Studies on Removal of Cr (VI) from Aqueous Solutions Using Powder of Mosambi Fruit Peelings (PMFP) As a Low Cost Sorbent

The powder of mosambi fruit peelings (PMFP) was used as an adsorbent for the removal of heavy metal like Cr (VI) from aqueous solutions was studied using batch tests. The influence of physico-chemical key parameters such as the initial metal ion concentration, pH, agitation time, adsorbent dosage, a...

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Main Authors: R. Hema Krishna, A. V. V. S. Swamy
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/769674
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author R. Hema Krishna
A. V. V. S. Swamy
author_facet R. Hema Krishna
A. V. V. S. Swamy
author_sort R. Hema Krishna
collection DOAJ
description The powder of mosambi fruit peelings (PMFP) was used as an adsorbent for the removal of heavy metal like Cr (VI) from aqueous solutions was studied using batch tests. The influence of physico-chemical key parameters such as the initial metal ion concentration, pH, agitation time, adsorbent dosage, and the particle size of adsorbent has been considered in batch tests. Sorbent ability to adsorb Cr (VI) ions was examined and the mechanism involved in the process investigated. The optimum results were determined at an initial metal ion concentration was 10 mg/lit, pH=2, agitation time – 60 min, an adsorbent dose (150 mg/50 ml) and the particle size (0.6 mm). The % adsorption, Langmuir constants [Q0=7.51(mg/g) and b=1.69(mg/lit)] Freundlich constant(Kf=2.94), Lagergren rate constants (Kad (min-1)=5.75 x 10-2) for [Cr(VI)] 10 mg/lit were determined for the adsorption system as a function of sorbate concentration. The equilibrium data obtained were tested using Langmuir, Freundlich adsorption isotherm models, and the kinetic data obtained were fitted to pseudo first order model.
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spelling doaj-art-6a12f2d852a749108c1823e9821c4ece2025-08-20T02:06:06ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01931389139910.1155/2012/769674Studies on Removal of Cr (VI) from Aqueous Solutions Using Powder of Mosambi Fruit Peelings (PMFP) As a Low Cost SorbentR. Hema Krishna0A. V. V. S. Swamy1Department of Chemistry, University of Toronto, Ontario, M5S2V8, CanadaDepartment of Environmental Sciences, Acharya Nagarjuna University, Andhrapradesh, IndiaThe powder of mosambi fruit peelings (PMFP) was used as an adsorbent for the removal of heavy metal like Cr (VI) from aqueous solutions was studied using batch tests. The influence of physico-chemical key parameters such as the initial metal ion concentration, pH, agitation time, adsorbent dosage, and the particle size of adsorbent has been considered in batch tests. Sorbent ability to adsorb Cr (VI) ions was examined and the mechanism involved in the process investigated. The optimum results were determined at an initial metal ion concentration was 10 mg/lit, pH=2, agitation time – 60 min, an adsorbent dose (150 mg/50 ml) and the particle size (0.6 mm). The % adsorption, Langmuir constants [Q0=7.51(mg/g) and b=1.69(mg/lit)] Freundlich constant(Kf=2.94), Lagergren rate constants (Kad (min-1)=5.75 x 10-2) for [Cr(VI)] 10 mg/lit were determined for the adsorption system as a function of sorbate concentration. The equilibrium data obtained were tested using Langmuir, Freundlich adsorption isotherm models, and the kinetic data obtained were fitted to pseudo first order model.http://dx.doi.org/10.1155/2012/769674
spellingShingle R. Hema Krishna
A. V. V. S. Swamy
Studies on Removal of Cr (VI) from Aqueous Solutions Using Powder of Mosambi Fruit Peelings (PMFP) As a Low Cost Sorbent
E-Journal of Chemistry
title Studies on Removal of Cr (VI) from Aqueous Solutions Using Powder of Mosambi Fruit Peelings (PMFP) As a Low Cost Sorbent
title_full Studies on Removal of Cr (VI) from Aqueous Solutions Using Powder of Mosambi Fruit Peelings (PMFP) As a Low Cost Sorbent
title_fullStr Studies on Removal of Cr (VI) from Aqueous Solutions Using Powder of Mosambi Fruit Peelings (PMFP) As a Low Cost Sorbent
title_full_unstemmed Studies on Removal of Cr (VI) from Aqueous Solutions Using Powder of Mosambi Fruit Peelings (PMFP) As a Low Cost Sorbent
title_short Studies on Removal of Cr (VI) from Aqueous Solutions Using Powder of Mosambi Fruit Peelings (PMFP) As a Low Cost Sorbent
title_sort studies on removal of cr vi from aqueous solutions using powder of mosambi fruit peelings pmfp as a low cost sorbent
url http://dx.doi.org/10.1155/2012/769674
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