Relaxation Modeling of Unidirectional Carbon Fiber Reinforced Polymer Composites Before and After UV-C Exposure

Carbon fiber-reinforced polymers (CFRPs) are widely used in aerospace for their lightweight and high-performance characteristics. This study examines the long-term viscoelastic behavior of CFRP after UV-C exposure, simulating low Earth orbit conditions. The viscoelastic properties of the polymer wer...

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Bibliographic Details
Main Authors: Flavia Palmeri, Susanna Laurenzi
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Fibers
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Online Access:https://www.mdpi.com/2079-6439/12/12/110
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Summary:Carbon fiber-reinforced polymers (CFRPs) are widely used in aerospace for their lightweight and high-performance characteristics. This study examines the long-term viscoelastic behavior of CFRP after UV-C exposure, simulating low Earth orbit conditions. The viscoelastic properties of the polymer were evaluated using dynamic mechanical analysis and the time-temperature superposition principle on both unexposed and UV-C-exposed samples. After UV-C exposure, the polymer’s instantaneous modulus decreased by about <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>15</mn><mo>%</mo></mrow></semantics></math></inline-formula>. Over a 32-year period, the modulus of the unexposed resin is expected to degrade to approximately <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>25</mn><mo>%</mo></mrow></semantics></math></inline-formula> of its initial value, while the exposed resin drops to around <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>15</mn><mo>%</mo></mrow></semantics></math></inline-formula>. These experimental results were incorporated into finite element method models of a unidirectional CFRP representative volume element. The simulations showed that UV-C exposure caused only a slight reduction in the CFRP’s axial relaxation coefficient along the fiber’s axis, with no significant time-dependent degradation, as the fiber dominates this behavior. In contrast, the axial relaxation coefficient perpendicular to the fiber’s axis, as well as the off-diagonal and shear relaxation coefficients, showed more notable changes, with an approximate <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>10</mn><mo>%</mo></mrow></semantics></math></inline-formula> reduction in their initial values after UV-C exposure. Over 32 years, degradation became much more severe, with differences between the pre- and post-exposure coefficient values reaching up to nearly <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>60</mn><mo>%</mo></mrow></semantics></math></inline-formula>.
ISSN:2079-6439