Interstitial tuning of Y3+ sites with Li+ sensitized improved Tb3+emission for WLED application

A series of wide-ranging single phase YPO4:xTb3+ phosphor was prepared by wet chemical route. In order to maximise the use of YPO4:Tb3+ nanoparticles in WLED, this work used Li+ sensitization to interstitially modify the particles' photoluminescence intensity. The prepared nanoparticles are cha...

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Main Authors: Davidson Pyngrope, Phlegon Syndai, Amresh I Prasad
Format: Article
Language:English
Published: Elsevier 2024-01-01
Series:Next Nanotechnology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2949829524000408
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author Davidson Pyngrope
Phlegon Syndai
Amresh I Prasad
author_facet Davidson Pyngrope
Phlegon Syndai
Amresh I Prasad
author_sort Davidson Pyngrope
collection DOAJ
description A series of wide-ranging single phase YPO4:xTb3+ phosphor was prepared by wet chemical route. In order to maximise the use of YPO4:Tb3+ nanoparticles in WLED, this work used Li+ sensitization to interstitially modify the particles' photoluminescence intensity. The prepared nanoparticles are characterized using X-Ray diffraction, FT-IR, TEM and Photoluminescence. The annealing effect on the particle size, morphology and its luminescence intensities are studied. This increased crystallinity led to a rise in the photoluminescence intensity of the nanoparticles. YPO4:Tb3+ nanoparticles' excitation and emission spectra were shown by photoluminescence investigations. Optical absorption and emission spectra confirmed all peaks associated to various transitions of the Tb3+ ions. Because of the increased crystallinity and decreased water content, the emission intensity rose with the annealing temperature. Li+ co-doping increased the emission intensity even more; where the emission intensity showed seven times. The results emphasise the significance of Li+ sensitization and annealing temperature in adjusting the luminous properties for possible uses in WLED and other display systems
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spelling doaj-art-6e7933cfdbf749f4a1b60525452ea1fc2025-08-20T02:20:40ZengElsevierNext Nanotechnology2949-82952024-01-01610007910.1016/j.nxnano.2024.100079Interstitial tuning of Y3+ sites with Li+ sensitized improved Tb3+emission for WLED applicationDavidson Pyngrope0Phlegon Syndai1Amresh I Prasad2Corresponding author.; Department of Nanotechnology, North-Eastern Hill University, Shillong, Meghalaya 793022, IndiaDepartment of Nanotechnology, North-Eastern Hill University, Shillong, Meghalaya 793022, IndiaDepartment of Nanotechnology, North-Eastern Hill University, Shillong, Meghalaya 793022, IndiaA series of wide-ranging single phase YPO4:xTb3+ phosphor was prepared by wet chemical route. In order to maximise the use of YPO4:Tb3+ nanoparticles in WLED, this work used Li+ sensitization to interstitially modify the particles' photoluminescence intensity. The prepared nanoparticles are characterized using X-Ray diffraction, FT-IR, TEM and Photoluminescence. The annealing effect on the particle size, morphology and its luminescence intensities are studied. This increased crystallinity led to a rise in the photoluminescence intensity of the nanoparticles. YPO4:Tb3+ nanoparticles' excitation and emission spectra were shown by photoluminescence investigations. Optical absorption and emission spectra confirmed all peaks associated to various transitions of the Tb3+ ions. Because of the increased crystallinity and decreased water content, the emission intensity rose with the annealing temperature. Li+ co-doping increased the emission intensity even more; where the emission intensity showed seven times. The results emphasise the significance of Li+ sensitization and annealing temperature in adjusting the luminous properties for possible uses in WLED and other display systemshttp://www.sciencedirect.com/science/article/pii/S2949829524000408Interstitial tuningPhotoluminescenceCrystal structure
spellingShingle Davidson Pyngrope
Phlegon Syndai
Amresh I Prasad
Interstitial tuning of Y3+ sites with Li+ sensitized improved Tb3+emission for WLED application
Next Nanotechnology
Interstitial tuning
Photoluminescence
Crystal structure
title Interstitial tuning of Y3+ sites with Li+ sensitized improved Tb3+emission for WLED application
title_full Interstitial tuning of Y3+ sites with Li+ sensitized improved Tb3+emission for WLED application
title_fullStr Interstitial tuning of Y3+ sites with Li+ sensitized improved Tb3+emission for WLED application
title_full_unstemmed Interstitial tuning of Y3+ sites with Li+ sensitized improved Tb3+emission for WLED application
title_short Interstitial tuning of Y3+ sites with Li+ sensitized improved Tb3+emission for WLED application
title_sort interstitial tuning of y3 sites with li sensitized improved tb3 emission for wled application
topic Interstitial tuning
Photoluminescence
Crystal structure
url http://www.sciencedirect.com/science/article/pii/S2949829524000408
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