Untargeted Chemical Profile, Antioxidant, and Enzyme Inhibition Activity of <i>Physalis angulata</i> L. from the Peruvian Amazon: A Contribution to the Validation of Its Pharmacological Potential

<i>Physalis angulata</i> is a plant of great value in traditional medicine known for its content of bioactive compounds, such as physalins and withanolides, which possess diverse biological activities. In this study, the chemical profile, antioxidant activity, and enzyme inhibition capac...

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Main Authors: Gabriel Vargas-Arana, Alfredo Torres-Benítez, José Erick Ortega-Valencia, Claudia Merino-Zegarra, Pilar Carranza-Rosales, Mario J. Simirgiotis
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Antioxidants
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Online Access:https://www.mdpi.com/2076-3921/14/3/246
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author Gabriel Vargas-Arana
Alfredo Torres-Benítez
José Erick Ortega-Valencia
Claudia Merino-Zegarra
Pilar Carranza-Rosales
Mario J. Simirgiotis
author_facet Gabriel Vargas-Arana
Alfredo Torres-Benítez
José Erick Ortega-Valencia
Claudia Merino-Zegarra
Pilar Carranza-Rosales
Mario J. Simirgiotis
author_sort Gabriel Vargas-Arana
collection DOAJ
description <i>Physalis angulata</i> is a plant of great value in traditional medicine known for its content of bioactive compounds, such as physalins and withanolides, which possess diverse biological activities. In this study, the chemical profile, antioxidant activity, and enzyme inhibition capacity of aqueous and ethanolic extracts obtained from the root, stem, leaves, calyx, and fruits of <i>P. angulata</i> collected in Peru were evaluated. A total of forty-two compounds were detected in the extracts using UHPLC-ESI-QTOF-MS analysis. In vitro analyses revealed that leaf extracts contained the highest concentration of phenolic compounds, while leaf and fruit extracts showed the best results in FRAP, DPPH, and ABTS antioxidant tests; on the other hand, inhibition of AChE, BChE, α-glucosidase, and α-amylase enzymes was variable, but calyx and fruit extracts showed higher effectiveness. In silico analyses indicated that the compounds physagulin A, physagulin F, physagulide P, physalin B, and withaminimin showed stable interactions and favorable binding affinities with the catalytic sites of the enzymes studied. These results confirm the pharmacological potential of extracts and compounds derived from different organs of <i>P. angulata</i>, suggesting their promising use in treating diseases related to the central nervous system and metabolic syndrome.
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spelling doaj-art-6c09ba7ade854b3e8e4a5ce15166fe1a2025-08-20T03:40:43ZengMDPI AGAntioxidants2076-39212025-02-0114324610.3390/antiox14030246Untargeted Chemical Profile, Antioxidant, and Enzyme Inhibition Activity of <i>Physalis angulata</i> L. from the Peruvian Amazon: A Contribution to the Validation of Its Pharmacological PotentialGabriel Vargas-Arana0Alfredo Torres-Benítez1José Erick Ortega-Valencia2Claudia Merino-Zegarra3Pilar Carranza-Rosales4Mario J. Simirgiotis5Laboratorio de Química de Productos Naturales, Instituto de Investigaciones de la Amazonía Peruana, Avenue Abelardo Quiñones Km 2.5, Iquitos 16001, PeruCarrera de Química y Farmacia, Facultad de Ciencias, Universidad San Sebastián, General Lagos 1163, Valdivia 5090000, ChileTecnológico Nacional de México, Instituto Tecnológico Superior de Xalapa, Sección 5ª Reserva Territorial S/N, Col. Santa Bárbara 91096, Veracruz, MexicoLaboratorio de Química de Productos Naturales, Instituto de Investigaciones de la Amazonía Peruana, Avenue Abelardo Quiñones Km 2.5, Iquitos 16001, PeruCentro de Investigación Biomédica del Noreste, Instituto Mexicano del Seguro Social, Monterrey 64720, Nuevo León, MexicoInstituto de Farmacia, Facultad de Ciencias, Universidad Austral de Chile, Campus Isla Teja, Valdivia 5090000, Chile<i>Physalis angulata</i> is a plant of great value in traditional medicine known for its content of bioactive compounds, such as physalins and withanolides, which possess diverse biological activities. In this study, the chemical profile, antioxidant activity, and enzyme inhibition capacity of aqueous and ethanolic extracts obtained from the root, stem, leaves, calyx, and fruits of <i>P. angulata</i> collected in Peru were evaluated. A total of forty-two compounds were detected in the extracts using UHPLC-ESI-QTOF-MS analysis. In vitro analyses revealed that leaf extracts contained the highest concentration of phenolic compounds, while leaf and fruit extracts showed the best results in FRAP, DPPH, and ABTS antioxidant tests; on the other hand, inhibition of AChE, BChE, α-glucosidase, and α-amylase enzymes was variable, but calyx and fruit extracts showed higher effectiveness. In silico analyses indicated that the compounds physagulin A, physagulin F, physagulide P, physalin B, and withaminimin showed stable interactions and favorable binding affinities with the catalytic sites of the enzymes studied. These results confirm the pharmacological potential of extracts and compounds derived from different organs of <i>P. angulata</i>, suggesting their promising use in treating diseases related to the central nervous system and metabolic syndrome.https://www.mdpi.com/2076-3921/14/3/246<i>Physalis angulata</i>extractsbioactive compoundsbiological activitytherapeutic properties
spellingShingle Gabriel Vargas-Arana
Alfredo Torres-Benítez
José Erick Ortega-Valencia
Claudia Merino-Zegarra
Pilar Carranza-Rosales
Mario J. Simirgiotis
Untargeted Chemical Profile, Antioxidant, and Enzyme Inhibition Activity of <i>Physalis angulata</i> L. from the Peruvian Amazon: A Contribution to the Validation of Its Pharmacological Potential
Antioxidants
<i>Physalis angulata</i>
extracts
bioactive compounds
biological activity
therapeutic properties
title Untargeted Chemical Profile, Antioxidant, and Enzyme Inhibition Activity of <i>Physalis angulata</i> L. from the Peruvian Amazon: A Contribution to the Validation of Its Pharmacological Potential
title_full Untargeted Chemical Profile, Antioxidant, and Enzyme Inhibition Activity of <i>Physalis angulata</i> L. from the Peruvian Amazon: A Contribution to the Validation of Its Pharmacological Potential
title_fullStr Untargeted Chemical Profile, Antioxidant, and Enzyme Inhibition Activity of <i>Physalis angulata</i> L. from the Peruvian Amazon: A Contribution to the Validation of Its Pharmacological Potential
title_full_unstemmed Untargeted Chemical Profile, Antioxidant, and Enzyme Inhibition Activity of <i>Physalis angulata</i> L. from the Peruvian Amazon: A Contribution to the Validation of Its Pharmacological Potential
title_short Untargeted Chemical Profile, Antioxidant, and Enzyme Inhibition Activity of <i>Physalis angulata</i> L. from the Peruvian Amazon: A Contribution to the Validation of Its Pharmacological Potential
title_sort untargeted chemical profile antioxidant and enzyme inhibition activity of i physalis angulata i l from the peruvian amazon a contribution to the validation of its pharmacological potential
topic <i>Physalis angulata</i>
extracts
bioactive compounds
biological activity
therapeutic properties
url https://www.mdpi.com/2076-3921/14/3/246
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