Preferable single-atom catalysts enabled by natural language processing for high energy density Na-S batteries

Abstract Employing appropriate single-atom (SA) catalysts in room-temperature sodium-sulfur (Na-S) batteries is propitious to promote the performance, whereas a universal designing strategy for the highly-efficient single-atom catalysts is absent. In this work, we adopt natural language processing t...

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Main Authors: Ruilin Bai, Yu Yao, Qiaosong Lin, Lize Wu, Zhen Li, Huijuan Wang, Mingze Ma, Di Mu, Lingxiang Hu, Hai Yang, Weihan Li, Shaolong Zhu, Xiaojun Wu, Xianhong Rui, Yan Yu
Format: Article
Language:English
Published: Nature Portfolio 2025-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-60931-x
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author Ruilin Bai
Yu Yao
Qiaosong Lin
Lize Wu
Zhen Li
Huijuan Wang
Mingze Ma
Di Mu
Lingxiang Hu
Hai Yang
Weihan Li
Shaolong Zhu
Xiaojun Wu
Xianhong Rui
Yan Yu
author_facet Ruilin Bai
Yu Yao
Qiaosong Lin
Lize Wu
Zhen Li
Huijuan Wang
Mingze Ma
Di Mu
Lingxiang Hu
Hai Yang
Weihan Li
Shaolong Zhu
Xiaojun Wu
Xianhong Rui
Yan Yu
author_sort Ruilin Bai
collection DOAJ
description Abstract Employing appropriate single-atom (SA) catalysts in room-temperature sodium-sulfur (Na-S) batteries is propitious to promote the performance, whereas a universal designing strategy for the highly-efficient single-atom catalysts is absent. In this work, we adopt natural language processing techniques to screen the potential single-atom catalysts, then a binary descriptor is constructed to optimize the catalyst candidates. Atomically dispersed cobalt anchored to both nitrogen and sulfur atoms (SA Co-N/S) is selected as an ideal catalyst to significantly facilitate sulfur reduction reaction. The sulfur cathode catalyzed with SA Co-N/S almost realizes complete transformation, and the corresponding pouch cell exhibits satisfactory performance with high mass loading. In-situ X-ray absorption spectroscopy reveals the dynamical interactions between SA Co-N/S and sulfur species in the sulfur reduction reaction. Our work provides a method to select the preferable SA catalyst and to understand the interfacial catalysis dynamics in the sustainable Na-S systems.
format Article
id doaj-art-66f323aea060480f8218e8b046c2ef22
institution Kabale University
issn 2041-1723
language English
publishDate 2025-07-01
publisher Nature Portfolio
record_format Article
series Nature Communications
spelling doaj-art-66f323aea060480f8218e8b046c2ef222025-08-20T03:37:37ZengNature PortfolioNature Communications2041-17232025-07-0116111510.1038/s41467-025-60931-xPreferable single-atom catalysts enabled by natural language processing for high energy density Na-S batteriesRuilin Bai0Yu Yao1Qiaosong Lin2Lize Wu3Zhen Li4Huijuan Wang5Mingze Ma6Di Mu7Lingxiang Hu8Hai Yang9Weihan Li10Shaolong Zhu11Xiaojun Wu12Xianhong Rui13Yan Yu14Hefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, University of Science and Technology of ChinaHefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, University of Science and Technology of ChinaUniversity of Chinese Academy of SciencesInstitute of Immunology, Zhejiang University School of MedicineHefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, University of Science and Technology of ChinaExperimental Center of Engineering and Material Science, University of Science and Technology of ChinaHefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, University of Science and Technology of ChinaSchool of Materials Science & Engineering, Shandong UniversityIBISC Lab, Université Paris-SaclayHefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, University of Science and Technology of ChinaDepartment of Mechanical and Materials Engineering, Western UniversityHefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, University of Science and Technology of ChinaHefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, University of Science and Technology of ChinaGuangdong Provincial Key Laboratory on Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of TechnologyHefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, University of Science and Technology of ChinaAbstract Employing appropriate single-atom (SA) catalysts in room-temperature sodium-sulfur (Na-S) batteries is propitious to promote the performance, whereas a universal designing strategy for the highly-efficient single-atom catalysts is absent. In this work, we adopt natural language processing techniques to screen the potential single-atom catalysts, then a binary descriptor is constructed to optimize the catalyst candidates. Atomically dispersed cobalt anchored to both nitrogen and sulfur atoms (SA Co-N/S) is selected as an ideal catalyst to significantly facilitate sulfur reduction reaction. The sulfur cathode catalyzed with SA Co-N/S almost realizes complete transformation, and the corresponding pouch cell exhibits satisfactory performance with high mass loading. In-situ X-ray absorption spectroscopy reveals the dynamical interactions between SA Co-N/S and sulfur species in the sulfur reduction reaction. Our work provides a method to select the preferable SA catalyst and to understand the interfacial catalysis dynamics in the sustainable Na-S systems.https://doi.org/10.1038/s41467-025-60931-x
spellingShingle Ruilin Bai
Yu Yao
Qiaosong Lin
Lize Wu
Zhen Li
Huijuan Wang
Mingze Ma
Di Mu
Lingxiang Hu
Hai Yang
Weihan Li
Shaolong Zhu
Xiaojun Wu
Xianhong Rui
Yan Yu
Preferable single-atom catalysts enabled by natural language processing for high energy density Na-S batteries
Nature Communications
title Preferable single-atom catalysts enabled by natural language processing for high energy density Na-S batteries
title_full Preferable single-atom catalysts enabled by natural language processing for high energy density Na-S batteries
title_fullStr Preferable single-atom catalysts enabled by natural language processing for high energy density Na-S batteries
title_full_unstemmed Preferable single-atom catalysts enabled by natural language processing for high energy density Na-S batteries
title_short Preferable single-atom catalysts enabled by natural language processing for high energy density Na-S batteries
title_sort preferable single atom catalysts enabled by natural language processing for high energy density na s batteries
url https://doi.org/10.1038/s41467-025-60931-x
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