832560951352623104 |
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| author | Harpreet Kaur Baljit Singh |
| author_facet | Harpreet Kaur Baljit Singh |
| author_sort | Harpreet Kaur |
| collection | DOAJ |
| description | Bismuth(III) phenoxides have been synthesized by electrochemical reactions of 1-naphthol, 2-naphthol, 4-aminophenol, 2-nitrophenol, 4-nitrophenol, 2-hydroxybenzoic acid, p-cresol, phenol, resorcinol, 2-tert-butylphenol and 2-tert-butyl-4-methoxyphenol at sacrificial bismuth anode and inert platinum cathode using tetrabutylammonium chloride as supporting electrolyte. The coordination compounds of these phenols with 1, 10-phenanthroline and 2, 2ʼ-bipyridyl have also been synthesized electrochemically. The solid products separated in the anode compartment have been isolated and characterized by elemental analysis and infrared spectral studies. Current efficiencies of these reactions are quite high. |
| format | Article |
| id | doaj-art-70f44e587bd340bbb898fb50f7600b81 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-70f44e587bd340bbb898fb50f7600b812025-02-03T01:26:22ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-019138138810.1155/2012/403782Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination CompoundsHarpreet Kaur0Baljit Singh1Chemistry Department, Punjabi University, Patiala-147002, IndiaChemistry Department, Punjabi University, Patiala-147002, IndiaBismuth(III) phenoxides have been synthesized by electrochemical reactions of 1-naphthol, 2-naphthol, 4-aminophenol, 2-nitrophenol, 4-nitrophenol, 2-hydroxybenzoic acid, p-cresol, phenol, resorcinol, 2-tert-butylphenol and 2-tert-butyl-4-methoxyphenol at sacrificial bismuth anode and inert platinum cathode using tetrabutylammonium chloride as supporting electrolyte. The coordination compounds of these phenols with 1, 10-phenanthroline and 2, 2ʼ-bipyridyl have also been synthesized electrochemically. The solid products separated in the anode compartment have been isolated and characterized by elemental analysis and infrared spectral studies. Current efficiencies of these reactions are quite high.http://dx.doi.org/10.1155/2012/403782 |
| spellingShingle | Harpreet Kaur Baljit Singh Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination Compounds E-Journal of Chemistry |
| title | Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination Compounds |
| title_full | Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination Compounds |
| title_fullStr | Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination Compounds |
| title_full_unstemmed | Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination Compounds |
| title_short | Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination Compounds |
| title_sort | direct electrochemical synthesis of bismuth iii phenoxides and their coordination compounds |
| url | http://dx.doi.org/10.1155/2012/403782 |
| work_keys_str_mv | AT harpreetkaur directelectrochemicalsynthesisofbismuthiiiphenoxidesandtheircoordinationcompounds AT baljitsingh directelectrochemicalsynthesisofbismuthiiiphenoxidesandtheircoordinationcompounds |