Preparation and Hydrolysis of Secondary Diasulfones
Two secondary α-diazosulfones, 1-tosyl-1-diazo-ethane (I) and 1-tosyl-1-diazo-isobutane (II) have been prepared and characterised. The corresponding alcohols produced by acid hydrolysis are unstable and decompose to aldehyde and p-toluene-sulfinic acid; the olefins also formed in the acid hydrolysi...
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
1973-06-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9089 |
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| _version_ | 1849697988598824960 |
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| author | B. Michel J.F. McGarrity H. Dahn |
| author_facet | B. Michel J.F. McGarrity H. Dahn |
| author_sort | B. Michel |
| collection | DOAJ |
| description |
Two secondary α-diazosulfones, 1-tosyl-1-diazo-ethane (I) and 1-tosyl-1-diazo-isobutane (II) have been prepared and characterised. The corresponding alcohols produced by acid hydrolysis are unstable and decompose to aldehyde and p-toluene-sulfinic acid; the olefins also formed in the acid hydrolysis of I and II were found to undergo further transformations.
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| format | Article |
| id | doaj-art-67857b1f6d3d40d4b3668d5041caa66c |
| institution | DOAJ |
| issn | 0009-4293 2673-2424 |
| language | deu |
| publishDate | 1973-06-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj-art-67857b1f6d3d40d4b3668d5041caa66c2025-08-20T03:19:03ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241973-06-0127610.2533/chimia.1973.320Preparation and Hydrolysis of Secondary DiasulfonesB. Michel0J.F. McGarrity1H. Dahn2Institut de chimie organique de l’Université de LausanneInstitut de chimie organique de l’Université de LausanneInstitut de chimie organique de l’Université de Lausanne Two secondary α-diazosulfones, 1-tosyl-1-diazo-ethane (I) and 1-tosyl-1-diazo-isobutane (II) have been prepared and characterised. The corresponding alcohols produced by acid hydrolysis are unstable and decompose to aldehyde and p-toluene-sulfinic acid; the olefins also formed in the acid hydrolysis of I and II were found to undergo further transformations. https://www.chimia.ch/chimia/article/view/9089 |
| spellingShingle | B. Michel J.F. McGarrity H. Dahn Preparation and Hydrolysis of Secondary Diasulfones CHIMIA |
| title | Preparation and Hydrolysis of Secondary Diasulfones |
| title_full | Preparation and Hydrolysis of Secondary Diasulfones |
| title_fullStr | Preparation and Hydrolysis of Secondary Diasulfones |
| title_full_unstemmed | Preparation and Hydrolysis of Secondary Diasulfones |
| title_short | Preparation and Hydrolysis of Secondary Diasulfones |
| title_sort | preparation and hydrolysis of secondary diasulfones |
| url | https://www.chimia.ch/chimia/article/view/9089 |
| work_keys_str_mv | AT bmichel preparationandhydrolysisofsecondarydiasulfones AT jfmcgarrity preparationandhydrolysisofsecondarydiasulfones AT hdahn preparationandhydrolysisofsecondarydiasulfones |