Filter Paper Inspired Zinc Oxide Nanomaterials with High Photocatalytic Activity for Degradation of Methylene Orange

Nanometer-sized zinc oxide (ZnO) has been synthesized through sol-gel method with natural cellulose substance (commercial filter paper) as template. The structure of zinc oxide nanomaterial was characterized by nitrogen adsorption-desorption and XRD. The morphology was observed by SEM and TEM. The r...

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Main Authors: Huang Liu, Yanhua Zhang, Hongtao Yang, Wei Xiao, Lanlan Sun
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2016/2862567
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author Huang Liu
Yanhua Zhang
Hongtao Yang
Wei Xiao
Lanlan Sun
author_facet Huang Liu
Yanhua Zhang
Hongtao Yang
Wei Xiao
Lanlan Sun
author_sort Huang Liu
collection DOAJ
description Nanometer-sized zinc oxide (ZnO) has been synthesized through sol-gel method with natural cellulose substance (commercial filter paper) as template. The structure of zinc oxide nanomaterial was characterized by nitrogen adsorption-desorption and XRD. The morphology was observed by SEM and TEM. The results show that the hexagonal wurtzite phase is actually the only crystal phase in the sample and the product faithfully inherits the hierarchical morphology and the complex network structure of the original filter paper, which is composed of many randomly intersecting zinc oxide microfibers and nanosheets with lots of close stacked particles adsorbed on the surface. Moreover, these zinc oxide nanomaterials possess abundant mesoporous structure with an average pore diameter of ca. 21 nm and a wide pore size distribution (3–30 nm). Due to the strong absorption ability in the UV range, the zinc oxide nanomaterial prepared by this method displays significantly high photocatalytic activity for degrading methyl orange. In a short period of 20 minutes, the zinc oxide nanomaterial has degraded about 50% of the original MO, and the MO dye is fully degraded after UV irradiation for 80 minutes.
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institution OA Journals
issn 2090-9063
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publishDate 2016-01-01
publisher Wiley
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spelling doaj-art-64f065b61a8f43b0b0a29bb4cdc68ce72025-08-20T02:06:36ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/28625672862567Filter Paper Inspired Zinc Oxide Nanomaterials with High Photocatalytic Activity for Degradation of Methylene OrangeHuang Liu0Yanhua Zhang1Hongtao Yang2Wei Xiao3Lanlan Sun4Research Institute for New Materials Technology, Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Science, Chongqing 402160, ChinaResearch Institute for New Materials Technology, Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Science, Chongqing 402160, ChinaResearch Institute for New Materials Technology, Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Science, Chongqing 402160, ChinaResearch Institute for New Materials Technology, Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Science, Chongqing 402160, ChinaResearch Institute for New Materials Technology, Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Science, Chongqing 402160, ChinaNanometer-sized zinc oxide (ZnO) has been synthesized through sol-gel method with natural cellulose substance (commercial filter paper) as template. The structure of zinc oxide nanomaterial was characterized by nitrogen adsorption-desorption and XRD. The morphology was observed by SEM and TEM. The results show that the hexagonal wurtzite phase is actually the only crystal phase in the sample and the product faithfully inherits the hierarchical morphology and the complex network structure of the original filter paper, which is composed of many randomly intersecting zinc oxide microfibers and nanosheets with lots of close stacked particles adsorbed on the surface. Moreover, these zinc oxide nanomaterials possess abundant mesoporous structure with an average pore diameter of ca. 21 nm and a wide pore size distribution (3–30 nm). Due to the strong absorption ability in the UV range, the zinc oxide nanomaterial prepared by this method displays significantly high photocatalytic activity for degrading methyl orange. In a short period of 20 minutes, the zinc oxide nanomaterial has degraded about 50% of the original MO, and the MO dye is fully degraded after UV irradiation for 80 minutes.http://dx.doi.org/10.1155/2016/2862567
spellingShingle Huang Liu
Yanhua Zhang
Hongtao Yang
Wei Xiao
Lanlan Sun
Filter Paper Inspired Zinc Oxide Nanomaterials with High Photocatalytic Activity for Degradation of Methylene Orange
Journal of Chemistry
title Filter Paper Inspired Zinc Oxide Nanomaterials with High Photocatalytic Activity for Degradation of Methylene Orange
title_full Filter Paper Inspired Zinc Oxide Nanomaterials with High Photocatalytic Activity for Degradation of Methylene Orange
title_fullStr Filter Paper Inspired Zinc Oxide Nanomaterials with High Photocatalytic Activity for Degradation of Methylene Orange
title_full_unstemmed Filter Paper Inspired Zinc Oxide Nanomaterials with High Photocatalytic Activity for Degradation of Methylene Orange
title_short Filter Paper Inspired Zinc Oxide Nanomaterials with High Photocatalytic Activity for Degradation of Methylene Orange
title_sort filter paper inspired zinc oxide nanomaterials with high photocatalytic activity for degradation of methylene orange
url http://dx.doi.org/10.1155/2016/2862567
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AT hongtaoyang filterpaperinspiredzincoxidenanomaterialswithhighphotocatalyticactivityfordegradationofmethyleneorange
AT weixiao filterpaperinspiredzincoxidenanomaterialswithhighphotocatalyticactivityfordegradationofmethyleneorange
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