Three-Dimensional Supramolecular Network Directed by Intermolecular Interactions in [Pb2(dmp)2(hfacac)4]
To investigate the interactions between noncovalent bond donor and acceptor giving rise to three dimensional networks, compound [Pb2(dmp)2(hfacac)2] (1) (dmp = 2,9-dimethyl-1,10-henanthroline and Hhfacac = hexafluoroacetylacetonate) has been prepared and characterized by elemental analysis, IR, 1H N...
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| Format: | Article |
| Language: | English |
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Wiley
2009-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2009/673828 |
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| author | Farzin Marandi Lotfali Saghatforoush Hossein Farzaneh |
| author_facet | Farzin Marandi Lotfali Saghatforoush Hossein Farzaneh |
| author_sort | Farzin Marandi |
| collection | DOAJ |
| description | To investigate the interactions between noncovalent bond donor and acceptor giving rise to three dimensional networks, compound [Pb2(dmp)2(hfacac)2] (1) (dmp = 2,9-dimethyl-1,10-henanthroline and Hhfacac = hexafluoroacetylacetonate) has been prepared and characterized by elemental analysis, IR, 1H NMR, and 13C NMR spectroscopy and its crystal structures was investigated. The single crystal structure show the coordination number of Pb(II) to be eight with two N-donor atoms from a “dmp” ligand and six O-donors from the anionic ligands. The supramolecular structure of 1 is realized by weak directional C–H∙∙∙O–C, C–F∙∙∙F–C and π–π stacking interactions. |
| format | Article |
| id | doaj-art-6dfec18932994337ac06024fcbc98ca1 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2009-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-6dfec18932994337ac06024fcbc98ca12025-08-20T03:33:50ZengWileyE-Journal of Chemistry0973-49452090-98102009-01-01641085109010.1155/2009/673828Three-Dimensional Supramolecular Network Directed by Intermolecular Interactions in [Pb2(dmp)2(hfacac)4]Farzin Marandi0Lotfali Saghatforoush1Hossein Farzaneh2Department of Science, Payame Noor University (PNU), Zanjan, IranDepartment of Science, Payame Noor University (PNU), Khoy, IranDepartment of Science, Zanjan University, Zanjan, IranTo investigate the interactions between noncovalent bond donor and acceptor giving rise to three dimensional networks, compound [Pb2(dmp)2(hfacac)2] (1) (dmp = 2,9-dimethyl-1,10-henanthroline and Hhfacac = hexafluoroacetylacetonate) has been prepared and characterized by elemental analysis, IR, 1H NMR, and 13C NMR spectroscopy and its crystal structures was investigated. The single crystal structure show the coordination number of Pb(II) to be eight with two N-donor atoms from a “dmp” ligand and six O-donors from the anionic ligands. The supramolecular structure of 1 is realized by weak directional C–H∙∙∙O–C, C–F∙∙∙F–C and π–π stacking interactions.http://dx.doi.org/10.1155/2009/673828 |
| spellingShingle | Farzin Marandi Lotfali Saghatforoush Hossein Farzaneh Three-Dimensional Supramolecular Network Directed by Intermolecular Interactions in [Pb2(dmp)2(hfacac)4] E-Journal of Chemistry |
| title | Three-Dimensional Supramolecular Network Directed by Intermolecular Interactions in [Pb2(dmp)2(hfacac)4] |
| title_full | Three-Dimensional Supramolecular Network Directed by Intermolecular Interactions in [Pb2(dmp)2(hfacac)4] |
| title_fullStr | Three-Dimensional Supramolecular Network Directed by Intermolecular Interactions in [Pb2(dmp)2(hfacac)4] |
| title_full_unstemmed | Three-Dimensional Supramolecular Network Directed by Intermolecular Interactions in [Pb2(dmp)2(hfacac)4] |
| title_short | Three-Dimensional Supramolecular Network Directed by Intermolecular Interactions in [Pb2(dmp)2(hfacac)4] |
| title_sort | three dimensional supramolecular network directed by intermolecular interactions in pb2 dmp 2 hfacac 4 |
| url | http://dx.doi.org/10.1155/2009/673828 |
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