Electrode Reaction Kinetics at High Electrolyte Concentrations. H2 Oxidation and O2 Evolution in KOH

The kinetics of electrode reactions in concentrated electrolytes can be described with the usual rate equation provided that activities, rather than concentrations, of the reacting species are being used, that account is being taken of the activity of participating water molecules and that an activ...

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Main Author: Paul Ruetschi
Format: Article
Language:deu
Published: Swiss Chemical Society 1969-07-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/8773
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author Paul Ruetschi
author_facet Paul Ruetschi
author_sort Paul Ruetschi
collection DOAJ
description The kinetics of electrode reactions in concentrated electrolytes can be described with the usual rate equation provided that activities, rather than concentrations, of the reacting species are being used, that account is being taken of the activity of participating water molecules and that an activity coefficient of the activated complex estimated from the activity coefficient of reacting and/or resulting species, is being introduced.
format Article
id doaj-art-6639ad8ccbf642958bfed826218bb256
institution OA Journals
issn 0009-4293
2673-2424
language deu
publishDate 1969-07-01
publisher Swiss Chemical Society
record_format Article
series CHIMIA
spelling doaj-art-6639ad8ccbf642958bfed826218bb2562025-08-20T02:20:29ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241969-07-0123710.2533/chimia.1969.255Electrode Reaction Kinetics at High Electrolyte Concentrations. H2 Oxidation and O2 Evolution in KOHPaul Ruetschi0Leclanché S. A., Yverdon The kinetics of electrode reactions in concentrated electrolytes can be described with the usual rate equation provided that activities, rather than concentrations, of the reacting species are being used, that account is being taken of the activity of participating water molecules and that an activity coefficient of the activated complex estimated from the activity coefficient of reacting and/or resulting species, is being introduced. https://www.chimia.ch/chimia/article/view/8773
spellingShingle Paul Ruetschi
Electrode Reaction Kinetics at High Electrolyte Concentrations. H2 Oxidation and O2 Evolution in KOH
CHIMIA
title Electrode Reaction Kinetics at High Electrolyte Concentrations. H2 Oxidation and O2 Evolution in KOH
title_full Electrode Reaction Kinetics at High Electrolyte Concentrations. H2 Oxidation and O2 Evolution in KOH
title_fullStr Electrode Reaction Kinetics at High Electrolyte Concentrations. H2 Oxidation and O2 Evolution in KOH
title_full_unstemmed Electrode Reaction Kinetics at High Electrolyte Concentrations. H2 Oxidation and O2 Evolution in KOH
title_short Electrode Reaction Kinetics at High Electrolyte Concentrations. H2 Oxidation and O2 Evolution in KOH
title_sort electrode reaction kinetics at high electrolyte concentrations h2 oxidation and o2 evolution in koh
url https://www.chimia.ch/chimia/article/view/8773
work_keys_str_mv AT paulruetschi electrodereactionkineticsathighelectrolyteconcentrationsh2oxidationando2evolutioninkoh