Specific Sn–O–Fe Active Sites from Atomically Sn-Doping Porous Fe2O3 for Ultrasensitive NO2 Detection

Highlights The heteroatom atomically doping strategy was reported to construct highly efficient sites on metal oxides for the detection of low-concentration gas. The atomically dispersed Sn atoms were intentionally incorporated into the Fe2O3 lattice during the oxidative annealing of Fe-based metal...

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Bibliographic Details
Main Authors: Yihong Zhong, Guotao Yuan, Dequan Bao, Yi Tao, Zhenqiu Gao, Wei Zhao, Shuo Li, Yuting Yang, Pingping Zhang, Hao Zhang, Xuhui Sun
Format: Article
Language:English
Published: SpringerOpen 2025-05-01
Series:Nano-Micro Letters
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Online Access:https://doi.org/10.1007/s40820-025-01770-9
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Summary:Highlights The heteroatom atomically doping strategy was reported to construct highly efficient sites on metal oxides for the detection of low-concentration gas. The atomically dispersed Sn atoms were intentionally incorporated into the Fe2O3 lattice during the oxidative annealing of Fe-based metal organic framework, leading to specific Sn–O–Fe sites, porous structures, and abundant oxygen vacancies. The optimized Sn-Fe2O3 exhibited exceptional sensing performance for NO2 detection: ultra-high sensitivity (Rg/Ra=2646.6 to 1 ppm NO2), ultra-low limit of detection (10 ppb), and high selectivity.
ISSN:2311-6706
2150-5551