Roles of doping in enhancing the performance of graphene/graphene-like semiconductors

Graphene is renowned for its excellent chemical, thermal, mechanical, electrical, and optical properties, which arise from its unique bonding structure. However, graphene is intrinsically a zero-bandgap material, limiting its development in the field of flexible nanoelectronics. To expand the range...

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Main Authors: Yuqi Zhou, Xinbo He, Mengyang Li
Format: Article
Language:English
Published: AIP Publishing LLC 2025-01-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/5.0248505
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author Yuqi Zhou
Xinbo He
Mengyang Li
author_facet Yuqi Zhou
Xinbo He
Mengyang Li
author_sort Yuqi Zhou
collection DOAJ
description Graphene is renowned for its excellent chemical, thermal, mechanical, electrical, and optical properties, which arise from its unique bonding structure. However, graphene is intrinsically a zero-bandgap material, limiting its development in the field of flexible nanoelectronics. To expand the range of applications for graphene in electronic devices, it is crucial to develop the strategies for inducing a bandgap. One of the most effective methods is chemical doping. Doping not only alters the electronic properties of graphene by modifying its inherent gapless nature but also engenders new materials with distinctive and potentially synergistic characteristics. Although there are many reviews on the doped graphene, there is a rare one to discuss the role of doping in enhancing the performance of graphene-based semiconductors. This paper reviews various doping types and their impacts on graphene, emphasizing the effects of boron (B) doping, nitrogen (N) doping, oxygen-group doping, other non-metallic atom or atomic pair doping, and metallic doping. We will further discuss how these dopants affect the geometry, electronic structure, and mechanical properties of graphene. It is expected to be meaningful for further understanding the nature of doped graphene and building new graphene-like structures.
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spelling doaj-art-6cc5548ad4724be0a041676eac3a8c3e2025-02-03T16:40:41ZengAIP Publishing LLCAIP Advances2158-32262025-01-01151010701010701-2010.1063/5.0248505Roles of doping in enhancing the performance of graphene/graphene-like semiconductorsYuqi Zhou0Xinbo He1Mengyang Li2School of Physics, Xidian University, Xi’an, Shaanxi 710071, ChinaSchool of Physics, Xidian University, Xi’an, Shaanxi 710071, ChinaSchool of Physics, Xidian University, Xi’an, Shaanxi 710071, ChinaGraphene is renowned for its excellent chemical, thermal, mechanical, electrical, and optical properties, which arise from its unique bonding structure. However, graphene is intrinsically a zero-bandgap material, limiting its development in the field of flexible nanoelectronics. To expand the range of applications for graphene in electronic devices, it is crucial to develop the strategies for inducing a bandgap. One of the most effective methods is chemical doping. Doping not only alters the electronic properties of graphene by modifying its inherent gapless nature but also engenders new materials with distinctive and potentially synergistic characteristics. Although there are many reviews on the doped graphene, there is a rare one to discuss the role of doping in enhancing the performance of graphene-based semiconductors. This paper reviews various doping types and their impacts on graphene, emphasizing the effects of boron (B) doping, nitrogen (N) doping, oxygen-group doping, other non-metallic atom or atomic pair doping, and metallic doping. We will further discuss how these dopants affect the geometry, electronic structure, and mechanical properties of graphene. It is expected to be meaningful for further understanding the nature of doped graphene and building new graphene-like structures.http://dx.doi.org/10.1063/5.0248505
spellingShingle Yuqi Zhou
Xinbo He
Mengyang Li
Roles of doping in enhancing the performance of graphene/graphene-like semiconductors
AIP Advances
title Roles of doping in enhancing the performance of graphene/graphene-like semiconductors
title_full Roles of doping in enhancing the performance of graphene/graphene-like semiconductors
title_fullStr Roles of doping in enhancing the performance of graphene/graphene-like semiconductors
title_full_unstemmed Roles of doping in enhancing the performance of graphene/graphene-like semiconductors
title_short Roles of doping in enhancing the performance of graphene/graphene-like semiconductors
title_sort roles of doping in enhancing the performance of graphene graphene like semiconductors
url http://dx.doi.org/10.1063/5.0248505
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