Effect of cardanol on the physical and chemical properties of sodium caseinate-coated papers for packaging applications

Despite their widespread application in food packaging, petroleum-based plastics contribute toward several environmental problems throughout their life cycle. Paper is considered a sustainable packaging material; however, its poor gas and water-vapor barrier properties limit its application in the f...

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Main Authors: Jihyeon Hwang, Yeon-Ji Jo, Dowan Kim
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Future Foods
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666833525000292
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author Jihyeon Hwang
Yeon-Ji Jo
Dowan Kim
author_facet Jihyeon Hwang
Yeon-Ji Jo
Dowan Kim
author_sort Jihyeon Hwang
collection DOAJ
description Despite their widespread application in food packaging, petroleum-based plastics contribute toward several environmental problems throughout their life cycle. Paper is considered a sustainable packaging material; however, its poor gas and water-vapor barrier properties limit its application in the food industry. In this study, papers coated with bio-based sodium caseinate (CasNa) and cardanol (CL), a plasticizer, are prepared as a sustainable food packing material. The morphological and chemical structure, mechanical properties, oxygen and water-vapor permeability, and thermal stability of pristine CasNa- and CasNa/CL-coated papers are investigated based on their CL content. CL incorporation into the CasNa matrix disrupts the robust physical interactions of CasNa, increasing the flexibility of CasNa-coated papers. Consequently, with increasing CL content, the hydrophobicity of the CasNa/CL-coated papers is enhanced with a reduction in the water-vapor transmittance rate from 461.3 ± 2.0 to 389.8 ± 3.9 g/m2·day and an increase in the water contact angle from 56.6 ± 2.4° to 72.9 ± 1.1°. Notably, the taste and flavor of coffee packaged with commercial and CasNa/CL (100 %)-coated coffee drip bags are similar, possibly owing to the good gas barrier properties of the CasNa/CL-coated papers. Therefore, this study proposes a bio-based green alternative to petroleum-based plastics that is expected to exhibit wide commercial applicability in packaging. Moreover, the results of this study could open new frontiers in sustainable food packaging.
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spelling doaj-art-6b223c0a0a3d404f949b93ff1728343d2025-02-12T05:32:59ZengElsevierFuture Foods2666-83352025-06-0111100567Effect of cardanol on the physical and chemical properties of sodium caseinate-coated papers for packaging applicationsJihyeon Hwang0Yeon-Ji Jo1Dowan Kim2Department of Food Processing & Distribution, College of Life Science, Gangneung-Wonju National University, 25457, Republic of KoreaDepartment of Food Processing & Distribution, College of Life Science, Gangneung-Wonju National University, 25457, Republic of Korea; Department of Marine Bio Food Science, College of Life Science, Gangneung-Wonju National University, 25457, Republic of Korea; Haeram Institute of Bakery Science, Gangneung-Wonju National University, Republic of KoreaDepartment of Food Processing & Distribution, College of Life Science, Gangneung-Wonju National University, 25457, Republic of Korea; Department of Marine Bio Food Science, College of Life Science, Gangneung-Wonju National University, 25457, Republic of Korea; Haeram Institute of Bakery Science, Gangneung-Wonju National University, Republic of Korea; Corresponding author at: Department of Marine Bio Food Science, College of Life Science, Gangneung-Wonju National University, 25457, Republic of Korea.Despite their widespread application in food packaging, petroleum-based plastics contribute toward several environmental problems throughout their life cycle. Paper is considered a sustainable packaging material; however, its poor gas and water-vapor barrier properties limit its application in the food industry. In this study, papers coated with bio-based sodium caseinate (CasNa) and cardanol (CL), a plasticizer, are prepared as a sustainable food packing material. The morphological and chemical structure, mechanical properties, oxygen and water-vapor permeability, and thermal stability of pristine CasNa- and CasNa/CL-coated papers are investigated based on their CL content. CL incorporation into the CasNa matrix disrupts the robust physical interactions of CasNa, increasing the flexibility of CasNa-coated papers. Consequently, with increasing CL content, the hydrophobicity of the CasNa/CL-coated papers is enhanced with a reduction in the water-vapor transmittance rate from 461.3 ± 2.0 to 389.8 ± 3.9 g/m2·day and an increase in the water contact angle from 56.6 ± 2.4° to 72.9 ± 1.1°. Notably, the taste and flavor of coffee packaged with commercial and CasNa/CL (100 %)-coated coffee drip bags are similar, possibly owing to the good gas barrier properties of the CasNa/CL-coated papers. Therefore, this study proposes a bio-based green alternative to petroleum-based plastics that is expected to exhibit wide commercial applicability in packaging. Moreover, the results of this study could open new frontiers in sustainable food packaging.http://www.sciencedirect.com/science/article/pii/S2666833525000292Sodium caseinateCardanolPaper coating materialsPlasticizing effectBio-based materialCoffee packaging
spellingShingle Jihyeon Hwang
Yeon-Ji Jo
Dowan Kim
Effect of cardanol on the physical and chemical properties of sodium caseinate-coated papers for packaging applications
Future Foods
Sodium caseinate
Cardanol
Paper coating materials
Plasticizing effect
Bio-based material
Coffee packaging
title Effect of cardanol on the physical and chemical properties of sodium caseinate-coated papers for packaging applications
title_full Effect of cardanol on the physical and chemical properties of sodium caseinate-coated papers for packaging applications
title_fullStr Effect of cardanol on the physical and chemical properties of sodium caseinate-coated papers for packaging applications
title_full_unstemmed Effect of cardanol on the physical and chemical properties of sodium caseinate-coated papers for packaging applications
title_short Effect of cardanol on the physical and chemical properties of sodium caseinate-coated papers for packaging applications
title_sort effect of cardanol on the physical and chemical properties of sodium caseinate coated papers for packaging applications
topic Sodium caseinate
Cardanol
Paper coating materials
Plasticizing effect
Bio-based material
Coffee packaging
url http://www.sciencedirect.com/science/article/pii/S2666833525000292
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AT dowankim effectofcardanolonthephysicalandchemicalpropertiesofsodiumcaseinatecoatedpapersforpackagingapplications