Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates
The binary and ternary metal complexes of Cu(II) & Ni(II) with some amino acids (leucine, isoleucine & serine) as primary ligand and pyrophosphate (PP), adenosine-5´-triphosphate (ATP), as secondary ligand have been studied potentiometrically at 35 °C and a constant ionic strength (1.0 mol d...
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Wiley
2011-01-01
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Series: | E-Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2011/157501 |
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author | Aruna Adam Suman Verma Gita Seth |
author_facet | Aruna Adam Suman Verma Gita Seth |
author_sort | Aruna Adam |
collection | DOAJ |
description | The binary and ternary metal complexes of Cu(II) & Ni(II) with some amino acids (leucine, isoleucine & serine) as primary ligand and pyrophosphate (PP), adenosine-5´-triphosphate (ATP), as secondary ligand have been studied potentiometrically at 35 °C and a constant ionic strength (1.0 mol dm-3 KNO3). The formation of various binary and ternary complexes has been inferred from the corresponding titration curves. The Irving & Rossotti titration technique has been applied to determine the formation constants corresponding to various complexation equilibria. |
format | Article |
id | doaj-art-6951f92a319b4a1abb7a25fdd26630f1 |
institution | Kabale University |
issn | 0973-4945 2090-9810 |
language | English |
publishDate | 2011-01-01 |
publisher | Wiley |
record_format | Article |
series | E-Journal of Chemistry |
spelling | doaj-art-6951f92a319b4a1abb7a25fdd26630f12025-02-03T01:03:23ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018S1S404S40810.1155/2011/157501Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and PhosphatesAruna Adam0Suman Verma1Gita Seth2B. B. D. Government College, Chimanpura, (Rajasthan), IndiaDepartment of Chemistry, University of Rajasthan, Jaipur–302055, IndiaDepartment of Chemistry, University of Rajasthan, Jaipur–302055, IndiaThe binary and ternary metal complexes of Cu(II) & Ni(II) with some amino acids (leucine, isoleucine & serine) as primary ligand and pyrophosphate (PP), adenosine-5´-triphosphate (ATP), as secondary ligand have been studied potentiometrically at 35 °C and a constant ionic strength (1.0 mol dm-3 KNO3). The formation of various binary and ternary complexes has been inferred from the corresponding titration curves. The Irving & Rossotti titration technique has been applied to determine the formation constants corresponding to various complexation equilibria.http://dx.doi.org/10.1155/2011/157501 |
spellingShingle | Aruna Adam Suman Verma Gita Seth Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates E-Journal of Chemistry |
title | Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates |
title_full | Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates |
title_fullStr | Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates |
title_full_unstemmed | Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates |
title_short | Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates |
title_sort | stability constants of mixed ligand complexes of cu ii and ni ii with some amino acids and phosphates |
url | http://dx.doi.org/10.1155/2011/157501 |
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