Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide
We synthesized N-(dimethylcarbamothioyl)-4-fluorobenzamide compound and its copper(II) and nickel(II) complexes. The structures of compounds have been characterized by elemental analysis and spectral data (IR, 1H NMR). Furthermore, crystal and molecular structure of the synthesized complexes have be...
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| Language: | English |
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Wiley
2018-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2018/6108242 |
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| author | Gun Binzet Ersan Turunc Ulrich Flörke Nevzat Külcü Hakan Arslan |
| author_facet | Gun Binzet Ersan Turunc Ulrich Flörke Nevzat Külcü Hakan Arslan |
| author_sort | Gun Binzet |
| collection | DOAJ |
| description | We synthesized N-(dimethylcarbamothioyl)-4-fluorobenzamide compound and its copper(II) and nickel(II) complexes. The structures of compounds have been characterized by elemental analysis and spectral data (IR, 1H NMR). Furthermore, crystal and molecular structure of the synthesized complexes have been identified by using single crystal X-ray diffraction data. In the complexes formation the metal atom was coordinated via two sulfur atoms and two oxygen atoms. The single crystal structure of copper(II) and nickel(II) complex exhibits slightly distorted square planar geometry. The oxygen atoms are in a cis configuration. It appeared that the lengths of the thiocarbonyl and carbonyl bonds are longer than the average for C=S and C=O; meanwhile the C‐N bonds in the complex ring appeared to be shorter than the average for C‐N single bonds. These data show that C-O, C-S, and C-N bond lengths of the complexes suggest considerable electronic delocalization in the chelate ring. All bond lengths and angles obtained as a result of the analyses are found to be within experimental error limits. The obtained crystal analysis data shows that the structure of complex compounds is compatible with similar compounds in literature. Electrochemical behavior of complexes has been investigated by cyclic voltammetry technique in aprotic media. From the cyclic voltammetric investigation, both of the complexes have demonstrated electroactive properties. |
| format | Article |
| id | doaj-art-66198fa2b3ef45548fc7b7c451af6baa |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2018-01-01 |
| publisher | Wiley |
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| series | Journal of Chemistry |
| spelling | doaj-art-66198fa2b3ef45548fc7b7c451af6baa2025-08-20T03:34:17ZengWileyJournal of Chemistry2090-90632090-90712018-01-01201810.1155/2018/61082426108242Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamideGun Binzet0Ersan Turunc1Ulrich Flörke2Nevzat Külcü3Hakan Arslan4Department of Elementary Science Education, Faculty of Education, Mersin University, 33160 Mersin, TurkeyAdvanced Technology Research and Application Center, Mersin University, 33343 Mersin, TurkeyDepartment of Chemistry, Paderborn University, 33098 Paderborn, GermanyDepartment of Chemistry, Faculty of Arts and Science, Mersin University, 33343 Mersin, TurkeyDepartment of Chemistry, Faculty of Arts and Science, Mersin University, 33343 Mersin, TurkeyWe synthesized N-(dimethylcarbamothioyl)-4-fluorobenzamide compound and its copper(II) and nickel(II) complexes. The structures of compounds have been characterized by elemental analysis and spectral data (IR, 1H NMR). Furthermore, crystal and molecular structure of the synthesized complexes have been identified by using single crystal X-ray diffraction data. In the complexes formation the metal atom was coordinated via two sulfur atoms and two oxygen atoms. The single crystal structure of copper(II) and nickel(II) complex exhibits slightly distorted square planar geometry. The oxygen atoms are in a cis configuration. It appeared that the lengths of the thiocarbonyl and carbonyl bonds are longer than the average for C=S and C=O; meanwhile the C‐N bonds in the complex ring appeared to be shorter than the average for C‐N single bonds. These data show that C-O, C-S, and C-N bond lengths of the complexes suggest considerable electronic delocalization in the chelate ring. All bond lengths and angles obtained as a result of the analyses are found to be within experimental error limits. The obtained crystal analysis data shows that the structure of complex compounds is compatible with similar compounds in literature. Electrochemical behavior of complexes has been investigated by cyclic voltammetry technique in aprotic media. From the cyclic voltammetric investigation, both of the complexes have demonstrated electroactive properties.http://dx.doi.org/10.1155/2018/6108242 |
| spellingShingle | Gun Binzet Ersan Turunc Ulrich Flörke Nevzat Külcü Hakan Arslan Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide Journal of Chemistry |
| title | Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide |
| title_full | Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide |
| title_fullStr | Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide |
| title_full_unstemmed | Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide |
| title_short | Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide |
| title_sort | crystal structure and cyclic voltammetric studies on the metal complexes of n dimethylcarbamothioyl 4 fluorobenzamide |
| url | http://dx.doi.org/10.1155/2018/6108242 |
| work_keys_str_mv | AT gunbinzet crystalstructureandcyclicvoltammetricstudiesonthemetalcomplexesofndimethylcarbamothioyl4fluorobenzamide AT ersanturunc crystalstructureandcyclicvoltammetricstudiesonthemetalcomplexesofndimethylcarbamothioyl4fluorobenzamide AT ulrichflorke crystalstructureandcyclicvoltammetricstudiesonthemetalcomplexesofndimethylcarbamothioyl4fluorobenzamide AT nevzatkulcu crystalstructureandcyclicvoltammetricstudiesonthemetalcomplexesofndimethylcarbamothioyl4fluorobenzamide AT hakanarslan crystalstructureandcyclicvoltammetricstudiesonthemetalcomplexesofndimethylcarbamothioyl4fluorobenzamide |