Effect of Impeller Agitation on Preparation of Tetra-n-Butyl Ammonium Bromide Semiclathrate Hydrate Slurries

The slurries-containing tetra-n-butyl ammonium bromide (TBAB) solution and its semiclathrate hydrate have attracted a lot of interest as latent heat transport media. These hydrate slurries contain some microparticles of crystal, and the size and shape of these hydrate particles could affect the mobi...

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Main Authors: Shunsuke Hashimoto, Hiroyuki Ito, Kazunari Ohgaki, Yoshiro Inoue
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Chemical Engineering
Online Access:http://dx.doi.org/10.1155/2012/856120
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author Shunsuke Hashimoto
Hiroyuki Ito
Kazunari Ohgaki
Yoshiro Inoue
author_facet Shunsuke Hashimoto
Hiroyuki Ito
Kazunari Ohgaki
Yoshiro Inoue
author_sort Shunsuke Hashimoto
collection DOAJ
description The slurries-containing tetra-n-butyl ammonium bromide (TBAB) solution and its semiclathrate hydrate have attracted a lot of interest as latent heat transport media. These hydrate slurries contain some microparticles of crystal, and the size and shape of these hydrate particles could affect the mobility of slurries. Hence, it is essential to investigate the efficient hydrate-slurry preparation methods and the effect of hydrate particles on the fluid property of slurries for the application to latent heat transport media. In the present study, the effect of agitation on particle size distribution and aggregation of particles was studied to prepare easily flowing TBAB hydrate slurries that were suitable for fluid transport. First of all, the effects of impeller rotational speed and impeller type on the particle size and frequency of aggregation were investigated. The results suggested that the particle size distribution and the frequency of particle aggregation are strongly affected by the intensity of shear rate and its uniformity, which was controllable with impeller type and its rotation speed.
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institution Kabale University
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publishDate 2012-01-01
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spelling doaj-art-6dd2debf2cd741aa9e962338da7f83ae2025-02-03T05:47:22ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782012-01-01201210.1155/2012/856120856120Effect of Impeller Agitation on Preparation of Tetra-n-Butyl Ammonium Bromide Semiclathrate Hydrate SlurriesShunsuke Hashimoto0Hiroyuki Ito1Kazunari Ohgaki2Yoshiro Inoue3Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, JapanDivision of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, JapanDivision of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, JapanDivision of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, JapanThe slurries-containing tetra-n-butyl ammonium bromide (TBAB) solution and its semiclathrate hydrate have attracted a lot of interest as latent heat transport media. These hydrate slurries contain some microparticles of crystal, and the size and shape of these hydrate particles could affect the mobility of slurries. Hence, it is essential to investigate the efficient hydrate-slurry preparation methods and the effect of hydrate particles on the fluid property of slurries for the application to latent heat transport media. In the present study, the effect of agitation on particle size distribution and aggregation of particles was studied to prepare easily flowing TBAB hydrate slurries that were suitable for fluid transport. First of all, the effects of impeller rotational speed and impeller type on the particle size and frequency of aggregation were investigated. The results suggested that the particle size distribution and the frequency of particle aggregation are strongly affected by the intensity of shear rate and its uniformity, which was controllable with impeller type and its rotation speed.http://dx.doi.org/10.1155/2012/856120
spellingShingle Shunsuke Hashimoto
Hiroyuki Ito
Kazunari Ohgaki
Yoshiro Inoue
Effect of Impeller Agitation on Preparation of Tetra-n-Butyl Ammonium Bromide Semiclathrate Hydrate Slurries
International Journal of Chemical Engineering
title Effect of Impeller Agitation on Preparation of Tetra-n-Butyl Ammonium Bromide Semiclathrate Hydrate Slurries
title_full Effect of Impeller Agitation on Preparation of Tetra-n-Butyl Ammonium Bromide Semiclathrate Hydrate Slurries
title_fullStr Effect of Impeller Agitation on Preparation of Tetra-n-Butyl Ammonium Bromide Semiclathrate Hydrate Slurries
title_full_unstemmed Effect of Impeller Agitation on Preparation of Tetra-n-Butyl Ammonium Bromide Semiclathrate Hydrate Slurries
title_short Effect of Impeller Agitation on Preparation of Tetra-n-Butyl Ammonium Bromide Semiclathrate Hydrate Slurries
title_sort effect of impeller agitation on preparation of tetra n butyl ammonium bromide semiclathrate hydrate slurries
url http://dx.doi.org/10.1155/2012/856120
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AT kazunariohgaki effectofimpelleragitationonpreparationoftetranbutylammoniumbromidesemiclathratehydrateslurries
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