Upcycling fruit waste into high-performance 3D porous aerogel for dye removal: Experimental and density functional theory study

Durian shell waste was subjected to hydrothermal treatment followed by freeze-drying to create highly porous 3D aerogels, whose surfaces were judiciously functionalized to enable strong interactions with RhB dye. The aerogels were tailored to be superhydrophilic/oleophobic to enhance affinity to the...

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Main Authors: Muhammad Imran, Meilan Pan, Ashraful Islam, Jia Wei Chew
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Case Studies in Chemical and Environmental Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666016425001458
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author Muhammad Imran
Meilan Pan
Ashraful Islam
Jia Wei Chew
author_facet Muhammad Imran
Meilan Pan
Ashraful Islam
Jia Wei Chew
author_sort Muhammad Imran
collection DOAJ
description Durian shell waste was subjected to hydrothermal treatment followed by freeze-drying to create highly porous 3D aerogels, whose surfaces were judiciously functionalized to enable strong interactions with RhB dye. The aerogels were tailored to be superhydrophilic/oleophobic to enhance affinity to the dye, magnetic to enable directional mobility, and highly porous (up to 97 %) to augment the specific surface area. The durian shell waste – derived, surface-modified aerogels exhibited RhB removal efficiency of over 99 %. Density Functional Theory (DFT) simulations suggest that the strong adsorption of RhB onto the aerogel was governed by π–π interactions, hydrogen bonding, and electrostatic interactions.
format Article
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language English
publishDate 2025-06-01
publisher Elsevier
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series Case Studies in Chemical and Environmental Engineering
spelling doaj-art-6dcd18984e9e466aaaeb6acca66d5d082025-08-20T03:07:11ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642025-06-011110123810.1016/j.cscee.2025.101238Upcycling fruit waste into high-performance 3D porous aerogel for dye removal: Experimental and density functional theory studyMuhammad Imran0Meilan Pan1Ashraful Islam2Jia Wei Chew3Division of Chemical Engineering, Chalmers University of Technology, 412 96, Gothenburg, SwedenCollege of Environment, Zhejiang University of Technology, Zhejiang, 310014, ChinaState Key Laboratory of Environmental Aquatic Chemistry, Chinese Academy of Sciences, Haidian District, Beijing, 100085, ChinaDivision of Chemical Engineering, Chalmers University of Technology, 412 96, Gothenburg, Sweden; Corresponding author.Durian shell waste was subjected to hydrothermal treatment followed by freeze-drying to create highly porous 3D aerogels, whose surfaces were judiciously functionalized to enable strong interactions with RhB dye. The aerogels were tailored to be superhydrophilic/oleophobic to enhance affinity to the dye, magnetic to enable directional mobility, and highly porous (up to 97 %) to augment the specific surface area. The durian shell waste – derived, surface-modified aerogels exhibited RhB removal efficiency of over 99 %. Density Functional Theory (DFT) simulations suggest that the strong adsorption of RhB onto the aerogel was governed by π–π interactions, hydrogen bonding, and electrostatic interactions.http://www.sciencedirect.com/science/article/pii/S2666016425001458Eco-friendly 3D porous aerogelGreen synthesisDye sorptionBiomass wasteDFT simulation
spellingShingle Muhammad Imran
Meilan Pan
Ashraful Islam
Jia Wei Chew
Upcycling fruit waste into high-performance 3D porous aerogel for dye removal: Experimental and density functional theory study
Case Studies in Chemical and Environmental Engineering
Eco-friendly 3D porous aerogel
Green synthesis
Dye sorption
Biomass waste
DFT simulation
title Upcycling fruit waste into high-performance 3D porous aerogel for dye removal: Experimental and density functional theory study
title_full Upcycling fruit waste into high-performance 3D porous aerogel for dye removal: Experimental and density functional theory study
title_fullStr Upcycling fruit waste into high-performance 3D porous aerogel for dye removal: Experimental and density functional theory study
title_full_unstemmed Upcycling fruit waste into high-performance 3D porous aerogel for dye removal: Experimental and density functional theory study
title_short Upcycling fruit waste into high-performance 3D porous aerogel for dye removal: Experimental and density functional theory study
title_sort upcycling fruit waste into high performance 3d porous aerogel for dye removal experimental and density functional theory study
topic Eco-friendly 3D porous aerogel
Green synthesis
Dye sorption
Biomass waste
DFT simulation
url http://www.sciencedirect.com/science/article/pii/S2666016425001458
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