Thermally stable rigid polyurethane foam with excellent thermal insulation and mechanical properties

Rigid polyurethane foam (RPUF) had been widely used in many fields due to its excellent performance. However, its poor thermal stability had invisibly formed a certain obstacle to its further development, so it was imperative to improve its thermal stability and other properties. In the current work...

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Main Authors: Xu Zhang, Shuai Ding, Zhaoqian Wang, Zhi Wang, Hua Xie
Format: Article
Language:English
Published: Elsevier 2025-09-01
Series:Case Studies in Thermal Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214157X2500927X
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author Xu Zhang
Shuai Ding
Zhaoqian Wang
Zhi Wang
Hua Xie
author_facet Xu Zhang
Shuai Ding
Zhaoqian Wang
Zhi Wang
Hua Xie
author_sort Xu Zhang
collection DOAJ
description Rigid polyurethane foam (RPUF) had been widely used in many fields due to its excellent performance. However, its poor thermal stability had invisibly formed a certain obstacle to its further development, so it was imperative to improve its thermal stability and other properties. In the current work, a one-step method was used to successfully prepare silk fibroin-based melamine (MA) modified RPUF. The thermal stability of the modified RPUF was studied by thermogravimetric (TG) analysis and four calculated methods, and the results showed that RPUF-MA10 with an MA of 10 wt% had the highest thermal stability and apparent activation energy (E). Thermal imaging studies show that RPUF-MA10 had better thermal insulation properties than RPUF-MA0. In quasi-static compression tests, RPUF-MA10 had the highest modulus of elasticity (0.33 MPa), compressive strength (0.15 MPa), energy absorption efficiency (52.53 %) and compressive strain (76.05 %). These results were now a good reference for the engineering applications of RPUF materials.
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institution Kabale University
issn 2214-157X
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publishDate 2025-09-01
publisher Elsevier
record_format Article
series Case Studies in Thermal Engineering
spelling doaj-art-654de194e1724d62810da696b79db8972025-08-20T03:50:53ZengElsevierCase Studies in Thermal Engineering2214-157X2025-09-017310666710.1016/j.csite.2025.106667Thermally stable rigid polyurethane foam with excellent thermal insulation and mechanical propertiesXu Zhang0Shuai Ding1Zhaoqian Wang2Zhi Wang3Hua Xie4Liaoning Key Laboratory of Aircraft Fire Explosion Control and Reliability Airworthiness Technology, Shenyang Aerospace University, Shenyang, 110136, China; School of Safety Engineering, Shenyang Aerospace University, Shenyang, 110136, China; Corresponding author. Liaoning Key Laboratory of Aircraft Fire Explosion Control and Reliability Airworthiness Technology, Shenyang Aerospace University, Shenyang, 110136, China.Liaoning Key Laboratory of Aircraft Fire Explosion Control and Reliability Airworthiness Technology, Shenyang Aerospace University, Shenyang, 110136, China; School of Safety Engineering, Shenyang Aerospace University, Shenyang, 110136, ChinaLiaoning Key Laboratory of Aircraft Fire Explosion Control and Reliability Airworthiness Technology, Shenyang Aerospace University, Shenyang, 110136, China; School of Safety Engineering, Shenyang Aerospace University, Shenyang, 110136, ChinaLiaoning Key Laboratory of Aircraft Fire Explosion Control and Reliability Airworthiness Technology, Shenyang Aerospace University, Shenyang, 110136, China; School of Safety Engineering, Shenyang Aerospace University, Shenyang, 110136, ChinaLiaoning Key Laboratory of Aircraft Fire Explosion Control and Reliability Airworthiness Technology, Shenyang Aerospace University, Shenyang, 110136, China; School of Safety Engineering, Shenyang Aerospace University, Shenyang, 110136, ChinaRigid polyurethane foam (RPUF) had been widely used in many fields due to its excellent performance. However, its poor thermal stability had invisibly formed a certain obstacle to its further development, so it was imperative to improve its thermal stability and other properties. In the current work, a one-step method was used to successfully prepare silk fibroin-based melamine (MA) modified RPUF. The thermal stability of the modified RPUF was studied by thermogravimetric (TG) analysis and four calculated methods, and the results showed that RPUF-MA10 with an MA of 10 wt% had the highest thermal stability and apparent activation energy (E). Thermal imaging studies show that RPUF-MA10 had better thermal insulation properties than RPUF-MA0. In quasi-static compression tests, RPUF-MA10 had the highest modulus of elasticity (0.33 MPa), compressive strength (0.15 MPa), energy absorption efficiency (52.53 %) and compressive strain (76.05 %). These results were now a good reference for the engineering applications of RPUF materials.http://www.sciencedirect.com/science/article/pii/S2214157X2500927XRigid polyurethane foamThermal stabilityMechanical propertiesThermal insulation
spellingShingle Xu Zhang
Shuai Ding
Zhaoqian Wang
Zhi Wang
Hua Xie
Thermally stable rigid polyurethane foam with excellent thermal insulation and mechanical properties
Case Studies in Thermal Engineering
Rigid polyurethane foam
Thermal stability
Mechanical properties
Thermal insulation
title Thermally stable rigid polyurethane foam with excellent thermal insulation and mechanical properties
title_full Thermally stable rigid polyurethane foam with excellent thermal insulation and mechanical properties
title_fullStr Thermally stable rigid polyurethane foam with excellent thermal insulation and mechanical properties
title_full_unstemmed Thermally stable rigid polyurethane foam with excellent thermal insulation and mechanical properties
title_short Thermally stable rigid polyurethane foam with excellent thermal insulation and mechanical properties
title_sort thermally stable rigid polyurethane foam with excellent thermal insulation and mechanical properties
topic Rigid polyurethane foam
Thermal stability
Mechanical properties
Thermal insulation
url http://www.sciencedirect.com/science/article/pii/S2214157X2500927X
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AT shuaiding thermallystablerigidpolyurethanefoamwithexcellentthermalinsulationandmechanicalproperties
AT zhaoqianwang thermallystablerigidpolyurethanefoamwithexcellentthermalinsulationandmechanicalproperties
AT zhiwang thermallystablerigidpolyurethanefoamwithexcellentthermalinsulationandmechanicalproperties
AT huaxie thermallystablerigidpolyurethanefoamwithexcellentthermalinsulationandmechanicalproperties