NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in th...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2018-03-01
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| Series: | Journal of Engineering Studies and Research |
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| Online Access: | https://jesr.ub.ro/index.php/1/article/view/66 |
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| author | DAME SEYE CHEIKH ABDOUL KHADIR DIOP ASSANE TOURE LIBASSE DIOP |
| author_facet | DAME SEYE CHEIKH ABDOUL KHADIR DIOP ASSANE TOURE LIBASSE DIOP |
| author_sort | DAME SEYE |
| collection | DOAJ |
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Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in the dysprosium one-. The maleate anion behaves as a bidentate, a monochelating, a bichelating or a tetradentate ligand while the formiate anion behaves as a monodentate ligand. For compounds containing a protonated amine or a methanol molecule, when hydrogen bonds are considered a supramolecular architecture may be obtained.
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| format | Article |
| id | doaj-art-6d72b5b5e4da4b8fbd3619b41fbda12f |
| institution | Kabale University |
| issn | 2068-7559 2344-4932 |
| language | English |
| publishDate | 2018-03-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj-art-6d72b5b5e4da4b8fbd3619b41fbda12f2025-02-09T11:37:57ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322018-03-01241NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDYDAME SEYE0 CHEIKH ABDOUL KHADIR DIOP1ASSANE TOURE 2LIBASSE DIOP3Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, Departement de Chimie, Laboratoire de Chimie Minerale et Analytique, Dakar, Senegal Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, Departement de Chimie, Laboratoire de Chimie Minerale et Analytique, Dakar, Senegal Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, Departement de Chimie, Laboratoire de Chimie Minerale et Analytique, Dakar, Senegal Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, Departement de Chimie, Laboratoire de Chimie Minerale et Analytique, Dakar, Senegal Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in the dysprosium one-. The maleate anion behaves as a bidentate, a monochelating, a bichelating or a tetradentate ligand while the formiate anion behaves as a monodentate ligand. For compounds containing a protonated amine or a methanol molecule, when hydrogen bonds are considered a supramolecular architecture may be obtained. https://jesr.ub.ro/index.php/1/article/view/66bidentatebichelatingdiscrete structuresupramolecular architecture |
| spellingShingle | DAME SEYE CHEIKH ABDOUL KHADIR DIOP ASSANE TOURE LIBASSE DIOP NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY Journal of Engineering Studies and Research bidentate bichelating discrete structure supramolecular architecture |
| title | NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY |
| title_full | NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY |
| title_fullStr | NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY |
| title_full_unstemmed | NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY |
| title_short | NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY |
| title_sort | new mx2 and m cl3 m cu zn m y dy pr x cl br maleato complexes and tetraphenylantimony formiate adduct synthesis and infrared study |
| topic | bidentate bichelating discrete structure supramolecular architecture |
| url | https://jesr.ub.ro/index.php/1/article/view/66 |
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