Annealing time effect on the optical properties of Zn(O,OH,S) films onto ZnO seed layer under un-vacuum ambient

In this study, Zn (O,OH,S) films were synthesized onto ZnO seed layers by chemical bath deposition, which were annealed at 500 °C. The differences of structural, morphological and detailed optical properties of the films were investigated depending on the annealing time (between 30 min. and 90 min.)...

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Main Authors: Fatma Özütok, Emin Yakar
Format: Article
Language:English
Published: Sakarya University 2018-12-01
Series:Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
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Online Access:https://dergipark.org.tr/tr/download/article-file/463687
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author Fatma Özütok
Emin Yakar
author_facet Fatma Özütok
Emin Yakar
author_sort Fatma Özütok
collection DOAJ
description In this study, Zn (O,OH,S) films were synthesized onto ZnO seed layers by chemical bath deposition, which were annealed at 500 °C. The differences of structural, morphological and detailed optical properties of the films were investigated depending on the annealing time (between 30 min. and 90 min.). While samples of 30.min and 90 min. showed decomposed structures, sample of 60 min. showed different dimensions of nano-flower structures. Although all films had ZnO-hexzagonal crystal structure, the most obvious ZnS-related peaks were observed in the sample of 90 min. Optical absorption edge was shifted at 362 nm from Uv-Vis spectroscopy. Although ZnO, Zn(OH)2 vibration related peaks were so sharp, ZnS vibration peaks were so weak for all samples from FTIR. The PL intensities were differential depending on the annealing time but defect state-corresponding peaks were similar for each films.
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publishDate 2018-12-01
publisher Sakarya University
record_format Article
series Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
spelling doaj-art-6e151d1e97564c65a54d1408d6651da52024-12-23T07:59:09ZengSakarya UniversitySakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi2147-835X2018-12-012261704171010.16984/saufenbilder.34975828Annealing time effect on the optical properties of Zn(O,OH,S) films onto ZnO seed layer under un-vacuum ambientFatma Özütok0Emin YakarÇANAKKALE ONSEKİZ MART ÜNİVERSİTESİIn this study, Zn (O,OH,S) films were synthesized onto ZnO seed layers by chemical bath deposition, which were annealed at 500 °C. The differences of structural, morphological and detailed optical properties of the films were investigated depending on the annealing time (between 30 min. and 90 min.). While samples of 30.min and 90 min. showed decomposed structures, sample of 60 min. showed different dimensions of nano-flower structures. Although all films had ZnO-hexzagonal crystal structure, the most obvious ZnS-related peaks were observed in the sample of 90 min. Optical absorption edge was shifted at 362 nm from Uv-Vis spectroscopy. Although ZnO, Zn(OH)2 vibration related peaks were so sharp, ZnS vibration peaks were so weak for all samples from FTIR. The PL intensities were differential depending on the annealing time but defect state-corresponding peaks were similar for each films.https://dergipark.org.tr/tr/download/article-file/463687zno seed layerphotoluminescence spectroscopyftirfilm characterizationzn(oohs) filmzno seed layerphotoluminescence spectroscopyftir
spellingShingle Fatma Özütok
Emin Yakar
Annealing time effect on the optical properties of Zn(O,OH,S) films onto ZnO seed layer under un-vacuum ambient
Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
zno seed layer
photoluminescence spectroscopy
ftir
film characterization
zn(o
oh
s) film
zno seed layer
photoluminescence spectroscopy
ftir
title Annealing time effect on the optical properties of Zn(O,OH,S) films onto ZnO seed layer under un-vacuum ambient
title_full Annealing time effect on the optical properties of Zn(O,OH,S) films onto ZnO seed layer under un-vacuum ambient
title_fullStr Annealing time effect on the optical properties of Zn(O,OH,S) films onto ZnO seed layer under un-vacuum ambient
title_full_unstemmed Annealing time effect on the optical properties of Zn(O,OH,S) films onto ZnO seed layer under un-vacuum ambient
title_short Annealing time effect on the optical properties of Zn(O,OH,S) films onto ZnO seed layer under un-vacuum ambient
title_sort annealing time effect on the optical properties of zn o oh s films onto zno seed layer under un vacuum ambient
topic zno seed layer
photoluminescence spectroscopy
ftir
film characterization
zn(o
oh
s) film
zno seed layer
photoluminescence spectroscopy
ftir
url https://dergipark.org.tr/tr/download/article-file/463687
work_keys_str_mv AT fatmaozutok annealingtimeeffectontheopticalpropertiesofznoohsfilmsontoznoseedlayerunderunvacuumambient
AT eminyakar annealingtimeeffectontheopticalpropertiesofznoohsfilmsontoznoseedlayerunderunvacuumambient