Fabrication of PVC Enrofloxacin-Selective Electrodes for Estimating Enrofloxacin in Pure Form and as Preparation Formula
This study explored the development and qualities of the response of electrochemical properties of enrofloxacin-selective electrodes using precipitation based on producing phosphotungstic, after utilizing a matrix of polyvinyl chloride (PVC) and dibutyl phthalate or dibutyl phosphate as a plasticiz...
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| Format: | Article |
| Language: | English |
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University of Baghdad, College of Science for Women
2023-12-01
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| Series: | مجلة بغداد للعلوم |
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| Online Access: | https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/7870 |
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| author | Omar Salih Hassan Sahar S M Alabdullah Amina M. Abass Ahmed Ahmed |
| author_facet | Omar Salih Hassan Sahar S M Alabdullah Amina M. Abass Ahmed Ahmed |
| author_sort | Omar Salih Hassan |
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This study explored the development and qualities of the response of electrochemical properties of enrofloxacin-selective electrodes using precipitation based on producing phosphotungstic, after utilizing a matrix of polyvinyl chloride (PVC) and dibutyl phthalate or dibutyl phosphate as a plasticizer. The resulting membrane sensors were an enrofloxacin-phosphotungstic electrode (sensors 1) and an ENR-DOP-PTA electrode (sensors 2). Linear responses of (ENR-DBPH-PTA) and (ENR-DOP-PTA) within the concentration ranges of 2.1×10-6-10-1 and 3.0×10-6-10-2 mol. L-1, respectively, for both sensors were observed. Slopes of 51.61±0.24 and 39.40± 0.16 mV/decade and pH ranges equal to 2.5-8.5 and 2.0-9.0 were observed for sensors 1 and 2, respectively. The coefficients of selectivity of the created sensors demonstrated phenomenal selectivity for ENR. The proposed sensors showed useful scientific properties for the assurance of ENR in drug dosage and pure form.
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| format | Article |
| id | doaj-art-6fa37e0b175b4464abe5d20308c2e5cd |
| institution | Kabale University |
| issn | 2078-8665 2411-7986 |
| language | English |
| publishDate | 2023-12-01 |
| publisher | University of Baghdad, College of Science for Women |
| record_format | Article |
| series | مجلة بغداد للعلوم |
| spelling | doaj-art-6fa37e0b175b4464abe5d20308c2e5cd2025-08-20T03:33:42ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862023-12-0120610.21123/bsj.2023.7870Fabrication of PVC Enrofloxacin-Selective Electrodes for Estimating Enrofloxacin in Pure Form and as Preparation FormulaOmar Salih Hassan0Sahar S M Alabdullah1Amina M. Abass2Ahmed Ahmed 3Department of Chemistry, College of Education for Pure Sciences, Tikrit University, Tikrit, Iraq Department of Chemistry, College of Science, Al-Nahrain University, Al-Jaderia, Baghdad-IraqDepartment of Chemistry, College of Science, Al-Nahrain University, Al-Jaderia, Baghdad-Iraq. Department of Chemistry, College of Science, Al-Nahrain University, Al-Jaderia, Baghdad-Iraq. This study explored the development and qualities of the response of electrochemical properties of enrofloxacin-selective electrodes using precipitation based on producing phosphotungstic, after utilizing a matrix of polyvinyl chloride (PVC) and dibutyl phthalate or dibutyl phosphate as a plasticizer. The resulting membrane sensors were an enrofloxacin-phosphotungstic electrode (sensors 1) and an ENR-DOP-PTA electrode (sensors 2). Linear responses of (ENR-DBPH-PTA) and (ENR-DOP-PTA) within the concentration ranges of 2.1×10-6-10-1 and 3.0×10-6-10-2 mol. L-1, respectively, for both sensors were observed. Slopes of 51.61±0.24 and 39.40± 0.16 mV/decade and pH ranges equal to 2.5-8.5 and 2.0-9.0 were observed for sensors 1 and 2, respectively. The coefficients of selectivity of the created sensors demonstrated phenomenal selectivity for ENR. The proposed sensors showed useful scientific properties for the assurance of ENR in drug dosage and pure form. https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/7870Detection limit, Enrofloxacin, Electrodes, Pharmaceutical preparations, Plasticizers, Selectivity |
| spellingShingle | Omar Salih Hassan Sahar S M Alabdullah Amina M. Abass Ahmed Ahmed Fabrication of PVC Enrofloxacin-Selective Electrodes for Estimating Enrofloxacin in Pure Form and as Preparation Formula مجلة بغداد للعلوم Detection limit, Enrofloxacin, Electrodes, Pharmaceutical preparations, Plasticizers, Selectivity |
| title | Fabrication of PVC Enrofloxacin-Selective Electrodes for Estimating Enrofloxacin in Pure Form and as Preparation Formula |
| title_full | Fabrication of PVC Enrofloxacin-Selective Electrodes for Estimating Enrofloxacin in Pure Form and as Preparation Formula |
| title_fullStr | Fabrication of PVC Enrofloxacin-Selective Electrodes for Estimating Enrofloxacin in Pure Form and as Preparation Formula |
| title_full_unstemmed | Fabrication of PVC Enrofloxacin-Selective Electrodes for Estimating Enrofloxacin in Pure Form and as Preparation Formula |
| title_short | Fabrication of PVC Enrofloxacin-Selective Electrodes for Estimating Enrofloxacin in Pure Form and as Preparation Formula |
| title_sort | fabrication of pvc enrofloxacin selective electrodes for estimating enrofloxacin in pure form and as preparation formula |
| topic | Detection limit, Enrofloxacin, Electrodes, Pharmaceutical preparations, Plasticizers, Selectivity |
| url | https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/7870 |
| work_keys_str_mv | AT omarsalihhassan fabricationofpvcenrofloxacinselectiveelectrodesforestimatingenrofloxacininpureformandaspreparationformula AT saharsmalabdullah fabricationofpvcenrofloxacinselectiveelectrodesforestimatingenrofloxacininpureformandaspreparationformula AT aminamabass fabricationofpvcenrofloxacinselectiveelectrodesforestimatingenrofloxacininpureformandaspreparationformula AT ahmedahmed fabricationofpvcenrofloxacinselectiveelectrodesforestimatingenrofloxacininpureformandaspreparationformula |