Mechanism of the Reaction of lron(I) Ions with Neutral 4-Octyne in the Gas Phase – Experimental Evidence for an irreversible β-Hydrogen Transfer
Experimental evidence is presented that β-hydrogen transfer, to generate bis-olefin Fe⊕ complexes from bare Fe⊕ and 2H-labeled 4-octynes is neither reversible nor associated with a primary kinetic isotope effect; unimolecular loss of labeled ethylene from the bis-olefin Fe⊕ complexes has, however,...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1986-10-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9756 |
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