Study on Absorption Refrigeration Cycle with a New Working Pair of Ionic Liquid and Water

The ionic liquids have offered a new way for improving working substance of absorption refrigeration cycle. However, the performance of the absorption refrigeration cycle with ionic liquids and water as working pairs is strongly dependent on the hygroscopy of ionic liquids. Two ionic liquids: 1-ethy...

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Main Authors: Su Hang, Guo Kaihua, Huangpu Lixia, Sun Li
Format: Article
Language:zho
Published: Journal of Refrigeration Magazines Agency Co., Ltd. 2013-01-01
Series:Zhileng xuebao
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Online Access:http://www.zhilengxuebao.com/thesisDetails#10.3969/j.issn.0253-4339.2013.03.024
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author Su Hang
Guo Kaihua
Huangpu Lixia
Sun Li
author_facet Su Hang
Guo Kaihua
Huangpu Lixia
Sun Li
author_sort Su Hang
collection DOAJ
description The ionic liquids have offered a new way for improving working substance of absorption refrigeration cycle. However, the performance of the absorption refrigeration cycle with ionic liquids and water as working pairs is strongly dependent on the hygroscopy of ionic liquids. Two ionic liquids: 1-ethyl-3-methylimidazolium acetate ([EMIm]Ac) and 1-hexyl-3-methylimidazolium chloride([HMIm]Cl),which have super water-absorption capability, were selected as the working pairs for absorption refrigeration cycles. First, we studied the thermodynamic properties (vapor pressure, specific heat, enthalpy, etc.) of the two ionic liquid aqueous solutions. Then we analyzed their coefficient of performance for the absorption refrigeration cycle. The study shows the two ionic liquid-water pairs can work in a higher temperature condition for single-stage absorption refrigeration cycles and have better coefficients of performance (COP) comparing to those of the ionic liquid working pairs studied by the existed works of other domestic and foreign scholars. The performance of [EMIm]Ac aqueous solution is superior to that of [HMIm]Cl. Comparing to the performance of the ordinary lithium bromide-water working pair, the COP of the single-stage absorption cycle of [EMIm]Ac aqueous solution is almost the same when the generation temperature reach 100℃, and for higher temperature range, the performance of [EMIm]Ac-water pair is a little superior to that of the ordinary lithium bromide-water working pair. Since the superiority of the ionic liquid is only in higher generation temperature, further breakthrough should be had for good properties of vapor pressure of ionic liquid in the low temperature.
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spelling doaj-art-6a576caedd5942a9b5c8bb92ccc175302025-08-20T02:47:15ZzhoJournal of Refrigeration Magazines Agency Co., Ltd.Zhileng xuebao0253-43392013-01-013466518840Study on Absorption Refrigeration Cycle with a New Working Pair of Ionic Liquid and WaterSu HangGuo KaihuaHuangpu LixiaSun LiThe ionic liquids have offered a new way for improving working substance of absorption refrigeration cycle. However, the performance of the absorption refrigeration cycle with ionic liquids and water as working pairs is strongly dependent on the hygroscopy of ionic liquids. Two ionic liquids: 1-ethyl-3-methylimidazolium acetate ([EMIm]Ac) and 1-hexyl-3-methylimidazolium chloride([HMIm]Cl),which have super water-absorption capability, were selected as the working pairs for absorption refrigeration cycles. First, we studied the thermodynamic properties (vapor pressure, specific heat, enthalpy, etc.) of the two ionic liquid aqueous solutions. Then we analyzed their coefficient of performance for the absorption refrigeration cycle. The study shows the two ionic liquid-water pairs can work in a higher temperature condition for single-stage absorption refrigeration cycles and have better coefficients of performance (COP) comparing to those of the ionic liquid working pairs studied by the existed works of other domestic and foreign scholars. The performance of [EMIm]Ac aqueous solution is superior to that of [HMIm]Cl. Comparing to the performance of the ordinary lithium bromide-water working pair, the COP of the single-stage absorption cycle of [EMIm]Ac aqueous solution is almost the same when the generation temperature reach 100℃, and for higher temperature range, the performance of [EMIm]Ac-water pair is a little superior to that of the ordinary lithium bromide-water working pair. Since the superiority of the ionic liquid is only in higher generation temperature, further breakthrough should be had for good properties of vapor pressure of ionic liquid in the low temperature.http://www.zhilengxuebao.com/thesisDetails#10.3969/j.issn.0253-4339.2013.03.024absorption refrigeration cycleionic liquidcoefficient of performance
spellingShingle Su Hang
Guo Kaihua
Huangpu Lixia
Sun Li
Study on Absorption Refrigeration Cycle with a New Working Pair of Ionic Liquid and Water
Zhileng xuebao
absorption refrigeration cycle
ionic liquid
coefficient of performance
title Study on Absorption Refrigeration Cycle with a New Working Pair of Ionic Liquid and Water
title_full Study on Absorption Refrigeration Cycle with a New Working Pair of Ionic Liquid and Water
title_fullStr Study on Absorption Refrigeration Cycle with a New Working Pair of Ionic Liquid and Water
title_full_unstemmed Study on Absorption Refrigeration Cycle with a New Working Pair of Ionic Liquid and Water
title_short Study on Absorption Refrigeration Cycle with a New Working Pair of Ionic Liquid and Water
title_sort study on absorption refrigeration cycle with a new working pair of ionic liquid and water
topic absorption refrigeration cycle
ionic liquid
coefficient of performance
url http://www.zhilengxuebao.com/thesisDetails#10.3969/j.issn.0253-4339.2013.03.024
work_keys_str_mv AT suhang studyonabsorptionrefrigerationcyclewithanewworkingpairofionicliquidandwater
AT guokaihua studyonabsorptionrefrigerationcyclewithanewworkingpairofionicliquidandwater
AT huangpulixia studyonabsorptionrefrigerationcyclewithanewworkingpairofionicliquidandwater
AT sunli studyonabsorptionrefrigerationcyclewithanewworkingpairofionicliquidandwater