Highly Shielded Peroxo‐Cerium(IV)‐Containing Polyoxometalate: Synthesis, Structure, and Oxidative Studies

Highly Shielded Peroxo‐Cerium(IV)‐Containing Polyoxometalate: Synthesis, Structure, and Oxidative Studies

The peroxo‐bridged di‐cerium(IV)‐di‐lithium‐containing polyoxometalate [(CeIV2O2)Li2(P2W16O59)2]16− (Ce2Li2P4W32) is synthesized in a one‐pot aqueous synthetic procedure and isolated as a hydrated mixed alkali salt, K13.6Na1.4Li[(CeIV2O2)Li2(P2W16O59)2]·32H2O (KNaLi‐Ce2Li2P4W32). The novel polyanion...

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Bibliographic Details
Main Authors: Anusree Sundar, Danica Bajuk‐Bogdanović, Gordana Ćirić‐Marjanović, Talha Nisar, Veit Wagner, Arnulf Materny, Geoffrey B. Jameson, Bassem S. Bassil, Ulrich Kortz
Format: Article
Language:English
Published: Wiley-VCH 2025-07-01
Series:ChemistryEurope
Subjects:
cerium
oxidation
Raman spectroscopy
peroxo‐species
polyoxometalates
Online Access:https://doi.org/10.1002/ceur.202500082
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