Study of Kinetics, Equilibrium and the Influence of Steric Effects on Proton-Transfer in the Reactions of 2, 2, 4- and 2, 6- Substituted Anilines with 2-Phenoxy-3,5-dinitropyridine in DMSO

Study of Kinetics, Equilibrium and the Influence of Steric Effects on Proton-Transfer in the Reactions of 2, 2, 4- and 2, 6- Substituted Anilines with 2-Phenoxy-3,5-dinitropyridine in DMSO

Kinetic and equilibrium results for the reactions of 2-phenoxy-3,5-dinitropyridine (1), with a series of 2, 2, 4- and 2, 6- substituted anilines (2a-f), in the presence of DABCO in DMSO are reported. The reactions yield the 2-anilino derivatives (5), without the accumulation of intermediates. Kinet...

Full description

Saved in:

Bibliographic Details
Main Author:	Basim H. Asghar
Format:	Article
Language:	English
Published:	Wiley 2010-01-01
Series:	E-Journal of Chemistry
Online Access:	http://dx.doi.org/10.1155/2010/721387
Tags:	Add Tag No Tags, Be the first to tag this record!

Similar Items

Isobaric vapour-liquid equilibrium studies for binary systems of a green solvent furfuryl alcohol with aniline and substituted anilines at 101.31 kPa
by: K.A. Sasikala, et al.
Published: (2025-03-01)

Chlorinated Anilines as Molecular Templates to Achieve [2 + 2] Cycloaddition Reactions within Organic Cocrystals
by: Grace K. White, et al.
Published: (2025-05-01)

Synthesis and evaluation of quinolinvinyl-phenoxy-1,2,3-triazole-acetamide hybrids against breast cancer
by: Maliheh Safavi, et al.
Published: (2025-05-01)

“Alkyl-Substituted Phenoxy” Spacer Strategy: Antiaggregated and Highly Soluble Zinc Phthalocyanines for Color Films
by: Shi Li, et al.
Published: (2024-12-01)

Synthesis of Various Polyaniline / Clay Nanocomposites Derived from Aniline and Substituted Aniline Derivatives by Mechanochemical Intercalation Method
by: N. Kalaivasan, et al.
Published: (2010-01-01)

Cobalt and Nickel Complexes Bearing 2,6-Bis(imino)phenoxy Ligands:Synthesis and Ethylene Oligomerization Study
by: Jian-Long Du, et al.
Published: (2006-01-01)

A concise synthesis of pyrrolo[2,3-d]pyrimidine through I2/DMSO promoted cascade annulation
by: Meng Xia, et al.
Published: (2025-08-01)

Antifungal Activities of Ketoazomethines of Phenyl Glyoxal and p-Substituted Anilines
by: Vishnu Vats, et al.
Published: (2011-01-01)

Shape-Selective Adsorption of Substituted Aniline Pollutants from Wastewater
by: Talib M. Albayati, et al.
Published: (2013-05-01)

Synthesis and Antithrombotic Activity Determination of (2-Methyl-4-[4-methyl-2-(4-trifluoromethylphenyl)-thiazole-5-ylmethylsulfanyl]phenoxy)acetic Acid Derivatives
by: D. V. Minin, et al.
Published: (2019-07-01)

Synthesis, and antibacterial activities of novel 1,3,4a,9-tetraza-4H-fluoren-2-amines incorporating phenoxy-N-arylacetamide, pyrazole, and 2-(4-(1-phenyl-1H-pyrazol-3-yl)phenoxy)-N-arylacetamide moieties
by: Reham E. Abdelwahab, et al.
Published: (2025-03-01)

Adsorption of CO2, CH4 and H2 onto zeolite 13 X: Kinetic and equilibrium studies
by: Hedi Jedli, et al.
Published: (2024-12-01)

Structure–Activity Optimization of Phenoxy-1,2-dioxetane Precursors as Probes for Singlet Oxygen Yields Unprecedented Detection Sensitivity
by: Rozan Tannous, et al.
Published: (2025-05-01)

Synthesis and interaction with model DNA of polyaniline and poly[N-(2-hydroxyethyl)aniline]
by: A.I. Khadieva, et al.
Published: (2019-03-01)

Removal of 2,4-Dichloro Phenoxy Acetic Acid by Silica Particles Obtained from the Siliceous Sand of Houeyogbe(Republic of Benin)
by: Houefaannick Leslie Glitho, et al.
Published: (2024-11-01)

Crystal structure of 14-(R)-(2′-cyano-phenoxy)-3,19-diacetyl andrographolide, C31H37NO7
by: Liu Zhuyun, et al.
Published: (2025-02-01)

Sensitivity of the phenoxy derivatives of 2,4-dihydro-5H-[1,2,3]triazolo[4,5-d]pyrimidin-5-ones to acidic and basic stimuli
by: Alexander K. Eltyshev, et al.
Published: (2021-08-01)

