TECHNOLOGICAL PROPERTIES OF NANODISPERSIONS BASED ON DER-330 EPOXY RESIN AND BS-50 FUMED SILICA

The influence of silica dioxide nanoparticles in the form of fumed silica BS-50 on the rheological properties, residual shrinkage and shrinkage stresses upon curing an epoxy resin is considered. It is shown that the introduction of BS-50 in the optimum concentration of nanoparticles into DER-330 epo...

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Main Authors: A. A. Pykhtin, I. D. Simonov-Emelyanov
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2016-08-01
Series:Тонкие химические технологии
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Online Access:https://www.finechem-mirea.ru/jour/article/view/41
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author A. A. Pykhtin
I. D. Simonov-Emelyanov
author_facet A. A. Pykhtin
I. D. Simonov-Emelyanov
author_sort A. A. Pykhtin
collection DOAJ
description The influence of silica dioxide nanoparticles in the form of fumed silica BS-50 on the rheological properties, residual shrinkage and shrinkage stresses upon curing an epoxy resin is considered. It is shown that the introduction of BS-50 in the optimum concentration of nanoparticles into DER-330 epoxy resin results in agglomeration, which is accompanied by an abnormal behavior of the disperse system with a decrease in viscosity by ~ 25%, ultimate shrinkage by ~ 15% and the level of residual stresses by a factor of ~ 4-10. These properties are manifested when the concentration of fumed silica is 0.05 vol. % The introduction of fumed silica slows the rise of residual stresses and increases the induction period from 2 to 4 hours. Depending on the mode of curing the minimum residual stress is observed at different concentrations of BS-50. At temperatures of 30ºC and 50°C concentration was 0.5 vol. %, and at 70°C - 0.05 vol. %. Curing at 30°C and 50°C result in a fall of residual stress by a factor of 12 and 4, respectively, at 70°C, by a factor of 4.
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series Тонкие химические технологии
spelling doaj-art-689f261a81eb48d98dc49e70e831e31c2025-08-20T03:42:45ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752016-08-01114636810.32362/2410-6593-2016-11-4-63-6841TECHNOLOGICAL PROPERTIES OF NANODISPERSIONS BASED ON DER-330 EPOXY RESIN AND BS-50 FUMED SILICAA. A. Pykhtin0I. D. Simonov-Emelyanov1Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)The influence of silica dioxide nanoparticles in the form of fumed silica BS-50 on the rheological properties, residual shrinkage and shrinkage stresses upon curing an epoxy resin is considered. It is shown that the introduction of BS-50 in the optimum concentration of nanoparticles into DER-330 epoxy resin results in agglomeration, which is accompanied by an abnormal behavior of the disperse system with a decrease in viscosity by ~ 25%, ultimate shrinkage by ~ 15% and the level of residual stresses by a factor of ~ 4-10. These properties are manifested when the concentration of fumed silica is 0.05 vol. % The introduction of fumed silica slows the rise of residual stresses and increases the induction period from 2 to 4 hours. Depending on the mode of curing the minimum residual stress is observed at different concentrations of BS-50. At temperatures of 30ºC and 50°C concentration was 0.5 vol. %, and at 70°C - 0.05 vol. %. Curing at 30°C and 50°C result in a fall of residual stress by a factor of 12 and 4, respectively, at 70°C, by a factor of 4.https://www.finechem-mirea.ru/jour/article/view/41epoxy resinnanoparticlesfumed silicananocomposite
spellingShingle A. A. Pykhtin
I. D. Simonov-Emelyanov
TECHNOLOGICAL PROPERTIES OF NANODISPERSIONS BASED ON DER-330 EPOXY RESIN AND BS-50 FUMED SILICA
Тонкие химические технологии
epoxy resin
nanoparticles
fumed silica
nanocomposite
title TECHNOLOGICAL PROPERTIES OF NANODISPERSIONS BASED ON DER-330 EPOXY RESIN AND BS-50 FUMED SILICA
title_full TECHNOLOGICAL PROPERTIES OF NANODISPERSIONS BASED ON DER-330 EPOXY RESIN AND BS-50 FUMED SILICA
title_fullStr TECHNOLOGICAL PROPERTIES OF NANODISPERSIONS BASED ON DER-330 EPOXY RESIN AND BS-50 FUMED SILICA
title_full_unstemmed TECHNOLOGICAL PROPERTIES OF NANODISPERSIONS BASED ON DER-330 EPOXY RESIN AND BS-50 FUMED SILICA
title_short TECHNOLOGICAL PROPERTIES OF NANODISPERSIONS BASED ON DER-330 EPOXY RESIN AND BS-50 FUMED SILICA
title_sort technological properties of nanodispersions based on der 330 epoxy resin and bs 50 fumed silica
topic epoxy resin
nanoparticles
fumed silica
nanocomposite
url https://www.finechem-mirea.ru/jour/article/view/41
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AT idsimonovemelyanov technologicalpropertiesofnanodispersionsbasedonder330epoxyresinandbs50fumedsilica