Importance of a role of (EuN3)2+ complex generated in the Eu3+/N3-/H2O2 system studied by the chemiluminescent method
Chemiluminescence has been studied in the systems containing hydrogen peroxide H2O2 and Eu3+ and N3- ions. Ultraweak emission lasting for a few tens of hours has been observed. The dominant bands in the spectral distribution of the chemiluminescence are those of λ=594 and 620 nm,which proves that ex...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2001-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://dx.doi.org/10.1155/S1110662X01000265 |
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| Summary: | Chemiluminescence has been studied in the systems containing hydrogen peroxide H2O2 and Eu3+ and N3- ions. Ultraweak emission lasting for a few tens of hours has been observed. The dominant bands
in the spectral distribution of the chemiluminescence are those of λ=594 and 620 nm,which proves that
excited Eu3+ ions are the only emitters in the system. As follows from measurements of chemiluminescence
intensity for different pH of the solution and concentration of F- ions,introduced as ligands competitive to
N3- ,it is in direct proportion to the concentration of the (EuN3)2+ complex forming in the solution. |
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| ISSN: | 1110-662X |