Selective sonochemical post-synthesis modification of LTA zeolite with zinc species.
LTA zeolite is known for its straightforward synthesis and well-defined structure, composed of α and β cages. This structure offers a versatile platform for hosting molecules of varying sizes. In the sodic form (NaA), the Na⁺ ions are located within these cages' cation exchange sites. When subs...
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| Format: | Article |
| Language: | English |
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Public Library of Science (PLoS)
2025-01-01
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| Series: | PLoS ONE |
| Online Access: | https://doi.org/10.1371/journal.pone.0324997 |
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| author | Jesús Isaías De León-Ramírez Víctor Alfredo Reyes Villegas Sergio Pérez-Sicairos José Román Chávez Méndez Fernando Chávez-Rivas Rosario Isidro Yocupicio-Gaxiola Vitalii Petranovskii |
| author_facet | Jesús Isaías De León-Ramírez Víctor Alfredo Reyes Villegas Sergio Pérez-Sicairos José Román Chávez Méndez Fernando Chávez-Rivas Rosario Isidro Yocupicio-Gaxiola Vitalii Petranovskii |
| author_sort | Jesús Isaías De León-Ramírez |
| collection | DOAJ |
| description | LTA zeolite is known for its straightforward synthesis and well-defined structure, composed of α and β cages. This structure offers a versatile platform for hosting molecules of varying sizes. In the sodic form (NaA), the Na⁺ ions are located within these cages' cation exchange sites. When substituted with zinc species, a precise tuning of pore size and properties can emerge. In this study, we employed an eco-friendly post-synthesis modification of a NaA zeolite with zinc species: ZnO, ZnO₂, and Zn(OH)₂ by a sono-assisted deposition method. This approach allowed a short deposition time (30 min), providing control over the desired Zn species incorporated into NaA zeolite. Equally, the facile selective integration of zinc species in the form of supported nanoparticles and Zn2+ in cation exchange sites modified the physicochemical properties of the material, including unique surface charge redistribution and pore architectures. These results highlight the potential of sono-assisted deposition as an alternative strategy for engineering advanced zeolitic materials, opening new avenues for innovative applications in catalysis, adsorption, and beyond. |
| format | Article |
| id | doaj-art-6df925922b184bdca44f34fc4a0661f5 |
| institution | Kabale University |
| issn | 1932-6203 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Public Library of Science (PLoS) |
| record_format | Article |
| series | PLoS ONE |
| spelling | doaj-art-6df925922b184bdca44f34fc4a0661f52025-08-20T03:32:20ZengPublic Library of Science (PLoS)PLoS ONE1932-62032025-01-01206e032499710.1371/journal.pone.0324997Selective sonochemical post-synthesis modification of LTA zeolite with zinc species.Jesús Isaías De León-RamírezVíctor Alfredo Reyes VillegasSergio Pérez-SicairosJosé Román Chávez MéndezFernando Chávez-RivasRosario Isidro Yocupicio-GaxiolaVitalii PetranovskiiLTA zeolite is known for its straightforward synthesis and well-defined structure, composed of α and β cages. This structure offers a versatile platform for hosting molecules of varying sizes. In the sodic form (NaA), the Na⁺ ions are located within these cages' cation exchange sites. When substituted with zinc species, a precise tuning of pore size and properties can emerge. In this study, we employed an eco-friendly post-synthesis modification of a NaA zeolite with zinc species: ZnO, ZnO₂, and Zn(OH)₂ by a sono-assisted deposition method. This approach allowed a short deposition time (30 min), providing control over the desired Zn species incorporated into NaA zeolite. Equally, the facile selective integration of zinc species in the form of supported nanoparticles and Zn2+ in cation exchange sites modified the physicochemical properties of the material, including unique surface charge redistribution and pore architectures. These results highlight the potential of sono-assisted deposition as an alternative strategy for engineering advanced zeolitic materials, opening new avenues for innovative applications in catalysis, adsorption, and beyond.https://doi.org/10.1371/journal.pone.0324997 |
| spellingShingle | Jesús Isaías De León-Ramírez Víctor Alfredo Reyes Villegas Sergio Pérez-Sicairos José Román Chávez Méndez Fernando Chávez-Rivas Rosario Isidro Yocupicio-Gaxiola Vitalii Petranovskii Selective sonochemical post-synthesis modification of LTA zeolite with zinc species. PLoS ONE |
| title | Selective sonochemical post-synthesis modification of LTA zeolite with zinc species. |
| title_full | Selective sonochemical post-synthesis modification of LTA zeolite with zinc species. |
| title_fullStr | Selective sonochemical post-synthesis modification of LTA zeolite with zinc species. |
| title_full_unstemmed | Selective sonochemical post-synthesis modification of LTA zeolite with zinc species. |
| title_short | Selective sonochemical post-synthesis modification of LTA zeolite with zinc species. |
| title_sort | selective sonochemical post synthesis modification of lta zeolite with zinc species |
| url | https://doi.org/10.1371/journal.pone.0324997 |
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