Steric Effects on Reaction Rates. VII. Application of a New MM2 Force-Field for Carbenium Ions to Solvolysis of Bridgehead Substrates
by: Paul Müller, et al.
Published: (1984-11-01)

Synthesis of 1,2-Dihydro-Substituted Aniline Analogues Involving N-Phenyl-3-aza-Cope Rearrangement Using a Metal-Free Catalytic Approach
by: Osamah Alduhaish, et al.
Published: (2020-01-01)

Synthese von [2.2](3,5) Pyridinophan
by: W. Jenny, et al.
Published: (1967-10-01)

Editorial for Vol. 35, No. 2
by: Juwon Lim
Published: (2025-06-01)

Molecular Interaction Study of some ortho and para Substituted Anilines with 1-Octanol
by: M. S. Manjunatha, et al.
Published: (2010-01-01)

KINETIC STUDY OF THE REACTION OF 2,2’-BIPYRIDYL CHROMIUM PEROXIDE WITH ALCOHOLS
Published: (2000-06-01)

Dual-targeting and steric hindrance resolution in HER2 IHC: a novel approach to improve diagnostic sensitivity
by: Li Luo, et al.
Published: (2025-07-01)

Molecular Evolution of H2O:O2 Ices at Different Temperatures in Simulated Space Environments. I. Chemical Kinetics and Equilibrium
by: J. R. C. Silva, et al.
Published: (2025-01-01)

2,2,3,3,4,4,4-Heptafluorobutyl Acetate—Chemical Equilibrium and Kinetics of the Esterification Reaction of 2,2,3,3,4,4,4-Heptafluorobutan-1-ol and Acetic Acid in the Presence of an Acidic Catalyst
by: Andrei V. Polkovnichenko, et al.
Published: (2025-04-01)

Influence of Donor/Withdrawing Groups in an 3,5-Aryl-Substituted Pyrazole Organocatalyst for the Chemical Fixation of CO2
by: Gabriel Elias Taliateli Oliveira Prado, et al.
Published: (2025-06-01)

Adsorption Equilibrium and Kinetics of Gardenia Blue on TiO2 Photoelectrode for Dye-Sensitized Solar Cells
by: Tae-Young Kim, et al.
Published: (2014-01-01)

CO2 Capture on Prussian Blue Analogues (PBAs): Modeling Equilibrium, Kinetics, and Isosteric Heats of Adsorption
by: Paloma M. Frías-Ureña, et al.
Published: (2025-03-01)

Synthesis, structure, and antimicrobial activity of aminated 5-chloro-6-nitrobenzofurazan with substituted anilines
by: I.V. Galkina, et al.
Published: (2017-12-01)

Aniline Derivatives Containing 1-Substituted 1,2,3-Triazole System as Potential Drug Candidates: Pharmacokinetic Profile Prediction, Lipophilicity Analysis Using Experimental and In Silico Studies
by: Elwira Chrobak, et al.
Published: (2024-11-01)

Multicomponent Reactions, Solvent-Free Synthesis of 2-Amino-4-aryl-6-substituted Pyridine-3,5-dicarbonitrile Derivatives, and Corrosion Inhibitors Evaluation
by: Naglaa F. H. Mahmoud, et al.
Published: (2018-01-01)

Antimicrobial and antifungal activity of 2-(1H-tetrazolo-5-yl)anilines and products of their structural modifications
by: O. M. Antypenko, et al.
Published: (2016-08-01)

Structural Analogues of Thyronamines: Some Aspects of the Structure and Bioactivity of 4-[4-(2-Aminoetoxy)benzyl]aniline
by: Alexander B. Eresko, et al.
Published: (2024-11-01)

Structural reactivity relationship and thermokinetic investigation of oxidation of substituted anilines by iridium (IV) in solution media
by: Riya Sailani
Published: (2025-03-01)

Steric Oscillations of the Baltic Sea Level
by: Zakharchuk Eugenii, et al.
Published: (2023-12-01)

REACTION OF 4-METHYL- 1 2,4-TRIAZOLINE- 3,5-DIONE WITH DI AND TRI-SUBSTITUTED STYRENES S.E. Mallakpour* and G.B. Butler**
Published: (1993-03-01)

Equilibrium and Kinetic Investigations of the Interaction of Model Platinum(II) Complex with DNA Constituents in Reference to the Antitumour Activity: Complex-Formation Reactions of [Pd(N,N-diethylethylenediamine)(H2O)2]2+ with Ligands of Biological Significance and Displacement Reactions of DNA Constituents
by: Eman Mohamed Shoukry
Published: (2009-01-01)

Interaction of potassium hexahalogenoosmates(IV) with DMSO
by: O. V. Rudnitskaya, et al.
Published: (2013-04-01)

Crystal structure of 2-(2,3-bis(4-methoxyphenyl)-1H-pyrrolo[2,3-b]quinoxalin-1-yl)anilin, C30H24N4O2
by: Tian Hangzhou, et al.
Published: (2024-12-01)