Profiling and cheminformatics bioprospection of curcurbitacin I and momordin Ic from Momordica balsamina on α-amylase and α-glucosidase

Momordica spp. has been traditionally used to manage type 2 diabetes mellitus, but the mechanisms and metabolites remain unclear. This study evaluated the inhibitory potential of Momordica balsamina extracts on α-amylase and α-glucosidase in vitro, identifying cucurbitacin I and momordin Ic via high...

Full description

Saved in:
Bibliographic Details
Main Authors: Viruska Jaichand, Adedayo Ayodeji Lanrewaju, Himansu Baijnath, Saheed Sabiu, Viresh Mohanlall
Format: Article
Language:English
Published: Taylor & Francis Group 2025-12-01
Series:Journal of Enzyme Inhibition and Medicinal Chemistry
Subjects:
Online Access:https://www.tandfonline.com/doi/10.1080/14756366.2025.2492706
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850171592229781504
author Viruska Jaichand
Adedayo Ayodeji Lanrewaju
Himansu Baijnath
Saheed Sabiu
Viresh Mohanlall
author_facet Viruska Jaichand
Adedayo Ayodeji Lanrewaju
Himansu Baijnath
Saheed Sabiu
Viresh Mohanlall
author_sort Viruska Jaichand
collection DOAJ
description Momordica spp. has been traditionally used to manage type 2 diabetes mellitus, but the mechanisms and metabolites remain unclear. This study evaluated the inhibitory potential of Momordica balsamina extracts on α-amylase and α-glucosidase in vitro, identifying cucurbitacin I and momordin Ic via high-performance liquid chromatography-photo diode array, and their inhibitory potential in silico. Ethyl acetate seed extract (14.46 µg/ml) and hexane fruit flesh extract (16.79 µg/ml) exhibited lower IC50 values against α-amylase and α-glucosidase, respectively, compared to acarbose (reference standard). Comparatively, momordin Ic concentrations (36.57–605.98 µg/ml) were higher than cucurbitacin I (17.08–44.34 µg/ml). A 140 ns simulation showed that cucurbitacin I (−63.06 kcal/mol) and momordin Ic (−66.53 kcal/mol) exhibited stronger binding to α-amylase than acarbose (−36.46 kcal/mol), whereas cucurbitacin I (−38.08 kcal/mol) and momordin Ic (−54.87 kcal/mol) displayed weaker binding to α-glucosidase, relative to acarbose (−63.73 kcal/mol). Generally, momordin Ic demonstrated better thermodynamic properties, hence further in vitro and in vivo studies are needed to validate their antidiabetic potential.
format Article
id doaj-art-6f0d5e1cb6be4f928a8bc626425f3341
institution OA Journals
issn 1475-6366
1475-6374
language English
publishDate 2025-12-01
publisher Taylor & Francis Group
record_format Article
series Journal of Enzyme Inhibition and Medicinal Chemistry
spelling doaj-art-6f0d5e1cb6be4f928a8bc626425f33412025-08-20T02:20:15ZengTaylor & Francis GroupJournal of Enzyme Inhibition and Medicinal Chemistry1475-63661475-63742025-12-0140110.1080/14756366.2025.2492706Profiling and cheminformatics bioprospection of curcurbitacin I and momordin Ic from Momordica balsamina on α-amylase and α-glucosidaseViruska Jaichand0Adedayo Ayodeji Lanrewaju1Himansu Baijnath2Saheed Sabiu3Viresh Mohanlall4Department of Biotechnology and Food Science, Faculty of Applied Science, Durban University of Technology, Durban, South AfricaDepartment of Biotechnology and Food Science, Faculty of Applied Science, Durban University of Technology, Durban, South AfricaWard Herbarium, School of Life Sciences, University of KwaZulu-Natal, Durban, South AfricaDepartment of Biotechnology and Food Science, Faculty of Applied Science, Durban University of Technology, Durban, South AfricaDepartment of Biotechnology and Food Science, Faculty