Future Changes in Carbon Chemistry Under the Implementation of Artificial Ocean Alkalinization Based on CMIP6 Simulations

Artificial ocean alkalinization (AOA) is one of the most promising marine carbon dioxide removal technologies, but its influence on marine carbon chemistry remains unclear. We applied data from the Sixth Coupled Model Intercomparison Project (CMIP6) to characterize the temporal and spatial variabili...

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Main Authors: Baoxiao Qu, Jinming Song, Xuegang Li, Huamao Yuan, Liqin Duan
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Oceans
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Online Access:https://www.mdpi.com/2673-1924/6/2/29
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author Baoxiao Qu
Jinming Song
Xuegang Li
Huamao Yuan
Liqin Duan
author_facet Baoxiao Qu
Jinming Song
Xuegang Li
Huamao Yuan
Liqin Duan
author_sort Baoxiao Qu
collection DOAJ
description Artificial ocean alkalinization (AOA) is one of the most promising marine carbon dioxide removal technologies, but its influence on marine carbon chemistry remains unclear. We applied data from the Sixth Coupled Model Intercomparison Project (CMIP6) to characterize the temporal and spatial variabilities of future marine carbon chemistry under the implementation of AOA. Our study shows that the marine carbon system varied significantly under the implementation of AOA, but some specific effects may be masked by the forcing of the high carbon emission scenario SSP5-8.5. Based on the CMIP6 protocol, which added 0.14 Pmol of alkalinity into the ocean annually, AOA promoted an increase in DIC, delayed the rise in <i>p</i>CO<sub>2</sub>, and mitigated declines in pH and Ω, respectively. The temperate oceans in both hemispheres were the most significantly impacted basins, whereas the Southern Ocean was the least affected. During this century, the oceanic carbon sink is expected to intensify rapidly until around the year 2080, and then gradually weaken. The implementation of AOA merely changed the relative strength of the oceanic sink, rather than its overall variation pattern. Furthermore, in the deep ocean, the effect of AOA was present but quite limited in mitigating ocean acidification.
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spelling doaj-art-6f377e07507e4ea1bc60d72a7158f6b82025-08-20T02:21:46ZengMDPI AGOceans2673-19242025-05-01622910.3390/oceans6020029Future Changes in Carbon Chemistry Under the Implementation of Artificial Ocean Alkalinization Based on CMIP6 SimulationsBaoxiao Qu0Jinming Song1Xuegang Li2Huamao Yuan3Liqin Duan4CAS Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266404, ChinaCAS Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266404, ChinaCAS Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266404, ChinaCAS Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266404, ChinaCAS Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266404, ChinaArtificial ocean alkalinization (AOA) is one of the most promising marine carbon dioxide removal technologies, but its influence on marine carbon chemistry remains unclear. We applied data from the Sixth Coupled Model Intercomparison Project (CMIP6) to characterize the temporal and spatial variabilities of future marine carbon chemistry under the implementation of AOA. Our study shows that the marine carbon system varied significantly under the implementation of AOA, but some specific effects may be masked by the forcing of the high carbon emission scenario SSP5-8.5. Based on the CMIP6 protocol, which added 0.14 Pmol of alkalinity into the ocean annually, AOA promoted an increase in DIC, delayed the rise in <i>p</i>CO<sub>2</sub>, and mitigated declines in pH and Ω, respectively. The temperate oceans in both hemispheres were the most significantly impacted basins, whereas the Southern Ocean was the least affected. During this century, the oceanic carbon sink is expected to intensify rapidly until around the year 2080, and then gradually weaken. The implementation of AOA merely changed the relative strength of the oceanic sink, rather than its overall variation pattern. Furthermore, in the deep ocean, the effect of AOA was present but quite limited in mitigating ocean acidification.https://www.mdpi.com/2673-1924/6/2/29carbon chemistryartificial ocean alkalinizationearth system modelCMIP6
spellingShingle Baoxiao Qu
Jinming Song
Xuegang Li
Huamao Yuan
Liqin Duan
Future Changes in Carbon Chemistry Under the Implementation of Artificial Ocean Alkalinization Based on CMIP6 Simulations
Oceans
carbon chemistry
artificial ocean alkalinization
earth system model
CMIP6
title Future Changes in Carbon Chemistry Under the Implementation of Artificial Ocean Alkalinization Based on CMIP6 Simulations
title_full Future Changes in Carbon Chemistry Under the Implementation of Artificial Ocean Alkalinization Based on CMIP6 Simulations
title_fullStr Future Changes in Carbon Chemistry Under the Implementation of Artificial Ocean Alkalinization Based on CMIP6 Simulations
title_full_unstemmed Future Changes in Carbon Chemistry Under the Implementation of Artificial Ocean Alkalinization Based on CMIP6 Simulations
title_short Future Changes in Carbon Chemistry Under the Implementation of Artificial Ocean Alkalinization Based on CMIP6 Simulations
title_sort future changes in carbon chemistry under the implementation of artificial ocean alkalinization based on cmip6 simulations
topic carbon chemistry
artificial ocean alkalinization
earth system model
CMIP6
url https://www.mdpi.com/2673-1924/6/2/29
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AT xuegangli futurechangesincarbonchemistryundertheimplementationofartificialoceanalkalinizationbasedoncmip6simulations
AT huamaoyuan futurechangesincarbonchemistryundertheimplementationofartificialoceanalkalinizationbasedoncmip6simulations
AT liqinduan futurechangesincarbonchemistryundertheimplementationofartificialoceanalkalinizationbasedoncmip6simulations