Electrochemical characteristics of lithium-sulfur pouch cells. Effect of compression force of electrode modules

The effect of the electrode sizes, the cell design and the compression force of the electrode modules on the impedance and discharge characteristics of lithium-sulfur cells was studied. It was shown that Swagelok and pouch cells with identical electrodes have different electrochemical characteristic...

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Main Authors: Kolosnitsyn, Dmitry Vladimirovich, Egorova, Nadezhda V., Ionina, Alena M., Kuzmina, Elena Vladimirovna, Karaseva, Elena Vladimirovna, Kolosnitsyn, Vladimir Sergeevich
Format: Article
Language:English
Published: Saratov State University 2025-02-01
Series:Электрохимическая энергетика
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Online Access:https://energetica.sgu.ru/sites/energetica.sgu.ru/files/text-pdf/2025/02/elektrohimicheskaya_energetika_2025_1-10-22.pdf
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author Kolosnitsyn, Dmitry Vladimirovich
Egorova, Nadezhda V.
Ionina, Alena M.
Kuzmina, Elena Vladimirovna
Karaseva, Elena Vladimirovna
Kolosnitsyn, Vladimir Sergeevich
author_facet Kolosnitsyn, Dmitry Vladimirovich
Egorova, Nadezhda V.
Ionina, Alena M.
Kuzmina, Elena Vladimirovna
Karaseva, Elena Vladimirovna
Kolosnitsyn, Vladimir Sergeevich
author_sort Kolosnitsyn, Dmitry Vladimirovich
collection DOAJ
description The effect of the electrode sizes, the cell design and the compression force of the electrode modules on the impedance and discharge characteristics of lithium-sulfur cells was studied. It was shown that Swagelok and pouch cells with identical electrodes have different electrochemical characteristics – charge transfer resistance, discharge capacity and cycling duration. It was found that the discharge capacity at the first cycle of Swagelok and pouch cells differs by 20% approximately. The capacity of pouch cells decreases faster during cycling. The cycling of pouch cells in a compressed state (similar to Swagelok cells) does not improve the electrochemical characteristics of pouch cells.
format Article
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institution DOAJ
issn 1608-4039
1680-9505
language English
publishDate 2025-02-01
publisher Saratov State University
record_format Article
series Электрохимическая энергетика
spelling doaj-art-6bf3d6a72902429a9dadeb07ef70ee552025-08-20T03:11:31ZengSaratov State UniversityЭлектрохимическая энергетика1608-40391680-95052025-02-01251102210.18500/1608-4039-2025-25-1-10-22Electrochemical characteristics of lithium-sulfur pouch cells. Effect of compression force of electrode modulesKolosnitsyn, Dmitry Vladimirovich0Egorova, Nadezhda V.1Ionina, Alena M.2Kuzmina, Elena Vladimirovna3Karaseva, Elena Vladimirovna4Kolosnitsyn, Vladimir Sergeevich5Ufa Institute of Chemistry of the Russian Academy of Sciences, 69 Prospect Oktyabrya, Ufa 450054, RussiaUfa Institute of Chemistry of the Russian Academy of Sciences, 69 Prospect Oktyabrya, Ufa 450054, RussiaUfa Institute of Chemistry of the Russian Academy of Sciences, 69 Prospect Oktyabrya, Ufa 450054, RussiaUfa Institute of Chemistry of the Russian Academy of Sciences, 69 Prospect Oktyabrya, Ufa 450054, RussiaInstitute of Organic Chemistry of the Ufa RAS Scientific Center, 71, Oktyabrya Ave, Ufa, 450054Institute of Organic Chemistry of the Ufa RAS Scientific Center, 71, Oktyabrya Ave, Ufa, 450054The effect of the electrode sizes, the cell design and the compression force of the electrode modules on the impedance and discharge characteristics of lithium-sulfur cells was studied. It was shown that Swagelok and pouch cells with identical electrodes have different electrochemical characteristics – charge transfer resistance, discharge capacity and cycling duration. It was found that the discharge capacity at the first cycle of Swagelok and pouch cells differs by 20% approximately. The capacity of pouch cells decreases faster during cycling. The cycling of pouch cells in a compressed state (similar to Swagelok cells) does not improve the electrochemical characteristics of pouch cells.https://energetica.sgu.ru/sites/energetica.sgu.ru/files/text-pdf/2025/02/elektrohimicheskaya_energetika_2025_1-10-22.pdflithium-sulfur cell (battery)pouch cellimpedancecyclingcoulombic efficiency
spellingShingle Kolosnitsyn, Dmitry Vladimirovich
Egorova, Nadezhda V.
Ionina, Alena M.
Kuzmina, Elena Vladimirovna
Karaseva, Elena Vladimirovna
Kolosnitsyn, Vladimir Sergeevich
Electrochemical characteristics of lithium-sulfur pouch cells. Effect of compression force of electrode modules
Электрохимическая энергетика
lithium-sulfur cell (battery)
pouch cell
impedance
cycling
coulombic efficiency
title Electrochemical characteristics of lithium-sulfur pouch cells. Effect of compression force of electrode modules
title_full Electrochemical characteristics of lithium-sulfur pouch cells. Effect of compression force of electrode modules
title_fullStr Electrochemical characteristics of lithium-sulfur pouch cells. Effect of compression force of electrode modules
title_full_unstemmed Electrochemical characteristics of lithium-sulfur pouch cells. Effect of compression force of electrode modules
title_short Electrochemical characteristics of lithium-sulfur pouch cells. Effect of compression force of electrode modules
title_sort electrochemical characteristics of lithium sulfur pouch cells effect of compression force of electrode modules
topic lithium-sulfur cell (battery)
pouch cell
impedance
cycling
coulombic efficiency
url https://energetica.sgu.ru/sites/energetica.sgu.ru/files/text-pdf/2025/02/elektrohimicheskaya_energetika_2025_1-10-22.pdf
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