Pyrolysis kinetics-dependent suitability of Al-based MOFs (CAU-10) for controlling amorphous γ-Al2O3 generation

Pyrolysis kinetics-dependent suitability of Al-based MOFs (CAU-10) for controlling amorphous γ-Al2O3 generation

The thermal degradation of Al-based MOF (CAU-10) were analyzed based on an isoconversional calculation method. The ɤ-Al2O3 formation were characterized using XRD, FTIR, 27Al NMR-MAS and SEM/EDX. The apparent activation energy Ea was evaluated using the iterative isoconversional method. The values of...

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Bibliographic Details
Main Authors: Donald Raoul Tchuifon Tchuifon, Lucresse Kora Tioma Nguena, Giscard Doungmo, Sandrale Grace Mokue Mafo, Frank Dorinel Solefack Feudjio, Cyrille Ghislain Fotsop
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Chemical Thermodynamics and Thermal Analysis
Subjects:
ɤ-Al2O3
MOF
CAU-10
Kinetic
Activation energy
Thermodynamics
Online Access:http://www.sciencedirect.com/science/article/pii/S266731262500015X
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