Nickel-Chitosan Hybrid as a Precursor for Nickel Oxide Nanoporous Particles for Organic Dyes Photodegredation

Hydrothermal synthesis of nickel-chitosan hybrid  has  been accomplished using Ni(CH3COO)2,4H2O, chitosan and water as starting material, template and solvent respectively, followed by calcination at 800 and 900˚C to provide nanoporous NiO800  and NiO900. The solid products were characterized by X-r...

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Main Author: F. Farzaneh
Format: Article
Language:English
Published: University of Tehran 2014-06-01
Series:Journal of Sciences, Islamic Republic of Iran
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Online Access:https://jsciences.ut.ac.ir/article_51394_5b70815382e2a3d528d5a2ddc0976049.pdf
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author F. Farzaneh
author_facet F. Farzaneh
author_sort F. Farzaneh
collection DOAJ
description Hydrothermal synthesis of nickel-chitosan hybrid  has  been accomplished using Ni(CH3COO)2,4H2O, chitosan and water as starting material, template and solvent respectively, followed by calcination at 800 and 900˚C to provide nanoporous NiO800  and NiO900. The solid products were characterized by X-ray diffraction (XRD), nitrogen adsorption-desorption, scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) techniques.  NiO800 proved to be active for adsorption of Congo red with pseudo-second order kinetic model and adsorption isotherms, respectively fitted by Freundlich equation. NiO900 was also found to successfully catalyze the photodegradation of organic dye pollutants such as Congo red  and methylene blue. The kinetic of photocatalytic behavior of NiO900 have proven to obey the first order and Langmuir–Hinshelwood model.
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publisher University of Tehran
record_format Article
series Journal of Sciences, Islamic Republic of Iran
spelling doaj-art-68bd99e356ed41dea9583e54e3044d6b2025-08-20T03:54:07ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69142014-06-0125211011851394Nickel-Chitosan Hybrid as a Precursor for Nickel Oxide Nanoporous Particles for Organic Dyes PhotodegredationF. Farzaneh0Department of Chemistry, Faculty of Sciences, Alzahra University, P.O. Box1993891176 Vanak, Tehran, Islamic Republic of IranHydrothermal synthesis of nickel-chitosan hybrid  has  been accomplished using Ni(CH3COO)2,4H2O, chitosan and water as starting material, template and solvent respectively, followed by calcination at 800 and 900˚C to provide nanoporous NiO800  and NiO900. The solid products were characterized by X-ray diffraction (XRD), nitrogen adsorption-desorption, scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) techniques.  NiO800 proved to be active for adsorption of Congo red with pseudo-second order kinetic model and adsorption isotherms, respectively fitted by Freundlich equation. NiO900 was also found to successfully catalyze the photodegradation of organic dye pollutants such as Congo red  and methylene blue. The kinetic of photocatalytic behavior of NiO900 have proven to obey the first order and Langmuir–Hinshelwood model.https://jsciences.ut.ac.ir/article_51394_5b70815382e2a3d528d5a2ddc0976049.pdfnanoparticlesnickel oxidephotodegradationadsorptionorganic dyes
spellingShingle F. Farzaneh
Nickel-Chitosan Hybrid as a Precursor for Nickel Oxide Nanoporous Particles for Organic Dyes Photodegredation
Journal of Sciences, Islamic Republic of Iran
nanoparticles
nickel oxide
photodegradation
adsorption
organic dyes
title Nickel-Chitosan Hybrid as a Precursor for Nickel Oxide Nanoporous Particles for Organic Dyes Photodegredation
title_full Nickel-Chitosan Hybrid as a Precursor for Nickel Oxide Nanoporous Particles for Organic Dyes Photodegredation
title_fullStr Nickel-Chitosan Hybrid as a Precursor for Nickel Oxide Nanoporous Particles for Organic Dyes Photodegredation
title_full_unstemmed Nickel-Chitosan Hybrid as a Precursor for Nickel Oxide Nanoporous Particles for Organic Dyes Photodegredation
title_short Nickel-Chitosan Hybrid as a Precursor for Nickel Oxide Nanoporous Particles for Organic Dyes Photodegredation
title_sort nickel chitosan hybrid as a precursor for nickel oxide nanoporous particles for organic dyes photodegredation
topic nanoparticles
nickel oxide
photodegradation
adsorption
organic dyes
url https://jsciences.ut.ac.ir/article_51394_5b70815382e2a3d528d5a2ddc0976049.pdf
work_keys_str_mv AT ffarzaneh nickelchitosanhybridasaprecursorfornickeloxidenanoporousparticlesfororganicdyesphotodegredation