Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates

The binary and ternary metal complexes of Cu(II) & Ni(II) with some amino acids (leucine, isoleucine & serine) as primary ligand and pyrophosphate (PP), adenosine-5´-triphosphate (ATP), as secondary ligand have been studied potentiometrically at 35 °C and a constant ionic strength (1.0 mol d...

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Main Authors: Aruna Adam, Suman Verma, Gita Seth
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/157501
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author Aruna Adam
Suman Verma
Gita Seth
author_facet Aruna Adam
Suman Verma
Gita Seth
author_sort Aruna Adam
collection DOAJ
description The binary and ternary metal complexes of Cu(II) & Ni(II) with some amino acids (leucine, isoleucine & serine) as primary ligand and pyrophosphate (PP), adenosine-5´-triphosphate (ATP), as secondary ligand have been studied potentiometrically at 35 °C and a constant ionic strength (1.0 mol dm-3 KNO3). The formation of various binary and ternary complexes has been inferred from the corresponding titration curves. The Irving & Rossotti titration technique has been applied to determine the formation constants corresponding to various complexation equilibria.
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institution Kabale University
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spelling doaj-art-6951f92a319b4a1abb7a25fdd26630f12025-02-03T01:03:23ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018S1S404S40810.1155/2011/157501Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and PhosphatesAruna Adam0Suman Verma1Gita Seth2B. B. D. Government College, Chimanpura, (Rajasthan), IndiaDepartment of Chemistry, University of Rajasthan, Jaipur–302055, IndiaDepartment of Chemistry, University of Rajasthan, Jaipur–302055, IndiaThe binary and ternary metal complexes of Cu(II) & Ni(II) with some amino acids (leucine, isoleucine & serine) as primary ligand and pyrophosphate (PP), adenosine-5´-triphosphate (ATP), as secondary ligand have been studied potentiometrically at 35 °C and a constant ionic strength (1.0 mol dm-3 KNO3). The formation of various binary and ternary complexes has been inferred from the corresponding titration curves. The Irving & Rossotti titration technique has been applied to determine the formation constants corresponding to various complexation equilibria.http://dx.doi.org/10.1155/2011/157501
spellingShingle Aruna Adam
Suman Verma
Gita Seth
Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates
E-Journal of Chemistry
title Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates
title_full Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates
title_fullStr Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates
title_full_unstemmed Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates
title_short Stability Constants of Mixed Ligand Complexes of Cu(II) and Ni(II) with Some Amino Acids and Phosphates
title_sort stability constants of mixed ligand complexes of cu ii and ni ii with some amino acids and phosphates
url http://dx.doi.org/10.1155/2011/157501
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