Preparation of Sintered Brick from Electrolytic Manganese Residue in Songtao

Aiming at electrolytic manganese residue in Songtao, sintered bricks were prepared by using shale, limestone and fly ash in coordination with electrolytic manganese residue. With the shale and limestone which are rich in Songtao and the fly ash from the local power plant as ore blending materials in...

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Main Authors: Youlian ZHOU, Leiming HUANG, Yunbo JI, Jinxing ZUO, Xiangsong WEI
Format: Article
Language:zho
Published: Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences 2025-06-01
Series:Kuangchan zonghe liyong
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Online Access:http://www.kczhly.com/en/article/doi/10.12476/kczhly.202210200665
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author Youlian ZHOU
Leiming HUANG
Yunbo JI
Jinxing ZUO
Xiangsong WEI
author_facet Youlian ZHOU
Leiming HUANG
Yunbo JI
Jinxing ZUO
Xiangsong WEI
author_sort Youlian ZHOU
collection DOAJ
description Aiming at electrolytic manganese residue in Songtao, sintered bricks were prepared by using shale, limestone and fly ash in coordination with electrolytic manganese residue. With the shale and limestone which are rich in Songtao and the fly ash from the local power plant as ore blending materials in coordination with electrolytic manganese residue, the experiments of briquetting, preheating and roasting were carried out. The results show that the dosage of electrolytic manganese residue can be 50%~70%, and the briquet strength will be reduced when the dosage is too high or too low. In the firing process, the effective solid binding and liquid binding can be obtained, and the briquet cracks due to internal stress gathering can be avoided by adjusting the firing temperature and time. The uneven shrinkage and glass phase of low strength resulting from rapid cooling should be avoided during cooling down. The recommended ratio iselectrolytic manganese residue∶shale∶limestone∶fly ash= 6∶2∶1∶1, and the firing system is as follows: preheating temperature 500 ℃, preheating time 30 min, roasting temperature 1 000 ℃, roasting time 120 min, cooling down in a furnace. At this condition, the roasted briquets with the average strength of 28.84 MPa can be obtained, which reaches the MU25 strength index of common sintered brick, and its leaching toxicity also meets the comprehensive standards of sewage discharge. This study provides a new technical idea for the detoxification and recycle of electrolytic manganese residue in Songtao.
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id doaj-art-674fc52283f34e2fbba37a20f6772645
institution Kabale University
issn 1000-6532
language zho
publishDate 2025-06-01
publisher Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences
record_format Article
series Kuangchan zonghe liyong
spelling doaj-art-674fc52283f34e2fbba37a20f67726452025-08-20T03:29:18ZzhoInstitute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesKuangchan zonghe liyong1000-65322025-06-01463576410.12476/kczhly.2022102006652025-03zhouyoulianPreparation of Sintered Brick from Electrolytic Manganese Residue in SongtaoYoulian ZHOU0Leiming HUANG1Yunbo JI2Jinxing ZUO3Xiangsong WEI4Geology Institute of China Chemical Geology and Mine Bureau, Beijing 100101, ChinaGeology Institute of China Chemical Geology and Mine Bureau, Beijing 100101, ChinaGeology Institute of China Chemical Geology and Mine Bureau, Beijing 100101, ChinaGeology Institute of China Chemical Geology and Mine Bureau, Beijing 100101, ChinaGeology Institute of China Chemical Geology and Mine Bureau, Beijing 100101, ChinaAiming at electrolytic manganese residue in Songtao, sintered bricks were prepared by using shale, limestone and fly ash in coordination with electrolytic manganese residue. With the shale and limestone which are rich in Songtao and the fly ash from the local power plant as ore blending materials in coordination with electrolytic manganese residue, the experiments of briquetting, preheating and roasting were carried out. The results show that the dosage of electrolytic manganese residue can be 50%~70%, and the briquet strength will be reduced when the dosage is too high or too low. In the firing process, the effective solid binding and liquid binding can be obtained, and the briquet cracks due to internal stress gathering can be avoided by adjusting the firing temperature and time. The uneven shrinkage and glass phase of low strength resulting from rapid cooling should be avoided during cooling down. The recommended ratio iselectrolytic manganese residue∶shale∶limestone∶fly ash= 6∶2∶1∶1, and the firing system is as follows: preheating temperature 500 ℃, preheating time 30 min, roasting temperature 1 000 ℃, roasting time 120 min, cooling down in a furnace. At this condition, the roasted briquets with the average strength of 28.84 MPa can be obtained, which reaches the MU25 strength index of common sintered brick, and its leaching toxicity also meets the comprehensive standards of sewage discharge. This study provides a new technical idea for the detoxification and recycle of electrolytic manganese residue in Songtao.http://www.kczhly.com/en/article/doi/10.12476/kczhly.202210200665ceramics and compositeselectrolytic manganese residuesintered brickcompressive strengthtoxic leaching
spellingShingle Youlian ZHOU
Leiming HUANG
Yunbo JI
Jinxing ZUO
Xiangsong WEI
Preparation of Sintered Brick from Electrolytic Manganese Residue in Songtao
Kuangchan zonghe liyong
ceramics and composites
electrolytic manganese residue
sintered brick
compressive strength
toxic leaching
title Preparation of Sintered Brick from Electrolytic Manganese Residue in Songtao
title_full Preparation of Sintered Brick from Electrolytic Manganese Residue in Songtao
title_fullStr Preparation of Sintered Brick from Electrolytic Manganese Residue in Songtao
title_full_unstemmed Preparation of Sintered Brick from Electrolytic Manganese Residue in Songtao
title_short Preparation of Sintered Brick from Electrolytic Manganese Residue in Songtao
title_sort preparation of sintered brick from electrolytic manganese residue in songtao
topic ceramics and composites
electrolytic manganese residue
sintered brick
compressive strength
toxic leaching
url http://www.kczhly.com/en/article/doi/10.12476/kczhly.202210200665
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AT jinxingzuo preparationofsinteredbrickfromelectrolyticmanganeseresidueinsongtao
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