A Highly Sensitive TDLAS-Based Water Vapor Isotopes Sensor Using a Quantum Cascade Laser

Based on tunable diode laser absorption spectroscopy (TDLAS), a water isotopes detection system was developed to detect the isotopic abundance of water vapor in the atmosphere. A single 1483.79 cm<sup>−1</sup> quantum cascade laser (QCL) and a 3120 cm optical path multi-pass cell (MPC) w...

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Bibliographic Details
Main Authors: Wenling Jin, Nailiang Cao, Yufei Ma
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Sensors
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Online Access:https://www.mdpi.com/1424-8220/25/3/840
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Summary:Based on tunable diode laser absorption spectroscopy (TDLAS), a water isotopes detection system was developed to detect the isotopic abundance of water vapor in the atmosphere. A single 1483.79 cm<sup>−1</sup> quantum cascade laser (QCL) and a 3120 cm optical path multi-pass cell (MPC) were adopted in the detection system. The selected spectral range, as well as the laser technology used, is particularly interesting for the real-time monitoring of water vapor isotopes in the atmosphere. In this study, a single laser can be used to perform high-sensitivity, rapid investigations of H<sub>2</sub>O, H<sub>2</sub><sup>18</sup>O, H<sub>2</sub><sup>17</sup>O, and HDO absorption lines. Finally, we measured the abundance values of three isotopes of water vapor in the atmosphere and compared them with data from the Global Network of Isotopes in Precipitation (GNIP) website, dedicated to exploring the possibility of in situ monitoring of H₂O isotopes in the atmosphere.
ISSN:1424-8220