Synthesis and Characterization of Pumice-Supported nZVI for Removal of Copper from Waters

The target of this work was to study the synthesis and characterization of pumice-supported nanoscale zero-valent iron (nZVI) and the effectiveness of nZVI coated pumice to remove copper from water. The impacts of pumice dose, pumice surface chemistry, pH, and water source on copper removal were stu...

Full description

Saved in:
Bibliographic Details
Main Authors: Bilgehan Ilker Harman, Mesut Genisoglu
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2016/4372136
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849415482845691904
author Bilgehan Ilker Harman
Mesut Genisoglu
author_facet Bilgehan Ilker Harman
Mesut Genisoglu
author_sort Bilgehan Ilker Harman
collection DOAJ
description The target of this work was to study the synthesis and characterization of pumice-supported nanoscale zero-valent iron (nZVI) and the effectiveness of nZVI coated pumice to remove copper from water. The impacts of pumice dose, pumice surface chemistry, pH, and water source on copper removal were studied. Natural pumice particles were used as granular support media and coated with nZVI. Results of nZVI coated pumice characterization showed nZVI coated successfully on pumice surface being proved with characterization methods such as SEM-EDS, XPS, and XRF. nZVI coating overwhelmed the surface chemistry properties of the underlying pumice particles. Higher surface areas and more iron content were obtained in nZVI coated pumice. nZVI coating significantly increased copper uptake compared to uncoated particles. High removal capacity has been observed for all tested pH values. Control experiments indicated that nZVI bound on pumice surfaces is stable at pH values of typical natural waters. The nZVI coated pumice was found to be effective in removing copper from waters having a wide range of specific UV absorbance (SUVA) values. Overall, the results indicated that nZVI coated pumice particles are maybe alternative adsorbents to remove copper.
format Article
id doaj-art-68c7dcfcf9904b13b3fcfd7df1e2c39b
institution Kabale University
issn 1687-8434
1687-8442
language English
publishDate 2016-01-01
publisher Wiley
record_format Article
series Advances in Materials Science and Engineering
spelling doaj-art-68c7dcfcf9904b13b3fcfd7df1e2c39b2025-08-20T03:33:31ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422016-01-01201610.1155/2016/43721364372136Synthesis and Characterization of Pumice-Supported nZVI for Removal of Copper from WatersBilgehan Ilker Harman0Mesut Genisoglu1Technical Science Vocational School, Suleyman Demirel University, 32260 Isparta, TurkeyDepartment of Environmental Engineering, Suleyman Demirel University, 32260 Isparta, TurkeyThe target of this work was to study the synthesis and characterization of pumice-supported nanoscale zero-valent iron (nZVI) and the effectiveness of nZVI coated pumice to remove copper from water. The impacts of pumice dose, pumice surface chemistry, pH, and water source on copper removal were studied. Natural pumice particles were used as granular support media and coated with nZVI. Results of nZVI coated pumice characterization showed nZVI coated successfully on pumice surface being proved with characterization methods such as SEM-EDS, XPS, and XRF. nZVI coating overwhelmed the surface chemistry properties of the underlying pumice particles. Higher surface areas and more iron content were obtained in nZVI coated pumice. nZVI coating significantly increased copper uptake compared to uncoated particles. High removal capacity has been observed for all tested pH values. Control experiments indicated that nZVI bound on pumice surfaces is stable at pH values of typical natural waters. The nZVI coated pumice was found to be effective in removing copper from waters having a wide range of specific UV absorbance (SUVA) values. Overall, the results indicated that nZVI coated pumice particles are maybe alternative adsorbents to remove copper.http://dx.doi.org/10.1155/2016/4372136
spellingShingle Bilgehan Ilker Harman
Mesut Genisoglu
Synthesis and Characterization of Pumice-Supported nZVI for Removal of Copper from Waters
Advances in Materials Science and Engineering
title Synthesis and Characterization of Pumice-Supported nZVI for Removal of Copper from Waters
title_full Synthesis and Characterization of Pumice-Supported nZVI for Removal of Copper from Waters
title_fullStr Synthesis and Characterization of Pumice-Supported nZVI for Removal of Copper from Waters
title_full_unstemmed Synthesis and Characterization of Pumice-Supported nZVI for Removal of Copper from Waters
title_short Synthesis and Characterization of Pumice-Supported nZVI for Removal of Copper from Waters
title_sort synthesis and characterization of pumice supported nzvi for removal of copper from waters
url http://dx.doi.org/10.1155/2016/4372136
work_keys_str_mv AT bilgehanilkerharman synthesisandcharacterizationofpumicesupportednzviforremovalofcopperfromwaters
AT mesutgenisoglu synthesisandcharacterizationofpumicesupportednzviforremovalofcopperfromwaters