Effect of Zr Doping on Structure and Ferroelectric Properties of Nanostructured Barium Titanate
ABSTRACT Using soft chemistry methods, solid solutions of BaTi1‐xZrxO3 with 0 ≤ x ≤ 1 were obtained. The phase nature and features of the perovskite crystalline structure were established by x‐ray analysis and Fourier transform infrared (FTIR) spectroscopy. It was found that the average particle siz...
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Wiley-VCH
2025-05-01
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| Series: | Nano Select |
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| Online Access: | https://doi.org/10.1002/nano.202300173 |
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| author | Mohamed M. Salem Aseel M. Altarawneh Yamen A. Alibwaini Ryad Ghazy Osama M. Hemeda Di Zhou Moustafa A. Darwish M. Khalid Hossain Daria I. Tishkevich Tatiana I. Zubar Ekaterina L. Trukhanova Alex V. Trukhanov Sergei V. Trukhanov Maha Mostafa |
| author_facet | Mohamed M. Salem Aseel M. Altarawneh Yamen A. Alibwaini Ryad Ghazy Osama M. Hemeda Di Zhou Moustafa A. Darwish M. Khalid Hossain Daria I. Tishkevich Tatiana I. Zubar Ekaterina L. Trukhanova Alex V. Trukhanov Sergei V. Trukhanov Maha Mostafa |
| author_sort | Mohamed M. Salem |
| collection | DOAJ |
| description | ABSTRACT Using soft chemistry methods, solid solutions of BaTi1‐xZrxO3 with 0 ≤ x ≤ 1 were obtained. The phase nature and features of the perovskite crystalline structure were established by x‐ray analysis and Fourier transform infrared (FTIR) spectroscopy. It was found that the average particle size increases with increasing content of zirconium cations. The average size of the crystallites, which are mostly irregular in shape and closely connected, is ∼43 nm. The d33 piezoelectric coefficient decreases while the concentration of zirconium cations increases. It is interesting to note that the residual polarization very strongly depends on the average crystallite size and, on the contrary, increases with increasing concentration of zirconium cations. The discovered behavior can be used in the design and production of electrostatic read‐only memory devices. |
| format | Article |
| id | doaj-art-6b52ef73e7394d10b8797b7af828bdbe |
| institution | OA Journals |
| issn | 2688-4011 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Nano Select |
| spelling | doaj-art-6b52ef73e7394d10b8797b7af828bdbe2025-08-20T02:15:30ZengWiley-VCHNano Select2688-40112025-05-0165n/an/a10.1002/nano.202300173Effect of Zr Doping on Structure and Ferroelectric Properties of Nanostructured Barium TitanateMohamed M. Salem0Aseel M. Altarawneh1Yamen A. Alibwaini2Ryad Ghazy3Osama M. Hemeda4Di Zhou5Moustafa A. Darwish6M. Khalid Hossain7Daria I. Tishkevich8Tatiana I. Zubar9Ekaterina L. Trukhanova10Alex V. Trukhanov11Sergei V. Trukhanov12Maha Mostafa13Physics Department Faculty of Science Tanta University Tanta EgyptPhysics Department Faculty of Science Tanta University Tanta EgyptPhysics Department Faculty of Science Tanta University Tanta EgyptPhysics Department Faculty of Science Tanta University Tanta EgyptPhysics Department Faculty of Science Tanta University Tanta EgyptElectronic Materials Research Laboratory School of Electronic Science and Engineering Key Laboratory of the Ministry of Education & International Center for Dielectric Research Xi'an Jiaotong University Xi'an ChinaPhysics Department Faculty of Science Tanta University Tanta EgyptInstitute of Electronics, Atomic Energy Research Establishment Bangladesh Atomic Energy Commission Dhaka BangladeshLaboratory of Magnetic Films Physics SSPA “Scientific and Practical Materials Research Centre of NAS of Belarus” Minsk BelarusLaboratory of Magnetic Films Physics SSPA “Scientific and Practical Materials Research Centre of NAS of Belarus” Minsk BelarusLaboratory of Magnetic Films Physics SSPA “Scientific and Practical Materials Research Centre of NAS of Belarus” Minsk BelarusLaboratory of Magnetic Films Physics SSPA “Scientific and Practical Materials Research Centre of NAS of Belarus” Minsk BelarusLaboratory of Magnetic Films Physics SSPA “Scientific and Practical Materials Research Centre of NAS of Belarus” Minsk BelarusPhysics Department Faculty of Science Tanta University Tanta EgyptABSTRACT Using soft chemistry methods, solid solutions of BaTi1‐xZrxO3 with 0 ≤ x ≤ 1 were obtained. The phase nature and features of the perovskite crystalline structure were established by x‐ray analysis and Fourier transform infrared (FTIR) spectroscopy. It was found that the average particle size increases with increasing content of zirconium cations. The average size of the crystallites, which are mostly irregular in shape and closely connected, is ∼43 nm. The d33 piezoelectric coefficient decreases while the concentration of zirconium cations increases. It is interesting to note that the residual polarization very strongly depends on the average crystallite size and, on the contrary, increases with increasing concentration of zirconium cations. The discovered behavior can be used in the design and production of electrostatic read‐only memory devices.https://doi.org/10.1002/nano.202300173doped titanatesferroelectricsperovskitespiezoelectricssoft chemistry methods |
| spellingShingle | Mohamed M. Salem Aseel M. Altarawneh Yamen A. Alibwaini Ryad Ghazy Osama M. Hemeda Di Zhou Moustafa A. Darwish M. Khalid Hossain Daria I. Tishkevich Tatiana I. Zubar Ekaterina L. Trukhanova Alex V. Trukhanov Sergei V. Trukhanov Maha Mostafa Effect of Zr Doping on Structure and Ferroelectric Properties of Nanostructured Barium Titanate Nano Select doped titanates ferroelectrics perovskites piezoelectrics soft chemistry methods |
| title | Effect of Zr Doping on Structure and Ferroelectric Properties of Nanostructured Barium Titanate |
| title_full | Effect of Zr Doping on Structure and Ferroelectric Properties of Nanostructured Barium Titanate |
| title_fullStr | Effect of Zr Doping on Structure and Ferroelectric Properties of Nanostructured Barium Titanate |
| title_full_unstemmed | Effect of Zr Doping on Structure and Ferroelectric Properties of Nanostructured Barium Titanate |
| title_short | Effect of Zr Doping on Structure and Ferroelectric Properties of Nanostructured Barium Titanate |
| title_sort | effect of zr doping on structure and ferroelectric properties of nanostructured barium titanate |
| topic | doped titanates ferroelectrics perovskites piezoelectrics soft chemistry methods |
| url | https://doi.org/10.1002/nano.202300173 |
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