4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide
4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide is formed through a direct, solventless reaction between benzaldehyde tosylhydrazone and potassium carbonate, which is carried out using an eco-friendly grinding method. The NMR spectra of the compo...
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| Language: | English |
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MDPI AG
2025-06-01
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| Online Access: | https://www.mdpi.com/1422-8599/2025/2/M2022 |
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| author | Leticia Almazán-Sánchez Marco A. García-Eleno Diego Martínez-Otero Erick Cuevas-Yañez |
| author_facet | Leticia Almazán-Sánchez Marco A. García-Eleno Diego Martínez-Otero Erick Cuevas-Yañez |
| author_sort | Leticia Almazán-Sánchez |
| collection | DOAJ |
| description | 4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide is formed through a direct, solventless reaction between benzaldehyde tosylhydrazone and potassium carbonate, which is carried out using an eco-friendly grinding method. The NMR spectra of the compound are here described. The structure was unequivocally determined by X-ray analysis. As suggested by Hirshfeld surface analysis, the predominant intermolecular H-O interactions in this molecule are involved in crystal packing. |
| format | Article |
| id | doaj-art-6aed41506bae4acb96bf36dd4989f672 |
| institution | DOAJ |
| issn | 1422-8599 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj-art-6aed41506bae4acb96bf36dd4989f6722025-08-20T03:16:23ZengMDPI AGMolbank1422-85992025-06-0120252M202210.3390/M20224-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazideLeticia Almazán-Sánchez0Marco A. García-Eleno1Diego Martínez-Otero2Erick Cuevas-Yañez3Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, MexicoCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, MexicoCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, MexicoCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, Mexico4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide is formed through a direct, solventless reaction between benzaldehyde tosylhydrazone and potassium carbonate, which is carried out using an eco-friendly grinding method. The NMR spectra of the compound are here described. The structure was unequivocally determined by X-ray analysis. As suggested by Hirshfeld surface analysis, the predominant intermolecular H-O interactions in this molecule are involved in crystal packing.https://www.mdpi.com/1422-8599/2025/2/M2022tosylhydrazonesulfonohydrazidecarbene insertioncrystal structure |
| spellingShingle | Leticia Almazán-Sánchez Marco A. García-Eleno Diego Martínez-Otero Erick Cuevas-Yañez 4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide Molbank tosylhydrazone sulfonohydrazide carbene insertion crystal structure |
| title | 4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide |
| title_full | 4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide |
| title_fullStr | 4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide |
| title_full_unstemmed | 4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide |
| title_short | 4-Methyl-<i>N</i>-(1-benzyl)-<i>N</i>’-(1-benzylidene)benzenesulfonohydrazide |
| title_sort | 4 methyl i n i 1 benzyl i n i 1 benzylidene benzenesulfonohydrazide |
| topic | tosylhydrazone sulfonohydrazide carbene insertion crystal structure |
| url | https://www.mdpi.com/1422-8599/2025/2/M2022 |
| work_keys_str_mv | AT leticiaalmazansanchez 4methylini1benzylini1benzylidenebenzenesulfonohydrazide AT marcoagarciaeleno 4methylini1benzylini1benzylidenebenzenesulfonohydrazide AT diegomartinezotero 4methylini1benzylini1benzylidenebenzenesulfonohydrazide AT erickcuevasyanez 4methylini1benzylini1benzylidenebenzenesulfonohydrazide |