Preparation and Characterization of Cyperus-Derived Exosomes Loaded with Selenium Nanoparticles for Selenium Delivery Based on Exosome Protein Quantitation

Appropriate carriers or templates are crucial for maintaining the stability, biological activity, and bioavailability of selenium nanoparticles (SeNPs). Selecting suitable templates remains challenging for fully utilizing SeNPs functionalities and developing applicable products. Exosome-like nanopar...

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Main Authors: Dexiu Zhao, Xiaojun Yang, Abulimiti Kelimu, Bin Wu, Weicheng Hu, Hongbo Fan, Lei Jing, Dongmei Yang, Xinhong Huang
Format: Article
Language:English
Published: MDPI AG 2025-08-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/14/15/2724
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author Dexiu Zhao
Xiaojun Yang
Abulimiti Kelimu
Bin Wu
Weicheng Hu
Hongbo Fan
Lei Jing
Dongmei Yang
Xinhong Huang
author_facet Dexiu Zhao
Xiaojun Yang
Abulimiti Kelimu
Bin Wu
Weicheng Hu
Hongbo Fan
Lei Jing
Dongmei Yang
Xinhong Huang
author_sort Dexiu Zhao
collection DOAJ
description Appropriate carriers or templates are crucial for maintaining the stability, biological activity, and bioavailability of selenium nanoparticles (SeNPs). Selecting suitable templates remains challenging for fully utilizing SeNPs functionalities and developing applicable products. Exosome-like nanoparticles (ELNs) have gained importance in drug delivery systems, yet research on selenium products prepared using exosomes remains limited. To address this gap, we utilized Cyperus bean ELNs to deliver SeNPs, investigated three preparation methods for SeNPs-ELNs, identified the optimal approach, and performed characterization studies. Notably, all three methods successfully loaded SeNPs. Ultrasonic cell fragmentation is the optimal approach, achieving significant increases in selenium loading (5.59 ± 0.167 ng/μg), enlargement of particle size (431.17 ± 10.78 nm), and reduced absolute zeta potential (−4.1 ± 0.43 mV). Moreover, both exosome formulations demonstrated enhanced stability against aggregation during storage at 4 °C, while their stability varied with pH conditions. In vitro digestibility tests showed greater stability of SeNP-ELNs in digestive fluids compared to ELNs alone. Additionally, neither ELNs nor SeNP-ELNs exhibited cytotoxicity toward LO<sub>2</sub> cells, and the relative erythrocyte hemolysis remained below 5% at protein concentrations of 2.5, 7.5, 15, 30, and 60 μg/mL. Overall, ultrasonic cell fragmentation effectively loaded plant-derived exosomes with nano-selenium at high capacity, presenting new opportunities for their use as functional components in food and pharmaceutical applications.
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spelling doaj-art-7069d85e99ef42f29ad4438f4d64b7ab2025-08-20T03:36:06ZengMDPI AGFoods2304-81582025-08-011415272410.3390/foods14152724Preparation and Characterization of Cyperus-Derived Exosomes Loaded with Selenium Nanoparticles for Selenium Delivery Based on Exosome Protein QuantitationDexiu Zhao0Xiaojun Yang1Abulimiti Kelimu2Bin Wu3Weicheng Hu4Hongbo Fan5Lei Jing6Dongmei Yang7Xinhong Huang8College of Food and Pharmaceutical Science, Xinjiang Agricultural University, Urumqi 836500, ChinaCollege of Food and Pharmaceutical Science, Xinjiang Agricultural University, Urumqi 836500, ChinaCollege of Food and Pharmaceutical Science, Xinjiang Agricultural University, Urumqi 836500, ChinaInstitute of Agricultural Products Storage and Processing, Xinjiang Academy of Agricultural Sciences, Urumqi 836500, ChinaMedical College, Yangzhou University, Yangzhou 225001, ChinaCollege of Food Science and Engineering, South China University of Technology, Guangzhou 510641, ChinaCollege of Food and Pharmaceutical Science, Xinjiang Agricultural University, Urumqi 836500, ChinaCollege of Food and Pharmaceutical Science, Xinjiang Agricultural University, Urumqi 836500, ChinaXinjiang Camel Milk Engineering Technology Research Center, Altay 836500, ChinaAppropriate carriers or templates are crucial for maintaining the stability, biological activity, and bioavailability of selenium nanoparticles (SeNPs). Selecting suitable templates remains challenging for fully utilizing SeNPs functionalities and developing applicable products. Exosome-like nanoparticles (ELNs) have gained importance in drug delivery systems, yet research on selenium products prepared using exosomes remains limited. To address this gap, we utilized Cyperus bean ELNs to deliver SeNPs, investigated three preparation methods for SeNPs-ELNs, identified the optimal approach, and performed characterization studies. Notably, all three methods successfully loaded SeNPs. Ultrasonic cell fragmentation is the optimal approach, achieving significant increases in selenium loading (5.59 ± 0.167 ng/μg), enlargement of particle size (431.17 ± 10.78 nm), and reduced absolute zeta potential (−4.1 ± 0.43 mV). Moreover, both exosome formulations demonstrated enhanced stability against aggregation during storage at 4 °C, while their stability varied with pH conditions. In vitro digestibility tests showed greater stability of SeNP-ELNs in digestive fluids compared to ELNs alone. Additionally, neither ELNs nor SeNP-ELNs exhibited cytotoxicity toward LO<sub>2</sub> cells, and the relative erythrocyte hemolysis remained below 5% at protein concentrations of 2.5, 7.5, 15, 30, and 60 μg/mL. Overall, ultrasonic cell fragmentation effectively loaded plant-derived exosomes with nano-selenium at high capacity, presenting new opportunities for their use as functional components in food and pharmaceutical applications.https://www.mdpi.com/2304-8158/14/15/2724SeNPsexosomeprotein quantitationPEG precipitationultrasonic cell fragmentation
spellingShingle Dexiu Zhao
Xiaojun Yang
Abulimiti Kelimu
Bin Wu
Weicheng Hu
Hongbo Fan
Lei Jing
Dongmei Yang
Xinhong Huang
Preparation and Characterization of Cyperus-Derived Exosomes Loaded with Selenium Nanoparticles for Selenium Delivery Based on Exosome Protein Quantitation
Foods
SeNPs
exosome
protein quantitation
PEG precipitation
ultrasonic cell fragmentation
title Preparation and Characterization of Cyperus-Derived Exosomes Loaded with Selenium Nanoparticles for Selenium Delivery Based on Exosome Protein Quantitation
title_full Preparation and Characterization of Cyperus-Derived Exosomes Loaded with Selenium Nanoparticles for Selenium Delivery Based on Exosome Protein Quantitation
title_fullStr Preparation and Characterization of Cyperus-Derived Exosomes Loaded with Selenium Nanoparticles for Selenium Delivery Based on Exosome Protein Quantitation
title_full_unstemmed Preparation and Characterization of Cyperus-Derived Exosomes Loaded with Selenium Nanoparticles for Selenium Delivery Based on Exosome Protein Quantitation
title_short Preparation and Characterization of Cyperus-Derived Exosomes Loaded with Selenium Nanoparticles for Selenium Delivery Based on Exosome Protein Quantitation
title_sort preparation and characterization of cyperus derived exosomes loaded with selenium nanoparticles for selenium delivery based on exosome protein quantitation
topic SeNPs
exosome
protein quantitation
PEG precipitation
ultrasonic cell fragmentation
url https://www.mdpi.com/2304-8158/14/15/2724
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