COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXES
The synthesis of polymeric suspensions with a narrow particle size distribution is an urgent problem in modern science. The resulting polymeric microspheres are applicable in various fields of chemistry, pharmaceuticals, biology and medicine. In particular, they can be used as carriers of bioligands...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2016-08-01
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| Series: | Тонкие химические технологии |
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| Online Access: | https://www.finechem-mirea.ru/jour/article/view/40 |
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| author | I. A. Gritskova A. A. Amelichev O. A. Satskevich A. V. Shkolnikov A. A. Ezhova G. A. Simakova V. A. Vasnyov N. A. Lobanova B. A. Izmaylov |
| author_facet | I. A. Gritskova A. A. Amelichev O. A. Satskevich A. V. Shkolnikov A. A. Ezhova G. A. Simakova V. A. Vasnyov N. A. Lobanova B. A. Izmaylov |
| author_sort | I. A. Gritskova |
| collection | DOAJ |
| description | The synthesis of polymeric suspensions with a narrow particle size distribution is an urgent problem in modern science. The resulting polymeric microspheres are applicable in various fields of chemistry, pharmaceuticals, biology and medicine. In particular, they can be used as carriers of bioligands to create diagnostic test systems. This article presents the results of a study on the colloid-chemical characteristics of water-insoluble fluorinated silicone surfactants and kinetics of the polymerization process in their presence. The results were compared with data from studies on the properties of surfactants of similar structure not containing fluorine atoms in their structure. Studying these substances’ rheology enabled to determine the most suitable surfactants for adsorption forming a strong interfacial layer during the formation of polymermonomer particles during the polymerisation. The ability of fluorinated silicone surfactants to form a stable polymeric slurry was proved during heterophase polymerization of vinyl monomers. The resulting polymeric suspensions were characterized by a narrow particle size distribution and high aggregative stability during the synthesis and in storage. |
| format | Article |
| id | doaj-art-7093ef49fcbf49afab115b9b7abd2a32 |
| institution | DOAJ |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2016-08-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-7093ef49fcbf49afab115b9b7abd2a322025-08-20T03:23:10ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752016-08-01114566210.32362/2410-6593-2016-11-4-56-6240COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXESI. A. Gritskova0A. A. Amelichev1O. A. Satskevich2A. V. Shkolnikov3A. A. Ezhova4G. A. Simakova5V. A. Vasnyov6N. A. Lobanova7B. A. Izmaylov8Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Peoples’ Friendship University of RussiaMoscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Nesmeyanov Institute of Organometallic Compounds RAS (INEOS)Moscow Technological University (Institute of Fine Chemical Technologies)Nesmeyanov Institute of Organometallic Compounds RAS (INEOS)The synthesis of polymeric suspensions with a narrow particle size distribution is an urgent problem in modern science. The resulting polymeric microspheres are applicable in various fields of chemistry, pharmaceuticals, biology and medicine. In particular, they can be used as carriers of bioligands to create diagnostic test systems. This article presents the results of a study on the colloid-chemical characteristics of water-insoluble fluorinated silicone surfactants and kinetics of the polymerization process in their presence. The results were compared with data from studies on the properties of surfactants of similar structure not containing fluorine atoms in their structure. Studying these substances’ rheology enabled to determine the most suitable surfactants for adsorption forming a strong interfacial layer during the formation of polymermonomer particles during the polymerisation. The ability of fluorinated silicone surfactants to form a stable polymeric slurry was proved during heterophase polymerization of vinyl monomers. The resulting polymeric suspensions were characterized by a narrow particle size distribution and high aggregative stability during the synthesis and in storage.https://www.finechem-mirea.ru/jour/article/view/40organosilicon surfactantssynthesis of polystyrene latexesheterophase polymerizationbioligand carriercolloid-chemical characteristics |
| spellingShingle | I. A. Gritskova A. A. Amelichev O. A. Satskevich A. V. Shkolnikov A. A. Ezhova G. A. Simakova V. A. Vasnyov N. A. Lobanova B. A. Izmaylov COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXES Тонкие химические технологии organosilicon surfactants synthesis of polystyrene latexes heterophase polymerization bioligand carrier colloid-chemical characteristics |
| title | COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXES |
| title_full | COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXES |
| title_fullStr | COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXES |
| title_full_unstemmed | COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXES |
| title_short | COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXES |
| title_sort | colloid chemical properties of silicone surfactants used in the synthesis of polystyrene latexes |
| topic | organosilicon surfactants synthesis of polystyrene latexes heterophase polymerization bioligand carrier colloid-chemical characteristics |
| url | https://www.finechem-mirea.ru/jour/article/view/40 |
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