TRIPHENYLTIN (IV) GLUTARATES: SYNTHESIS, FT-IR AND MÖSSBAUER STUDIES
Four new adducts catena-O,O′-glutaratotriphenylstannate, [(Me4N)2O2C(CH2)3CO2×4SnPh3Cl] (1), [(Me4N)2O2C(CH2)3CO2×3SnPh3Cl] (2), [(SnPh3)2O2C(CH2)3CO2×SnPh3Cl] (2′) and [(Cy2NH2)2O2C(CH2)3CO2×SnPh3Cl] (3), have been isolated from the reactions carried out in solution. The compounds have been charac...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2024-01-01
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| Series: | Journal of Engineering Studies and Research |
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| Online Access: | https://jesr.ub.ro/index.php/1/article/view/405 |
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| author | MOUHAMADOU SEMBENE BOYE MOUHAMADOU BIRAME DIOP MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP ALAIN WATTIAUX |
| author_facet | MOUHAMADOU SEMBENE BOYE MOUHAMADOU BIRAME DIOP MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP ALAIN WATTIAUX |
| author_sort | MOUHAMADOU SEMBENE BOYE |
| collection | DOAJ |
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Four new adducts catena-O,O′-glutaratotriphenylstannate, [(Me4N)2O2C(CH2)3CO2×4SnPh3Cl] (1), [(Me4N)2O2C(CH2)3CO2×3SnPh3Cl] (2), [(SnPh3)2O2C(CH2)3CO2×SnPh3Cl] (2′) and [(Cy2NH2)2O2C(CH2)3CO2×SnPh3Cl] (3), have been isolated from the reactions carried out in solution. The compounds have been characterized by FT-IR and Mössbauer spectroscopies except for 2’ whose structure is proposed on the basis of FT-IR data. Overall, the spectra studies sheew existence of several caracteristic bands such as υ (C=O), υ (CO2–), υ (Sn–O), υ (Sn–Cl), vibrations of glutarate ions, and the intense doublet showing the presence of phenyl groups. In the solid state, the suggested structures are discrete or of infinite chain. In this work, the geometry at Sn centers, trigonal bipyramidal or tetrahedral, is ascertained by the Mössbauer parameters. The glutarate ions exhibit a monodentate, tridentate or tetradentate coordination behavior towards the Sn atoms.
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| format | Article |
| id | doaj-art-6ff7a0c59451406980b7300c6569fb56 |
| institution | Kabale University |
| issn | 2068-7559 2344-4932 |
| language | English |
| publishDate | 2024-01-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj-art-6ff7a0c59451406980b7300c6569fb562025-02-09T11:36:48ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322024-01-01293TRIPHENYLTIN (IV) GLUTARATES: SYNTHESIS, FT-IR AND MÖSSBAUER STUDIESMOUHAMADOU SEMBENE BOYEMOUHAMADOU BIRAME DIOPMODOU SARRAMINATA DIASSE-SARRLIBASSE DIOPALAIN WATTIAUX Four new adducts catena-O,O′-glutaratotriphenylstannate, [(Me4N)2O2C(CH2)3CO2×4SnPh3Cl] (1), [(Me4N)2O2C(CH2)3CO2×3SnPh3Cl] (2), [(SnPh3)2O2C(CH2)3CO2×SnPh3Cl] (2′) and [(Cy2NH2)2O2C(CH2)3CO2×SnPh3Cl] (3), have been isolated from the reactions carried out in solution. The compounds have been characterized by FT-IR and Mössbauer spectroscopies except for 2’ whose structure is proposed on the basis of FT-IR data. Overall, the spectra studies sheew existence of several caracteristic bands such as υ (C=O), υ (CO2–), υ (Sn–O), υ (Sn–Cl), vibrations of glutarate ions, and the intense doublet showing the presence of phenyl groups. In the solid state, the suggested structures are discrete or of infinite chain. In this work, the geometry at Sn centers, trigonal bipyramidal or tetrahedral, is ascertained by the Mössbauer parameters. The glutarate ions exhibit a monodentate, tridentate or tetradentate coordination behavior towards the Sn atoms. https://jesr.ub.ro/index.php/1/article/view/405dimeric, discrete and polymeric structures, glutarate, spectroscop, tetrahedral or trigonal bipyramidal environments. |
| spellingShingle | MOUHAMADOU SEMBENE BOYE MOUHAMADOU BIRAME DIOP MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP ALAIN WATTIAUX TRIPHENYLTIN (IV) GLUTARATES: SYNTHESIS, FT-IR AND MÖSSBAUER STUDIES Journal of Engineering Studies and Research dimeric, discrete and polymeric structures, glutarate, spectroscop, tetrahedral or trigonal bipyramidal environments. |
| title | TRIPHENYLTIN (IV) GLUTARATES: SYNTHESIS, FT-IR AND MÖSSBAUER STUDIES |
| title_full | TRIPHENYLTIN (IV) GLUTARATES: SYNTHESIS, FT-IR AND MÖSSBAUER STUDIES |
| title_fullStr | TRIPHENYLTIN (IV) GLUTARATES: SYNTHESIS, FT-IR AND MÖSSBAUER STUDIES |
| title_full_unstemmed | TRIPHENYLTIN (IV) GLUTARATES: SYNTHESIS, FT-IR AND MÖSSBAUER STUDIES |
| title_short | TRIPHENYLTIN (IV) GLUTARATES: SYNTHESIS, FT-IR AND MÖSSBAUER STUDIES |
| title_sort | triphenyltin iv glutarates synthesis ft ir and mossbauer studies |
| topic | dimeric, discrete and polymeric structures, glutarate, spectroscop, tetrahedral or trigonal bipyramidal environments. |
| url | https://jesr.ub.ro/index.php/1/article/view/405 |
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