Self-adaptable mechanical ceramic fibrous aerogels from prestressed topology and multistable constraints

Abstract Ceramic aerogels, widely used as thermal insulation materials, are renowned for their remarkable characteristics, including ultralight weight and ultralow thermal conductivity. However, their application is often limited by susceptibility to damage under repeated dynamic thermal shocks—a ch...

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Main Authors: Hongxing Wang, Longdi Cheng, Jianyong Yu, Yang Si
Format: Article
Language:English
Published: Nature Portfolio 2025-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-62164-4
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author Hongxing Wang
Longdi Cheng
Jianyong Yu
Yang Si
author_facet Hongxing Wang
Longdi Cheng
Jianyong Yu
Yang Si
author_sort Hongxing Wang
collection DOAJ
description Abstract Ceramic aerogels, widely used as thermal insulation materials, are renowned for their remarkable characteristics, including ultralight weight and ultralow thermal conductivity. However, their application is often limited by susceptibility to damage under repeated dynamic thermal shocks—a challenge that remains inadequately addressed. Herein, we present a multicomponent structural engineering approach that integrates ceramic nanofibers with traditional textile knitting topology to fabricate mechanically adaptable ceramic fibrous aerogels. Benefiting from the porous nanofibrous network and the synchronized motion of the prestressed knitted topological framework, which can be readily activated to accommodate deformation while efficiently dissipating energy, the resulting aerogels exhibit exceptional mechanical properties. Specifically, our aerogels demonstrate a high tensile strength of 356.6 kPa, a compressive strength of 109.1 kPa, and remarkable mechanical adaptability in response to external stimuli. Moreover, these aerogels achieve a high fracture energy of 117.26 kJ m-3 and display exceptional recovery from deformation after 1000 cycles of compression or 500 cycles of tension. This study elucidates the structural-property interdependence in aerogel materials through multiscale analysis and advances the rational design of the next-generation impact-absorbing systems and metamaterials.
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spelling doaj-art-6df2f5dfe8d945c096b5effe4a6810522025-08-20T03:46:17ZengNature PortfolioNature Communications2041-17232025-07-0116111210.1038/s41467-025-62164-4Self-adaptable mechanical ceramic fibrous aerogels from prestressed topology and multistable constraintsHongxing Wang0Longdi Cheng1Jianyong Yu2Yang Si3State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Textiles, Donghua UniversityState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Textiles, Donghua UniversityState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Textiles, Donghua UniversityState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Textiles, Donghua UniversityAbstract Ceramic aerogels, widely used as thermal insulation materials, are renowned for their remarkable characteristics, including ultralight weight and ultralow thermal conductivity. However, their application is often limited by susceptibility to damage under repeated dynamic thermal shocks—a challenge that remains inadequately addressed. Herein, we present a multicomponent structural engineering approach that integrates ceramic nanofibers with traditional textile knitting topology to fabricate mechanically adaptable ceramic fibrous aerogels. Benefiting from the porous nanofibrous network and the synchronized motion of the prestressed knitted topological framework, which can be readily activated to accommodate deformation while efficiently dissipating energy, the resulting aerogels exhibit exceptional mechanical properties. Specifically, our aerogels demonstrate a high tensile strength of 356.6 kPa, a compressive strength of 109.1 kPa, and remarkable mechanical adaptability in response to external stimuli. Moreover, these aerogels achieve a high fracture energy of 117.26 kJ m-3 and display exceptional recovery from deformation after 1000 cycles of compression or 500 cycles of tension. This study elucidates the structural-property interdependence in aerogel materials through multiscale analysis and advances the rational design of the next-generation impact-absorbing systems and metamaterials.https://doi.org/10.1038/s41467-025-62164-4
spellingShingle Hongxing Wang
Longdi Cheng
Jianyong Yu
Yang Si
Self-adaptable mechanical ceramic fibrous aerogels from prestressed topology and multistable constraints
Nature Communications
title Self-adaptable mechanical ceramic fibrous aerogels from prestressed topology and multistable constraints
title_full Self-adaptable mechanical ceramic fibrous aerogels from prestressed topology and multistable constraints
title_fullStr Self-adaptable mechanical ceramic fibrous aerogels from prestressed topology and multistable constraints
title_full_unstemmed Self-adaptable mechanical ceramic fibrous aerogels from prestressed topology and multistable constraints
title_short Self-adaptable mechanical ceramic fibrous aerogels from prestressed topology and multistable constraints
title_sort self adaptable mechanical ceramic fibrous aerogels from prestressed topology and multistable constraints
url https://doi.org/10.1038/s41467-025-62164-4
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AT jianyongyu selfadaptablemechanicalceramicfibrousaerogelsfromprestressedtopologyandmultistableconstraints
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