of Applied Science, Durban University of Technology, Durban, South AfricaMomordica spp. has been traditionally used to manage type 2 diabetes mellitus, but the mechanisms and metabolites remain unclear. This study evaluated the inhibitory potential of Momordica balsamina extracts on α-amylase and α-glucosidase in vitro, identifying cucurbitacin I and momordin Ic via high-performance liquid chromatography-photo diode array, and their inhibitory potential in silico. Ethyl acetate seed extract (14.46 µg/ml) and hexane fruit flesh extract (16.79 µg/ml) exhibited lower IC50 values against α-amylase and α-glucosidase, respectively, compared to acarbose (reference standard). Comparatively, momordin Ic concentrations (36.57–605.98 µg/ml) were higher than cucurbitacin I (17.08–44.34 µg/ml). A 140 ns simulation showed that cucurbitacin I (−63.06 kcal/mol) and momordin Ic (−66.53 kcal/mol) exhibited stronger binding to α-amylase than acarbose (−36.46 kcal/mol), whereas cucurbitacin I (−38.08 kcal/mol) and momordin Ic (−54.87 kcal/mol) displayed weaker binding to α-glucosidase, relative to acarbose (−63.73 kcal/mol). Generally, momordin Ic demonstrated better thermodynamic properties, hence further in vitro and in vivo studies are needed to validate their antidiabetic potential.https://www.tandfonline.com/doi/10.1080/14756366.2025.2492706Binding free energycucurbitacin IMomordica balsaminamomordin Ictype 2 diabetes mellitus
spellingShingle Viruska Jaichand
Adedayo Ayodeji Lanrewaju
Himansu Baijnath
Saheed Sabiu
Viresh Mohanlall
Profiling and cheminformatics bioprospection of curcurbitacin I and momordin Ic from Momordica balsamina on α-amylase and α-glucosidase
Journal of Enzyme Inhibition and Medicinal Chemistry
Binding free energy
cucurbitacin I
Momordica balsamina
momordin Ic
type 2 diabetes mellitus
title Profiling and cheminformatics bioprospection of curcurbitacin I and momordin Ic from Momordica balsamina on α-amylase and α-glucosidase
title_full Profiling and cheminformatics bioprospection of curcurbitacin I and momordin Ic from Momordica balsamina on α-amylase and α-glucosidase
title_fullStr Profiling and cheminformatics bioprospection of curcurbitacin I and momordin Ic from Momordica balsamina on α-amylase and α-glucosidase
title_full_unstemmed Profiling and cheminformatics bioprospection of curcurbitacin I and momordin Ic from Momordica balsamina on α-amylase and α-glucosidase
title_short Profiling and cheminformatics bioprospection of curcurbitacin I and momordin Ic from Momordica balsamina on α-amylase and α-glucosidase
title_sort profiling and cheminformatics bioprospection of curcurbitacin i and momordin ic from momordica balsamina on α amylase and α glucosidase
topic Binding free energy
cucurbitacin I
Momordica balsamina
momordin Ic
type 2 diabetes mellitus
url https://www.tandfonline.com/doi/10.1080/14756366.2025.2492706
work_keys_str_mv AT viruskajaichand profilingandcheminformaticsbioprospectionofcurcurbitaciniandmomordinicfrommomordicabalsaminaonaamylaseandaglucosidase
AT adedayoayodejilanrewaju profilingandcheminformaticsbioprospectionofcurcurbitaciniandmomordinicfrommomordicabalsaminaonaamylaseandaglucosidase
AT himansubaijnath profilingandcheminformaticsbioprospectionofcurcurbitaciniandmomordinicfrommomordicabalsaminaonaamylaseandaglucosidase
AT saheedsabiu profilingandcheminformaticsbioprospectionofcurcurbitaciniandmomordinicfrommomordicabalsaminaonaamylaseandaglucosidase
AT vireshmohanlall profilingandcheminformaticsbioprospectionofcurcurbitaciniandmomordinicfrommomordicabalsaminaonaamylaseandaglucosidase