Adsorption of Polyelectrolytes at the Manganese Oxide(IV)–Polymer Solution Interface: Structure of Adsorbed Layers

The influence of the molecular weight of polyelectrolytes on their adsorption and on the structure of the adsorbed layers at the manganese oxide(IV)–polymer solution interface was determined. Polyacrylic acid (PAA) and polyacrylamide (PAM) were applied as ionic polymers. An explanation was proposed...

Full description

Saved in:
Bibliographic Details
Main Authors: S. Chibowski, M. Wiśniewska, M. Paszkiewicz
Format: Article
Language:English
Published: SAGE Publishing 2002-06-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361702320644798
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The influence of the molecular weight of polyelectrolytes on their adsorption and on the structure of the adsorbed layers at the manganese oxide(IV)–polymer solution interface was determined. Polyacrylic acid (PAA) and polyacrylamide (PAM) were applied as ionic polymers. An explanation was proposed for the observed changes in surface charge and zeta potential of the solid in the presence of these polymers. The thickness of the adsorption layer of PAA and PAM was determined and the free energies of adsorption of these polymers on the MnO 2 surface were calculated from the zeta potential measurements.
ISSN:0263-6174
2048-4038