The effect of crosslink density on the cold crystallization behavior of polybutadiene elastomers
This report presents an insightful investigation of the cold crystallization behavior of sulfur-crosslinked polybutadiene elastomers. The influence of crosslink density on the cold crystallization activities of sulfur-crosslinked polybutadiene rubber (BR) is investigated using differential scanning...
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| Format: | Article |
| Language: | English |
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Budapest University of Technology and Economics
2023-07-01
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| Series: | eXPRESS Polymer Letters |
| Subjects: | |
| Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0012441&mi=cd |
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| _version_ | 1849253341124624384 |
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| author | Arpan Datta Sarma Erathimmanna Bhoje Gowd Amit Das Gert Heinrich |
| author_facet | Arpan Datta Sarma Erathimmanna Bhoje Gowd Amit Das Gert Heinrich |
| author_sort | Arpan Datta Sarma |
| collection | DOAJ |
| description | This report presents an insightful investigation of the cold crystallization behavior of sulfur-crosslinked polybutadiene elastomers. The influence of crosslink density on the cold crystallization activities of sulfur-crosslinked polybutadiene rubber (BR) is investigated using differential scanning calorimetry, dynamic mechanical analysis, and X-ray techniques. A significant increase in storage modulus (E') is observed at a temperature just above the glass transition temperature (Tg). This behavior was found to be highly dependent on the crosslink density of the rubber. The dynamic mechanical behavior of the sulfur crosslinked BR is supported by further studies using differential scanning calorimetry and low-temperature X-ray diffraction. This study could contribute to a better understanding of the behavior of BR-containing tire tread rubbers at lower temperatures. |
| format | Article |
| id | doaj-art-6bde3f7ad81640ed8a1c8cb4a366ca37 |
| institution | Kabale University |
| issn | 1788-618X |
| language | English |
| publishDate | 2023-07-01 |
| publisher | Budapest University of Technology and Economics |
| record_format | Article |
| series | eXPRESS Polymer Letters |
| spelling | doaj-art-6bde3f7ad81640ed8a1c8cb4a366ca372025-08-20T03:56:23ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2023-07-0117769069810.3144/expresspolymlett.2023.51The effect of crosslink density on the cold crystallization behavior of polybutadiene elastomersArpan Datta SarmaErathimmanna Bhoje GowdAmit DasGert HeinrichThis report presents an insightful investigation of the cold crystallization behavior of sulfur-crosslinked polybutadiene elastomers. The influence of crosslink density on the cold crystallization activities of sulfur-crosslinked polybutadiene rubber (BR) is investigated using differential scanning calorimetry, dynamic mechanical analysis, and X-ray techniques. A significant increase in storage modulus (E') is observed at a temperature just above the glass transition temperature (Tg). This behavior was found to be highly dependent on the crosslink density of the rubber. The dynamic mechanical behavior of the sulfur crosslinked BR is supported by further studies using differential scanning calorimetry and low-temperature X-ray diffraction. This study could contribute to a better understanding of the behavior of BR-containing tire tread rubbers at lower temperatures.http://www.expresspolymlett.com/letolt.php?file=EPL-0012441&mi=cddynamic mechanical analysisrubbercold crystallizationlow-temperature moduluslow-temperature x-ray diffraction |
| spellingShingle | Arpan Datta Sarma Erathimmanna Bhoje Gowd Amit Das Gert Heinrich The effect of crosslink density on the cold crystallization behavior of polybutadiene elastomers eXPRESS Polymer Letters dynamic mechanical analysis rubber cold crystallization low-temperature modulus low-temperature x-ray diffraction |
| title | The effect of crosslink density on the cold crystallization behavior of polybutadiene elastomers |
| title_full | The effect of crosslink density on the cold crystallization behavior of polybutadiene elastomers |
| title_fullStr | The effect of crosslink density on the cold crystallization behavior of polybutadiene elastomers |
| title_full_unstemmed | The effect of crosslink density on the cold crystallization behavior of polybutadiene elastomers |
| title_short | The effect of crosslink density on the cold crystallization behavior of polybutadiene elastomers |
| title_sort | effect of crosslink density on the cold crystallization behavior of polybutadiene elastomers |
| topic | dynamic mechanical analysis rubber cold crystallization low-temperature modulus low-temperature x-ray diffraction |
| url | http://www.expresspolymlett.com/letolt.php?file=EPL-0012441&mi=cd |
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