Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanism
Kinetics of [2+2+2]-cycloaddition of acrylates to norbornadiene in the presence of η3-bis(allyl) nickel was studied. The thermodynamic parameters were determined. Kinetics equations for all of the isomer reaction products were found. The data obtained agree with the formerly proposed mechanism.
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2010-10-01
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| Series: | Тонкие химические технологии |
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| Online Access: | https://www.finechem-mirea.ru/jour/article/view/932 |
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| author | I. E. Efros O. A. Nikityuk D. V. Dmitriev V. R. Flid |
| author_facet | I. E. Efros O. A. Nikityuk D. V. Dmitriev V. R. Flid |
| author_sort | I. E. Efros |
| collection | DOAJ |
| description | Kinetics of [2+2+2]-cycloaddition of acrylates to norbornadiene in the presence of η3-bis(allyl) nickel was studied. The thermodynamic parameters were determined. Kinetics equations for all of the isomer reaction products were found. The data obtained agree with the formerly proposed mechanism. |
| format | Article |
| id | doaj-art-65e6747f3b8f40b6ae4cbfcc67cf6249 |
| institution | Kabale University |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2010-10-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-65e6747f3b8f40b6ae4cbfcc67cf62492025-08-20T03:56:24ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752010-10-01555864926Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanismI. E. Efros0O. A. Nikityuk1D. V. Dmitriev2V. R. Flid3M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571Kinetics of [2+2+2]-cycloaddition of acrylates to norbornadiene in the presence of η3-bis(allyl) nickel was studied. The thermodynamic parameters were determined. Kinetics equations for all of the isomer reaction products were found. The data obtained agree with the formerly proposed mechanism.https://www.finechem-mirea.ru/jour/article/view/932catalysiscycloadditionacrylatekineticsmechanism |
| spellingShingle | I. E. Efros O. A. Nikityuk D. V. Dmitriev V. R. Flid Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanism Тонкие химические технологии catalysis cycloaddition acrylate kinetics mechanism |
| title | Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanism |
| title_full | Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanism |
| title_fullStr | Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanism |
| title_full_unstemmed | Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanism |
| title_short | Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanism |
| title_sort | catalytic cycloaddition of acrylates to norbornadiene kinetics and mechanism |
| topic | catalysis cycloaddition acrylate kinetics mechanism |
| url | https://www.finechem-mirea.ru/jour/article/view/932 |
| work_keys_str_mv | AT ieefros catalyticcycloadditionofacrylatestonorbornadienekineticsandmechanism AT oanikityuk catalyticcycloadditionofacrylatestonorbornadienekineticsandmechanism AT dvdmitriev catalyticcycloadditionofacrylatestonorbornadienekineticsandmechanism AT vrflid catalyticcycloadditionofacrylatestonorbornadienekineticsandmechanism |