Efficient Degradation of Methylene Blue in Industrial Wastewater and High Cycling Stability of Nano ZnO

Photocatalytic degradation research has attracted significant attention in the wake of the increasingly severe global challenge of water pollution. In this study, nano-ZnO was synthesized through a straightforward method using zinc acetate anhydrous as the precursor. The experimental results reveale...

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Main Authors: Ping Liang, Weiye Yang, Hongyan Peng, Shihua Zhao
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/29/23/5584
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author Ping Liang
Weiye Yang
Hongyan Peng
Shihua Zhao
author_facet Ping Liang
Weiye Yang
Hongyan Peng
Shihua Zhao
author_sort Ping Liang
collection DOAJ
description Photocatalytic degradation research has attracted significant attention in the wake of the increasingly severe global challenge of water pollution. In this study, nano-ZnO was synthesized through a straightforward method using zinc acetate anhydrous as the precursor. The experimental results revealed that annealing conditions significantly influenced the bandgap energy (Eg) of ZnO, with a positive correlation observed between the intensity of photoluminescence (PL) spectra and photocatalytic activity. Under optimal annealing conditions at 300 °C for 1.5 h, the photocatalytic degradation efficiency of methylene blue (MB) exceeded 98% within 40 min of ultraviolet (UV) irradiation, surpassing the efficiencies reported for ZnO in recent studies. This high performance underscores the excellent photocatalytic activity of the synthesized ZnO samples. Furthermore, after five photocatalytic cycles, the degradation efficiency of MB remained above 90%, and the crystalline structure of the ZnO samples remained stable, demonstrating their exceptional structural stability during the photocatalytic process. Additionally, this study examined the effects of stirring conditions and different light sources on MB degradation, providing valuable insights for future research in related fields.
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spelling doaj-art-67cfd474694340a2a0300ef5ba41edc82025-08-20T02:50:33ZengMDPI AGMolecules1420-30492024-11-012923558410.3390/molecules29235584Efficient Degradation of Methylene Blue in Industrial Wastewater and High Cycling Stability of Nano ZnOPing Liang0Weiye Yang1Hongyan Peng2Shihua Zhao3College of Physics and Electronic Engineering, Hainan Normol University, Haikou 571158, ChinaCollege of Physics and Electronic Engineering, Hainan Normol University, Haikou 571158, ChinaCollege of Physics and Electronic Engineering, Hainan Normol University, Haikou 571158, ChinaCollege of Physics and Electronic Engineering, Hainan Normol University, Haikou 571158, ChinaPhotocatalytic degradation research has attracted significant attention in the wake of the increasingly severe global challenge of water pollution. In this study, nano-ZnO was synthesized through a straightforward method using zinc acetate anhydrous as the precursor. The experimental results revealed that annealing conditions significantly influenced the bandgap energy (Eg) of ZnO, with a positive correlation observed between the intensity of photoluminescence (PL) spectra and photocatalytic activity. Under optimal annealing conditions at 300 °C for 1.5 h, the photocatalytic degradation efficiency of methylene blue (MB) exceeded 98% within 40 min of ultraviolet (UV) irradiation, surpassing the efficiencies reported for ZnO in recent studies. This high performance underscores the excellent photocatalytic activity of the synthesized ZnO samples. Furthermore, after five photocatalytic cycles, the degradation efficiency of MB remained above 90%, and the crystalline structure of the ZnO samples remained stable, demonstrating their exceptional structural stability during the photocatalytic process. Additionally, this study examined the effects of stirring conditions and different light sources on MB degradation, providing valuable insights for future research in related fields.https://www.mdpi.com/1420-3049/29/23/5584zinc oxidedegradationcycling stabilityphotocatalysismethylene blue (MB)
spellingShingle Ping Liang
Weiye Yang
Hongyan Peng
Shihua Zhao
Efficient Degradation of Methylene Blue in Industrial Wastewater and High Cycling Stability of Nano ZnO
Molecules
zinc oxide
degradation
cycling stability
photocatalysis
methylene blue (MB)
title Efficient Degradation of Methylene Blue in Industrial Wastewater and High Cycling Stability of Nano ZnO
title_full Efficient Degradation of Methylene Blue in Industrial Wastewater and High Cycling Stability of Nano ZnO
title_fullStr Efficient Degradation of Methylene Blue in Industrial Wastewater and High Cycling Stability of Nano ZnO
title_full_unstemmed Efficient Degradation of Methylene Blue in Industrial Wastewater and High Cycling Stability of Nano ZnO
title_short Efficient Degradation of Methylene Blue in Industrial Wastewater and High Cycling Stability of Nano ZnO
title_sort efficient degradation of methylene blue in industrial wastewater and high cycling stability of nano zno
topic zinc oxide
degradation
cycling stability
photocatalysis
methylene blue (MB)
url https://www.mdpi.com/1420-3049/29/23/5584
work_keys_str_mv AT pingliang efficientdegradationofmethyleneblueinindustrialwastewaterandhighcyclingstabilityofnanozno
AT weiyeyang efficientdegradationofmethyleneblueinindustrialwastewaterandhighcyclingstabilityofnanozno
AT hongyanpeng efficientdegradationofmethyleneblueinindustrialwastewaterandhighcyclingstabilityofnanozno
AT shihuazhao efficientdegradationofmethyleneblueinindustrialwastewaterandhighcyclingstabilityofnanozno