Color Compounds Removal from Tequila Vinasses Using Silica Gel Adsorbents Functionalized with Thiol Moieties: Equilibrium and Kinetics Studies

Tequila vinasses are organic wastes generated during ethanol fermentation at elevated temperatures (≥90 °C) and pH ≤ 4.0, making them hazardous to the environment. This paper describes a new, simplified UV–vis spectroscopy-based procedure for monitoring the adsorption of color compounds in tequila v...

Full description

Saved in:
Bibliographic Details
Main Authors: Carlos Gonzalez-Valerio, Alejandro A. Peregrina-Lucano, Ricardo Manríquez-González, Aida A. Pérez-Fonseca, Jorge R. Robledo-Ortíz, Ilya G. Shenderovich, Sergio Gómez-Salazar
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/29/24/5910
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Tequila vinasses are organic wastes generated during ethanol fermentation at elevated temperatures (≥90 °C) and pH ≤ 4.0, making them hazardous to the environment. This paper describes a new, simplified UV–vis spectroscopy-based procedure for monitoring the adsorption of color compounds in tequila vinasses onto silica-based adsorbents, along with an optimized synthesis method to produce the most efficient sol–gel synthesized thiol-functionalized adsorbent. Under optimized conditions, the uptake capacity of this adsorbent reaches 0.8 g g<sup>−1</sup> in 90 min. Experimental results demonstrate that the adsorbent has a specific affinity for melanoidin-type molecules. The adsorbent demonstrates excellent thermal stability (~316 °C). The results of this work indicate that the adsorbent possesses potential in the treatment of tequila vinasses from wastewater discharges.
ISSN:1420-3049