Is Ozonation Treatment Efficient to Provide Safe Reclaimed Water? Assessing the Effects of Synthetic Wastewater Effluents in Human Cell Models

Ozonation has been promoted as a successful methodology for recovering effluents from wastewater treatment plants, with special emphasis on wastewater contaminated with pharmaceutical and personal care products (PPCPs). Still, ozonation reactions may generate potentially toxic by-products, jeopardiz...

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Main Authors: Ana Teresa Rocha, Fátima Jesus, Helena Oliveira, João Gomes, Joana Luísa Pereira
Format: Article
Language:English
Published: MDPI AG 2025-07-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/14/7784
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author Ana Teresa Rocha
Fátima Jesus
Helena Oliveira
João Gomes
Joana Luísa Pereira
author_facet Ana Teresa Rocha
Fátima Jesus
Helena Oliveira
João Gomes
Joana Luísa Pereira
author_sort Ana Teresa Rocha
collection DOAJ
description Ozonation has been promoted as a successful methodology for recovering effluents from wastewater treatment plants, with special emphasis on wastewater contaminated with pharmaceutical and personal care products (PPCPs). Still, ozonation reactions may generate potentially toxic by-products, jeopardizing human health safety, a critical aspect considering the use of reclaimed water. We aimed at understanding the potential impacts of ozonation on the quality of reclaimed water for human use through cell viability assays with human skin keratinocytes (HaCaT cell line). Under this context, the cytotoxicity of synthetic effluents contaminated with methyl- and propylparaben, paracetamol, sulfamethoxazole, and carbamazepine, both individually and in mixtures, was assessed before and after ozonation. The viability of HaCaT cells decreased after exposure to untreated synthetic effluents, denoting the cytotoxicity of the tested PPCPs singly and more prominently in mixtures (especially in those combining two and three PPCPs). A similar pattern was observed when testing effluents treated with ozonation. Since the parent contaminants were fully removed during ozonation, the observed cytotoxicity relates to degradation by-products and interactive effects among them. This study suggests that ozonation is poorly efficient in reducing cytotoxicity, as required for the safe use of ozone-treated reclaimed water in activities involving direct contact with human skin.
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spelling doaj-art-66036b7909ee47b09d63b79e705b5f332025-08-20T03:58:25ZengMDPI AGApplied Sciences2076-34172025-07-011514778410.3390/app15147784Is Ozonation Treatment Efficient to Provide Safe Reclaimed Water? Assessing the Effects of Synthetic Wastewater Effluents in Human Cell ModelsAna Teresa Rocha0Fátima Jesus1Helena Oliveira2João Gomes3Joana Luísa Pereira4Department of Biology, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Biology, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Biology, University of Aveiro, 3810-193 Aveiro, PortugalCERES, Department of Chemical Engineering, Faculty of Sciences and Technology, University of Coimbra, 3030-790 Coimbra, PortugalDepartment of Biology, University of Aveiro, 3810-193 Aveiro, PortugalOzonation has been promoted as a successful methodology for recovering effluents from wastewater treatment plants, with special emphasis on wastewater contaminated with pharmaceutical and personal care products (PPCPs). Still, ozonation reactions may generate potentially toxic by-products, jeopardizing human health safety, a critical aspect considering the use of reclaimed water. We aimed at understanding the potential impacts of ozonation on the quality of reclaimed water for human use through cell viability assays with human skin keratinocytes (HaCaT cell line). Under this context, the cytotoxicity of synthetic effluents contaminated with methyl- and propylparaben, paracetamol, sulfamethoxazole, and carbamazepine, both individually and in mixtures, was assessed before and after ozonation. The viability of HaCaT cells decreased after exposure to untreated synthetic effluents, denoting the cytotoxicity of the tested PPCPs singly and more prominently in mixtures (especially in those combining two and three PPCPs). A similar pattern was observed when testing effluents treated with ozonation. Since the parent contaminants were fully removed during ozonation, the observed cytotoxicity relates to degradation by-products and interactive effects among them. This study suggests that ozonation is poorly efficient in reducing cytotoxicity, as required for the safe use of ozone-treated reclaimed water in activities involving direct contact with human skin.https://www.mdpi.com/2076-3417/15/14/7784wastewater treatmentwastewater reusehuman health safetyHaCaTcytotoxicityparabens
spellingShingle Ana Teresa Rocha
Fátima Jesus
Helena Oliveira
João Gomes
Joana Luísa Pereira
Is Ozonation Treatment Efficient to Provide Safe Reclaimed Water? Assessing the Effects of Synthetic Wastewater Effluents in Human Cell Models
Applied Sciences
wastewater treatment
wastewater reuse
human health safety
HaCaT
cytotoxicity
parabens
title Is Ozonation Treatment Efficient to Provide Safe Reclaimed Water? Assessing the Effects of Synthetic Wastewater Effluents in Human Cell Models
title_full Is Ozonation Treatment Efficient to Provide Safe Reclaimed Water? Assessing the Effects of Synthetic Wastewater Effluents in Human Cell Models
title_fullStr Is Ozonation Treatment Efficient to Provide Safe Reclaimed Water? Assessing the Effects of Synthetic Wastewater Effluents in Human Cell Models
title_full_unstemmed Is Ozonation Treatment Efficient to Provide Safe Reclaimed Water? Assessing the Effects of Synthetic Wastewater Effluents in Human Cell Models
title_short Is Ozonation Treatment Efficient to Provide Safe Reclaimed Water? Assessing the Effects of Synthetic Wastewater Effluents in Human Cell Models
title_sort is ozonation treatment efficient to provide safe reclaimed water assessing the effects of synthetic wastewater effluents in human cell models
topic wastewater treatment
wastewater reuse
human health safety
HaCaT
cytotoxicity
parabens
url https://www.mdpi.com/2076-3417/15/14/7784
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